Investigation of gamma and neutron shielding parameters for borosilicate glasses doped europium oxide for the immobilization of radioactive waste

Eu 3+ -doped borosilicate glasses were prepared by the melt-quenching method. Optical, physical and nuclear shielding properties of these glasses were studied. The FTIR measurements indicated that the continuous increase of europium concentration helped conversion of [BO 4 ] to [BO 3 ] groups. FTIR...

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Published inJournal of materials science. Materials in electronics Vol. 31; no. 9; pp. 6963 - 6976
Main Authors Saudi, H. A., Abd-Allah, W. M., Shaaban, Kh. S.
Format Journal Article
LanguageEnglish
Published New York Springer US 01.05.2020
Springer Nature B.V
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Abstract Eu 3+ -doped borosilicate glasses were prepared by the melt-quenching method. Optical, physical and nuclear shielding properties of these glasses were studied. The FTIR measurements indicated that the continuous increase of europium concentration helped conversion of [BO 4 ] to [BO 3 ] groups. FTIR spectroscopy results were in good agreement with optical band energy gap, density and molar volume values revealing network modifications caused by europium ions in the glass structure. The amorphous natures of the samples were ascertained by XRD studies. Optical properties of the glass samples are studied before and after neutron at room temperature. The absorption spectra of all glasses indicated that there is a decrease in the optical band gap values due to the enhancement of the number of non-bridging oxygen (NBO) atoms with the addition of Eu 2 O 3 . Nuclear shielding properties of these have been investigated. The mass attenuation coefcients have been calculated using the XCOM program.
AbstractList Eu 3+ -doped borosilicate glasses were prepared by the melt-quenching method. Optical, physical and nuclear shielding properties of these glasses were studied. The FTIR measurements indicated that the continuous increase of europium concentration helped conversion of [BO 4 ] to [BO 3 ] groups. FTIR spectroscopy results were in good agreement with optical band energy gap, density and molar volume values revealing network modifications caused by europium ions in the glass structure. The amorphous natures of the samples were ascertained by XRD studies. Optical properties of the glass samples are studied before and after neutron at room temperature. The absorption spectra of all glasses indicated that there is a decrease in the optical band gap values due to the enhancement of the number of non-bridging oxygen (NBO) atoms with the addition of Eu 2 O 3 . Nuclear shielding properties of these have been investigated. The mass attenuation coefcients have been calculated using the XCOM program.
Eu3+-doped borosilicate glasses were prepared by the melt-quenching method. Optical, physical and nuclear shielding properties of these glasses were studied. The FTIR measurements indicated that the continuous increase of europium concentration helped conversion of [BO4] to [BO3] groups. FTIR spectroscopy results were in good agreement with optical band energy gap, density and molar volume values revealing network modifications caused by europium ions in the glass structure. The amorphous natures of the samples were ascertained by XRD studies. Optical properties of the glass samples are studied before and after neutron at room temperature. The absorption spectra of all glasses indicated that there is a decrease in the optical band gap values due to the enhancement of the number of non-bridging oxygen (NBO) atoms with the addition of Eu2O3. Nuclear shielding properties of these have been investigated. The mass attenuation coefcients have been calculated using the XCOM program.
Author Shaaban, Kh. S.
Abd-Allah, W. M.
Saudi, H. A.
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  surname: Saudi
  fullname: Saudi, H. A.
  organization: Department of Physics, Faculty of Science, Al-Azhar University (Girls’ Branch)
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  givenname: W. M.
  surname: Abd-Allah
  fullname: Abd-Allah, W. M.
  organization: Radiation Chemistry Department, National Center for Radiation Research and Technology, Egyptian Atomic Energy Authority(EAEA)
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  givenname: Kh. S.
  surname: Shaaban
  fullname: Shaaban, Kh. S.
  email: khamies1078@yahoo.com
  organization: Chemistry Department, Faculty of Science, Al - Azhar University
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SSID ssj0006438
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Snippet Eu 3+ -doped borosilicate glasses were prepared by the melt-quenching method. Optical, physical and nuclear shielding properties of these glasses were studied....
Eu3+-doped borosilicate glasses were prepared by the melt-quenching method. Optical, physical and nuclear shielding properties of these glasses were studied....
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StartPage 6963
SubjectTerms Absorption spectra
Atomic properties
Attenuation
Borosilicate glass
Characterization and Evaluation of Materials
Chemistry and Materials Science
Energy gap
Europium
Europium compounds
Fourier transforms
Infrared spectroscopy
Materials Science
Molar volume
Optical and Electronic Materials
Optical properties
Radioactive wastes
Room temperature
Shielding
Spectrum analysis
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Title Investigation of gamma and neutron shielding parameters for borosilicate glasses doped europium oxide for the immobilization of radioactive waste
URI https://link.springer.com/article/10.1007/s10854-020-03261-6
https://www.proquest.com/docview/2390461526
Volume 31
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