Pyrone hydroperoxide formation during the Maillard reaction and its implication in biological systems

• Published in: Biochimica et biophysica acta Vol. 1245; no. 3; pp. 278 - 284
• Main Authors: Lertsiri, Sittiwat, Fujimoto, Kenshiro, Miyazawa, Teruo
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 14.12.1995
• Subjects: Animals; Cattle; Chemiluminescence; Chromatography, High Pressure Liquid; Enolization; Glucose - metabolism; Glycation; Humans; Hydrogen peroxide; Hydrogen Peroxide - metabolism; Hydrogen-Ion Concentration; Luminescent Measurements; Maillard Reaction; Peroxides - metabolism; Pyrone hydroperoxide; Pyrones - metabolism; Serum Albumin, Bovine - metabolism; Maillard reaction; Chemiluminescence; Hydrogen peroxide; Enolization; Glycation; Pyrone hydroperoxide

Hydroperoxide formation during Maillard reaction (amino-carbonyl reaction) was investigated using luminol-chemiluminescence-high performance liquid chromatography (CL-HPLC). From the equimolar reaction mixture of I M β-alanine/ d-glucose in phosphate buffer (pH 8.0) at 95°C, two hydroperoxides and H...