FACTORS AFFECTING THE INCORPORATION OF COBALT AND NICKEL IN JAROSITE-TYPE COMPOUNDS
Laboratory studies have shown that minor amounts of cobalt and nickel are structurally incorporated in sodium jarosite, potassium jarosite and ammonium jarosite and that the extent of incorporation increases as the concentration of dissolved cobalt or nickel increases. Potassium jarosite incorporate...
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Published in | Canadian metallurgical quarterly Vol. 43; no. 3; pp. 305 - 319 |
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Main Authors | , |
Format | Journal Article |
Language | English |
Published |
Kingston, ON
Taylor & Francis
2004
Metallurgical Society of the Canadian Institute of Mining and Metallurgy |
Subjects | |
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Abstract | Laboratory studies have shown that minor amounts of cobalt and nickel are structurally incorporated in sodium jarosite, potassium jarosite and ammonium jarosite and that the extent of incorporation increases as the concentration of dissolved cobalt or nickel increases. Potassium jarosite incorporates more cobalt or nickel (∼1% Co or Ni) than does sodium jarosite or ammonium jarosite (∼0.4% Co or Ni). Elevated temperatures increase the incorporation of Co or Ni in the jarosite precipitates, but the increase is modest. Increasing concentrations of Na
2
SO
4
, K
2
SO
4
or (NH
4
)
2
SO
4
result in an increase in the Co and Ni contents of the jarosite precipitates. The extent of Co or Ni incorporation also increases as the pH of the synthesis solution increases. In contrast, elevated concentrations of ferric sulphate reduce the extent of Co or Ni incorporation in the jarosite precipitates. The above parametric dependencies suggest that Co(II) and Ni(II) substitute to a limited extent for Fe(III) in the jarosite structure and the X-ray diffraction analyses of the precipitates support this hypothesis. Efforts to extend the level of incorporation by the coupled substitution of Co(II) + Cu(II) for K(I) + Fe(III) or by the precipitation of lead jarosite were not successful. The oxidation of Co(II) to Co(III) resulted in a modest increase in the Co content of the jarosite precipitates, but the presence of poorly crystalline Co(III) oxyhydroxide (heterogenite) sometimes accounts for part of the increase.
Une étude de laboratoire a montré que des quantités mineures de cobalt et de nickel étaient incorporées structurellement dans la jarosite de sodium, la jarosite de potassium et la jarosite d'ammonium et que le degré d'incorporation augmentait à mesure que la concentration de cobalt et de nickel dissous augmentait. La jarosite de potassium incorpore plus de cobalt ou de nickel (∼1% Co ou Ni) que ne le fait la jarosite de sodium ou la jarosite d'ammonium (∼0.4% Co ou Ni). Les températures élevées augmentent l'incorporation du Co ou du Ni dans les précipités de jarosite, mais l'augmentation est modeste. L'augmentation des concentrations de Na
2
SO
4
, K
2
SO
4
ou (NH
4
)
2
SO
4
résulte en une augmentation du contenu en Co et en Ni des précipités de jarosite. Le degré d'incorporation de Co ou de Ni augmente également à mesure que le pH de la solution de synthèse augmente. Par contre, des concentrations élevées de sulfate ferrique réduisent le degré d'incorporation du Co ou du Ni dans les précipités de jarosite. Les dépendances paramétriques mentionnées ci-dessus suggèrent que le Co(II) et le Ni(II) se substituent de façon limitée au Fe(III) dans la structure de la jarosite et les analyses de diffraction des rayons x des précipités supportent cette hypothèse. Les efforts pour étendre le niveau d'incorporation par la substitution couplée de Co(II) + Cu(II) pour le K(I) + Fe(III) ou par la précipitation de la jarosite de plomb n'ont pas eu de succès. L'oxydation du Co(II) en Co(III) a résulté en une augmentation modeste de la teneur en Co dans les précipités de jarosite, mais la présence de l'oxyhydroxyde Co(III) (hétérogénite) faiblement cristallin tient parfois compte d'une partie de l'augmentation |
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AbstractList | Laboratory studies have shown that minor amounts of cobalt and nickel are structurally incorporated in sodium jarosite, potassium jarosite and ammonium jarosite and that the extent of incorporation increases as the concentration of dissolved cobalt or nickel increases. Potassium jarosite incorporates more cobalt or nickel (∼1% Co or Ni) than does sodium jarosite or ammonium jarosite (∼0.4% Co or Ni). Elevated temperatures increase the incorporation of Co or Ni in the jarosite precipitates, but the increase is modest. Increasing concentrations of Na
2
SO
4
, K
2
SO
4
or (NH
4
)
2
SO
4
result in an increase in the Co and Ni contents of the jarosite precipitates. The extent of Co or Ni incorporation also increases as the pH of the synthesis solution increases. In contrast, elevated concentrations of ferric sulphate reduce the extent of Co or Ni incorporation in the jarosite precipitates. The above parametric dependencies suggest that Co(II) and Ni(II) substitute to a limited extent for Fe(III) in the jarosite structure and the X-ray diffraction analyses of the precipitates support this hypothesis. Efforts to extend the level of incorporation by the coupled substitution of Co(II) + Cu(II) for K(I) + Fe(III) or by the precipitation of lead jarosite were not successful. The oxidation of Co(II) to Co(III) resulted in a modest increase in the Co content of the jarosite precipitates, but the presence of poorly crystalline Co(III) oxyhydroxide (heterogenite) sometimes accounts for part of the increase.
