Abrasion properties of self-suspended hairy titanium dioxide nanomaterials
Considering the excellent solubility of pyrrolidone ring organic compounds, the synthesized N -(trimethoxysilyl) propyl- N -methyl-2-pyrrolidone chlorides was tethered onto titanium dioxide (TiO 2 ) nanoparticles to improve dispersion of TiO 2 , and then polyethylene oxide (PEO) oligomer through ion...
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| Published in | Applied nanoscience Vol. 7; no. 8; pp. 691 - 700 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Berlin/Heidelberg
Springer Berlin Heidelberg
01.11.2017
Springer Nature B.V |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Considering the excellent solubility of pyrrolidone ring organic compounds, the synthesized
N
-(trimethoxysilyl) propyl-
N
-methyl-2-pyrrolidone chlorides was tethered onto titanium dioxide (TiO
2
) nanoparticles to improve dispersion of TiO
2
, and then polyethylene oxide (PEO) oligomer through ion exchange embraced the tethered TiO
2
to obtain a novel self-suspended hairy TiO
2
nanomaterials without any solvent. A variety of techniques were carried out to illustrate the structure and properties of the self-suspended hairy TiO
2
nanomaterials. It was found that TiO
2
nanoparticles embody monodispersity in the hybrid system though the “false reunion” phenomenon occurring due to nonpermanent weak physical cross-linking. Remarkably, self-suspended hairy TiO
2
nanomaterials exhibit lower viscosity, facilitating maneuverable and outstanding antifriction and wear resistance properties, due to the synergistic lubricating effect between spontaneously forming lubricating film and nano-lubrication of TiO
2
cores, overcoming the deficiency of both solid and liquid lubricants. This make them promising candidates for the micro-electromechanic/nano-electromechanic systems (MEMS/NEMS). |
|---|---|
| AbstractList | Considering the excellent solubility of pyrrolidone ring organic compounds, the synthesized
N
-(trimethoxysilyl) propyl-
N
-methyl-2-pyrrolidone chlorides was tethered onto titanium dioxide (TiO
2
) nanoparticles to improve dispersion of TiO
2
, and then polyethylene oxide (PEO) oligomer through ion exchange embraced the tethered TiO
2
to obtain a novel self-suspended hairy TiO
2
nanomaterials without any solvent. A variety of techniques were carried out to illustrate the structure and properties of the self-suspended hairy TiO
2
nanomaterials. It was found that TiO
2
nanoparticles embody monodispersity in the hybrid system though the “false reunion” phenomenon occurring due to nonpermanent weak physical cross-linking. Remarkably, self-suspended hairy TiO
2
nanomaterials exhibit lower viscosity, facilitating maneuverable and outstanding antifriction and wear resistance properties, due to the synergistic lubricating effect between spontaneously forming lubricating film and nano-lubrication of TiO
2
cores, overcoming the deficiency of both solid and liquid lubricants. This make them promising candidates for the micro-electromechanic/nano-electromechanic systems (MEMS/NEMS). Considering the excellent solubility of pyrrolidone ring organic compounds, the synthesized N-(trimethoxysilyl) propyl-N-methyl-2-pyrrolidone chlorides was tethered onto titanium dioxide (TiO2) nanoparticles to improve dispersion of TiO2, and then polyethylene oxide (PEO) oligomer through ion exchange embraced the tethered TiO2 to obtain a novel self-suspended hairy TiO2 nanomaterials without any solvent. A variety of techniques were carried out to illustrate the structure and properties of the self-suspended hairy TiO2 nanomaterials. It was found that TiO2 nanoparticles embody monodispersity in the hybrid system though the “false reunion” phenomenon occurring due to nonpermanent weak physical cross-linking. Remarkably, self-suspended hairy TiO2 nanomaterials exhibit lower viscosity, facilitating maneuverable and outstanding antifriction and wear resistance properties, due to the synergistic lubricating effect between spontaneously forming lubricating film and nano-lubrication of TiO2 cores, overcoming the deficiency of both solid and liquid lubricants. This make them promising candidates for the micro-electromechanic/nano-electromechanic systems (MEMS/NEMS). |
| Author | Li, Shi-yun Yu, Ya-ming Zhang, Jiao-xia Liu, Si Wang, Lei Wang, Xiao-jing Yan, Chao |
| Author_xml | – sequence: 1 givenname: Jiao-xia surname: Zhang fullname: Zhang, Jiao-xia organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology – sequence: 2 givenname: Si surname: Liu fullname: Liu, Si organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology – sequence: 3 givenname: Chao orcidid: 0000-0002-6008-9452 surname: Yan fullname: Yan, Chao email: chaoyan@just.edu.cn organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology – sequence: 4 givenname: Xiao-jing surname: Wang fullname: Wang, Xiao-jing organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology – sequence: 5 givenname: Lei surname: Wang fullname: Wang, Lei organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology – sequence: 6 givenname: Ya-ming surname: Yu fullname: Yu, Ya-ming organization: College of Materials Science and Engineering, Huaqiao University – sequence: 7 givenname: Shi-yun surname: Li fullname: Li, Shi-yun organization: School of Materials Science and Engineering, Jiangsu University of Science and Technology |
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| Snippet | Considering the excellent solubility of pyrrolidone ring organic compounds, the synthesized
N
-(trimethoxysilyl) propyl-
N
-methyl-2-pyrrolidone chlorides was... Considering the excellent solubility of pyrrolidone ring organic compounds, the synthesized N-(trimethoxysilyl) propyl-N-methyl-2-pyrrolidone chlorides was... |
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| SubjectTerms | Abrasion Antifriction Chemistry and Materials Science Crosslinking Hybrid systems Lubricants Lubricants & lubrication Lubrication Materials Science Membrane Biology Nanochemistry Nanoelectromechanical systems Nanomaterials Nanoparticles Nanotechnology Nanotechnology and Microengineering Organic compounds Original Article Polyethylenes Properties (attributes) Titanium dioxide Titanium oxides |
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| Title | Abrasion properties of self-suspended hairy titanium dioxide nanomaterials |
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