Mordenite Nanorods Prepared by an Inexpensive Pyrrolidine‐based Mesoporogen for Alkane Hydroisomerization
We report the synthesis of hierarchical mordenite zeolite nanorods in one step using inexpensive mono‐quaternary ammonium N‐cetyl‐N‐methylpyrrolidinium (C16NMP) as mesoporogen to the synthesis gel. The presence of a small amount of C16NMP results in the formation of 0.6–1 μm rods‐like crystals orien...
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| Published in | ChemCatChem Vol. 11; no. 12; pp. 2803 - 2811 |
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| Abstract | We report the synthesis of hierarchical mordenite zeolite nanorods in one step using inexpensive mono‐quaternary ammonium N‐cetyl‐N‐methylpyrrolidinium (C16NMP) as mesoporogen to the synthesis gel. The presence of a small amount of C16NMP results in the formation of 0.6–1 μm rods‐like crystals oriented along the c‐axis with a high mesoporous volume (0.12 cm3 g−1) and external surface area (∼90 m2 g−1) compared to bulk mordenite. Acidity characterization shows that the presence of C16NMP during mordenite formation leads to a redistribution of aluminum in the zeolite framework: the amount of Brønsted acid sites in the side‐pockets (8MR channels) is increased at the expense of those in the 12MR main channels. As these latter acid sites are the ones involved in the conversion of alkene intermediates in bifunctional hydroconversion of alkanes, an optimized hierarchical mordenite prepared with C16NMP displays a more ideal hydrocracking selectivity than bulk MOR prepared solely with sodium.
Knock on wood! An inexpensive mono‐quaternary ammonium N‐cetyl‐N‐methylpyrrolidinium surfactant releases the potential of directly‐synthesized mordenite for alkane hydroisomerization |
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| AbstractList | We report the synthesis of hierarchical mordenite zeolite nanorods in one step using inexpensive mono‐quaternary ammonium N‐cetyl‐N‐methylpyrrolidinium (C16NMP) as mesoporogen to the synthesis gel. The presence of a small amount of C16NMP results in the formation of 0.6–1 μm rods‐like crystals oriented along the c‐axis with a high mesoporous volume (0.12 cm3 g−1) and external surface area (∼90 m2 g−1) compared to bulk mordenite. Acidity characterization shows that the presence of C16NMP during mordenite formation leads to a redistribution of aluminum in the zeolite framework: the amount of Brønsted acid sites in the side‐pockets (8MR channels) is increased at the expense of those in the 12MR main channels. As these latter acid sites are the ones involved in the conversion of alkene intermediates in bifunctional hydroconversion of alkanes, an optimized hierarchical mordenite prepared with C16NMP displays a more ideal hydrocracking selectivity than bulk MOR prepared solely with sodium.
Knock on wood! An inexpensive mono‐quaternary ammonium N‐cetyl‐N‐methylpyrrolidinium surfactant releases the potential of directly‐synthesized mordenite for alkane hydroisomerization We report the synthesis of hierarchical mordenite zeolite nanorods in one step using inexpensive mono‐quaternary ammonium N‐cetyl‐N‐methylpyrrolidinium (C16NMP) as mesoporogen to the synthesis gel. The presence of a small amount of C16NMP results in the formation of 0.6–1 μm rods‐like crystals oriented along the c‐axis with a high mesoporous volume (0.12 cm3 g−1) and external surface area (∼90 m2 g−1) compared to bulk mordenite. Acidity characterization shows that the presence of C16NMP during mordenite formation leads to a redistribution of aluminum in the zeolite framework: the amount of Brønsted acid sites in the side‐pockets (8MR channels) is increased at the expense of those in the 12MR main channels. As these latter acid sites are the ones involved in the conversion of alkene intermediates in bifunctional hydroconversion of alkanes, an optimized hierarchical mordenite prepared with C16NMP displays a more ideal hydrocracking selectivity than bulk MOR prepared solely with sodium. Abstract We report the synthesis of hierarchical mordenite zeolite nanorods in one step using inexpensive mono‐quaternary ammonium N‐cetyl‐N‐methylpyrrolidinium (C 16 NMP) as mesoporogen to the synthesis gel. The presence of a small amount of C 16 NMP results in the formation of 0.6–1 μm rods‐like crystals oriented along the c ‐axis with a high mesoporous volume (0.12 cm 3 g −1 ) and external surface area (∼90 m 2 g −1 ) compared to bulk mordenite. Acidity characterization shows that the presence of C 16 NMP during mordenite formation leads to a redistribution of aluminum in the zeolite framework: the amount of Brønsted acid sites in the side‐pockets (8MR channels) is increased at the expense of those in the 12MR main channels. As these latter acid sites are the ones involved in the conversion of alkene intermediates in bifunctional hydroconversion of alkanes, an optimized hierarchical mordenite prepared with C 16 NMP displays a more ideal hydrocracking selectivity than bulk MOR prepared solely with sodium. |
| Author | Romero Hidalgo, Douglas E. Kosinov, Nikolay Hensen, Emiel J. M. van Hoof, Arno J. F. Bolshakov, Aleksei |
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| Snippet | We report the synthesis of hierarchical mordenite zeolite nanorods in one step using inexpensive mono‐quaternary ammonium N‐cetyl‐N‐methylpyrrolidinium... Abstract We report the synthesis of hierarchical mordenite zeolite nanorods in one step using inexpensive mono‐quaternary ammonium... |
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| SubjectTerms | Alkanes Aluminum Channels Crystal structure hierarchical zeolite Hydrocracking mordenite Nanorods paraffin hydroconversion Selectivity Synthesis Zeolites |
| Title | Mordenite Nanorods Prepared by an Inexpensive Pyrrolidine‐based Mesoporogen for Alkane Hydroisomerization |
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