(2-Carbamoyl­ethyl)­bis­(di­methyl­glyoximato-N,N′)[(R)-1-(1-naphthyl)­ethyl­amine]­cobalt(III) ethanol solvate and bis­(di­methyl­glyoximato-N,N′)[2-(N-methyl­carbamoyl)­ethyl][methyl (S)-phenyl­alaninate-N]­cobalt(III)

• Published in: Acta crystallographica. Section C, Crystal structure communications Vol. 56; no. 9; pp. 1062 - 1064
• Main Authors: Ohgo, Yoshiki, Ohashi, Yuji, Hagiwara, Mieko, Shida, Mitsuru, Arai, Yoshifusa, Takeuchi, Seiji, Ohgo, Yoshiaki
• Format: Journal Article
• Language: English
• Published: 5 Abbey Square, Chester, Cheshire CH1 2HU, England Munksgaard International Publishers 01.09.2000; Blackwell
• Subjects: Chemistry; Condensed matter: structure, mechanical and thermal properties; Exact sciences and technology; General and physical chemistry; Inorganic compounds; Metal complexes; Photochemistry; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Physics; Structure of solids and liquids; crystallography; Structure of specific crystalline solids; Inorganic compounds; Transition element complexes; Photochemical reactions; Unsaturated cyclic compound; Molecular structure; Cobalt III Complexes; Organic ligand; Esters; XRD; Cetoxime; Experimental study; Condensed benzenic compound; Chemical reaction kinetics; Cobalt Organic compounds; Solvate; Complexes Mixed; Chemical preparation; Visible radiation; Bicyclic compound; Carboxamide; Dioxime; Primary amine; Crystal structure

The 2‐carbamoyl­ethyl and 2‐(methyl­carbamoyl)­ethyl groups in the title cobaloxime complexes, [Co(C4H7N2O2)2(C3H6­NO)(C12H13N)]·C2H6O and [Co(C4H7N2O2)2(C4H8NO)(C10H13NO2)], were isomerized to 1‐carbamoyl­ethyl and 1‐(methyl­carbamoyl)­ethyl groups, respectively, on exposure to visible light in the...