Une étude de laboratoire a montré que des quantités mineures de cobalt et de nickel étaient incorporées structurellement dans la jarosite de sodium, la jarosite de potassium et la jarosite d'ammonium et que le degré d'incorporation augmentait à mesure que la concentration de cobalt et de nickel dissous augmentait. La jarosite de potassium incorpore plus de cobalt ou de nickel (∼1% Co ou Ni) que ne le fait la jarosite de sodium ou la jarosite d'ammonium (∼0.4% Co ou Ni). Les températures élevées augmentent l'incorporation du Co ou du Ni dans les précipités de jarosite, mais l'augmentation est modeste. L'augmentation des concentrations de Na
2
SO
4
, K
2
SO
4
ou (NH
4
)
2
SO
4
résulte en une augmentation du contenu en Co et en Ni des précipités de jarosite. Le degré d'incorporation de Co ou de Ni augmente également à mesure que le pH de la solution de synthèse augmente. Par contre, des concentrations élevées de sulfate ferrique réduisent le degré d'incorporation du Co ou du Ni dans les précipités de jarosite. Les dépendances paramétriques mentionnées ci-dessus suggèrent que le Co(II) et le Ni(II) se substituent de façon limitée au Fe(III) dans la structure de la jarosite et les analyses de diffraction des rayons x des précipités supportent cette hypothèse. Les efforts pour étendre le niveau d'incorporation par la substitution couplée de Co(II) + Cu(II) pour le K(I) + Fe(III) ou par la précipitation de la jarosite de plomb n'ont pas eu de succès. L'oxydation du Co(II) en Co(III) a résulté en une augmentation modeste de la teneur en Co dans les précipités de jarosite, mais la présence de l'oxyhydroxyde Co(III) (hétérogénite) faiblement cristallin tient parfois compte d'une partie de l'augmentation Laboratory studies have shown that minor amounts of cobalt and nickel are structurally incorporated in sodium jarosite, potassium jarosite and ammonium jarosite and that the extent of incorporation increases as the concentration of dissolved cobalt or nickel increases. Potassium jarosite incorporates more cobalt or nickel (~1% Co or Ni) than does sodium jarosite or ammonium jarosite (~0.4% Co or Ni). Elevated temperatures increase the incorporation of Co or Ni in the jarosite precipitates, but the increase is modest. Increasing concentrations of Na2SO4, K2SO4 or (NH4)2SO4 result in an increase in the Co and Ni contents of the jarosite precipitates. The extent of Co or Ni incorporation also increases as the pH of the synthesis solution increases. In contrast, elevated concentrations of ferric sulphate reduce the extent of Co or Ni incorporation in the jarosite precipitates. The above parametric dependencies suggest that Co(II) and Ni(II) substitute to a limited extent for Fe(III) in the jarosite structure and the X-ray diffraction analyses of the precipitates support this hypothesis. Efforts to extend the level of incorporation by the coupled substitution of Co(II) + Cu(II) for K(I) + Fe(III) or by the precipitation of lead jarosite were not successful. The oxidation of Co(II) to Co(III) resulted in a modest increase in the Co content of the jarosite precipitates, but the presence of poorly crystalline Co(III) oxyhydroxide (heterogenite) sometimes accounts for part of the increase. |
Author | CHEN, T.T. DUTRIZAC, J.E. |
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Title | FACTORS AFFECTING THE INCORPORATION OF COBALT AND NICKEL IN JAROSITE-TYPE COMPOUNDS |
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