Preparation, Surface Characterization and Anticorrosive Behavior of Polyaniline and Poly(3,4-ethylenedioxythiophene) Deposited on Aluminum Alloy AA2024-T3

This work is focused on studying the preparation and characterization of two different conducting polymers, polyaniline and poly(3,4-ethylenedioxythiophene), on aluminum alloy AA2024-T3. In addition to the direct electrochemical deposition of the conducting polymers onto an untreated aluminum substr...

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Published inSurface engineering and applied electrochemistry Vol. 54; no. 3; pp. 297 - 306
Main Authors Iribarren, J. I., Català, M., Conchello, A. J., Pérez-Madrigal, M. M., Alemán, C.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.05.2018
Springer Nature B.V
Subjects
Accelerated tests
Aluminum alloys
Aluminum base alloys
Conducting polymers
Corrosion prevention
Corrosion tests
Engineering
Machines
Manufacturing
Organic chemistry
Pickling
Polyanilines
Polymers
Processes
Protective coatings
Self-assembled monolayers
Self-assembly
Substrates
Surface properties
surface pre-treatments
anticorrosive properties
aluminum protection
conducting polymers
steel protection
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Abstract This work is focused on studying the preparation and characterization of two different conducting polymers, polyaniline and poly(3,4-ethylenedioxythiophene), on aluminum alloy AA2024-T3. In addition to the direct electrochemical deposition of the conducting polymers onto an untreated aluminum substrate, the alloy surface pre-treatments based on single chemical acid pickling or chemical acid pickling followed by application of self-assembled monolayers have been also considered before the coating application. Coatings electrochemically deposited onto both untreated and pre-treated substrates have been characterized by physicochemical and electrochemical techniques, whereas their protective performance has been evaluated by means of polarization electrochemical techniques and accelerated corrosion tests. Although conducting polymers are widely used as protective coatings for steel substrates, the results obtained in this work indicate that their protective effect is not improved when deposited onto aluminum.
AbstractList This work is focused on studying the preparation and characterization of two different conducting polymers, polyaniline and poly(3,4-ethylenedioxythiophene), on aluminum alloy AA2024-T3. In addition to the direct electrochemical deposition of the conducting polymers onto an untreated aluminum substrate, the alloy surface pre-treatments based on single chemical acid pickling or chemical acid pickling followed by application of self-assembled monolayers have been also considered before the coating application. Coatings electrochemically deposited onto both untreated and pre-treated substrates have been characterized by physicochemical and electrochemical techniques, whereas their protective performance has been evaluated by means of polarization electrochemical techniques and accelerated corrosion tests. Although conducting polymers are widely used as protective coatings for steel substrates, the results obtained in this work indicate that their protective effect is not improved when deposited onto aluminum.
Author Alemán, C.
Iribarren, J. I.
Conchello, A. J.
Català, M.
Pérez-Madrigal, M. M.
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Issue 3
Keywords surface pre-treatments
anticorrosive properties
aluminum protection
conducting polymers
steel protection
Language English
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Snippet This work is focused on studying the preparation and characterization of two different conducting polymers, polyaniline and poly(3,4-ethylenedioxythiophene),...
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SubjectTerms Accelerated tests
Aluminum alloys
Aluminum base alloys
Conducting polymers
Corrosion prevention
Corrosion tests
Engineering
Machines
Manufacturing
Organic chemistry
Pickling
Polyanilines
Polymers
Processes
Protective coatings
Self-assembled monolayers
Self-assembly
Substrates
Surface properties
Title Preparation, Surface Characterization and Anticorrosive Behavior of Polyaniline and Poly(3,4-ethylenedioxythiophene) Deposited on Aluminum Alloy AA2024-T3
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