Use of Pistachio Shells as an Adsorbent for the Removal of Zinc(II) Ion
In this study, the removal of zinc(II) ion from an aqueous solution by pistachio shells (PS) is investigated. The dynamic behavior of the adsorption is examined on the effects of pH, adsorbent dosage, and contact time. The adsorption rates are determined quantitatively and simulated by the Lagergren...
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| Published in | Clean : soil, air, water Vol. 39; no. 5; pp. 475 - 481 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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WILEY-VCH Verlag
01.05.2011
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| Abstract | In this study, the removal of zinc(II) ion from an aqueous solution by pistachio shells (PS) is investigated. The dynamic behavior of the adsorption is examined on the effects of pH, adsorbent dosage, and contact time. The adsorption rates are determined quantitatively and simulated by the Lagergren first order, pseudo‐second order, Elovich, and intra‐particle diffusion kinetic models. The adsorption kinetic models are also tested for validity. The thermodynamic parameters, which are also deduced from adsorption experiments, are very useful in elucidating the nature of adsorption. The experimental results reveal that the optimum pH value and the contact time for the adsorption of Zn2+ onto PS are found as 6 and 10 min, respectively. According to these parameters, adsorption process follows the pseudo‐second order kinetic model with high correlation coefficients (R2 = 0.999). The obtained results demonstrate that PS is a reasonably effective adsorbent for the removal of Zn2+ from aqueous leachate of hazardous waste.
The present study investigates the adsorption of Zn2+ on pistachio shell (PS), including the effects of pH, adsorbent dosage, and contact time. The obtained results demonstrate that PS is a reasonably effective adsorbent for the removal of Zn2+ from aqueous leachate of hazardous waste. |
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| AbstractList | Abstract
In this study, the removal of zinc(II) ion from an aqueous solution by pistachio shells (PS) is investigated. The dynamic behavior of the adsorption is examined on the effects of pH, adsorbent dosage, and contact time. The adsorption rates are determined quantitatively and simulated by the Lagergren first order, pseudo‐second order, Elovich, and intra‐particle diffusion kinetic models. The adsorption kinetic models are also tested for validity. The thermodynamic parameters, which are also deduced from adsorption experiments, are very useful in elucidating the nature of adsorption. The experimental results reveal that the optimum pH value and the contact time for the adsorption of Zn
2+
onto PS are found as 6 and 10 min, respectively. According to these parameters, adsorption process follows the pseudo‐second order kinetic model with high correlation coefficients (
R
2
= 0.999). The obtained results demonstrate that PS is a reasonably effective adsorbent for the removal of Zn
2+
from aqueous leachate of hazardous waste. In this study, the removal of zinc(II) ion from an aqueous solution by pistachio shells (PS) is investigated. The dynamic behavior of the adsorption is examined on the effects of pH, adsorbent dosage, and contact time. The adsorption rates are determined quantitatively and simulated by the Lagergren first order, pseudo‐second order, Elovich, and intra‐particle diffusion kinetic models. The adsorption kinetic models are also tested for validity. The thermodynamic parameters, which are also deduced from adsorption experiments, are very useful in elucidating the nature of adsorption. The experimental results reveal that the optimum pH value and the contact time for the adsorption of Zn2+ onto PS are found as 6 and 10 min, respectively. According to these parameters, adsorption process follows the pseudo‐second order kinetic model with high correlation coefficients (R2 = 0.999). The obtained results demonstrate that PS is a reasonably effective adsorbent for the removal of Zn2+ from aqueous leachate of hazardous waste. The present study investigates the adsorption of Zn2+ on pistachio shell (PS), including the effects of pH, adsorbent dosage, and contact time. The obtained results demonstrate that PS is a reasonably effective adsorbent for the removal of Zn2+ from aqueous leachate of hazardous waste. |
| Author | Turan, Nurdan Gamze Mesci, Başak |
| Author_xml | – sequence: 1 givenname: Nurdan Gamze surname: Turan fullname: Turan, Nurdan Gamze email: gturan@omu.edu.tr organization: Engineering Faculty, Department of Environmental Engineering, Ondokuz Mayıs University, Kurupelit, Samsun, Turkey – sequence: 2 givenname: Başak surname: Mesci fullname: Mesci, Başak organization: Engineering Faculty, Department of Material Science and Engineering, Ondokuz Mayıs University, Kurupelit, Samsun, Turkey |
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| Cites_doi | 10.1016/j.jcis.2007.05.032 10.1016/S0043-1354(98)00475-8 10.1016/0960-8524(94)00123-I 10.1016/S0269-7491(98)00034-7 10.1016/j.cej.2007.06.035 10.1016/S0043-1354(03)00409-3 10.1016/j.desal.2007.01.206 10.1016/S0304-3894(02)00026-2 10.1016/j.jhazmat.2006.09.083 10.1016/j.jhazmat.2005.10.029 10.1021/cr60205a003 10.1016/j.jhazmat.2007.09.012 10.1016/j.desal.2007.01.221 10.1021/ac00183a024 10.1016/0166-6622(87)80259-7 10.1002/clen.200700203 10.1016/j.biortech.2005.02.010 10.1016/S0143-7208(01)00056-0 10.1016/S0960-8524(98)00196-5 10.2136/sssaj1980.03615995004400020013x 10.1016/S0304-386X(98)00065-6 10.1016/S0969-8043(97)00340-0 10.1016/j.jcis.2006.10.086 10.1016/j.jhazmat.2004.09.001 10.1016/j.desal.2007.07.008 10.1016/j.desal.2007.01.025 10.1016/j.cej.2008.01.019 10.2134/jeq1997.00472425002600050019x 10.1002/clen.200800187 10.1023/B:SCIE.0000013305.99473.cf 10.1002/ep.10456 10.1002/clen.200800194 10.1016/j.procbio.2004.11.007 10.1016/0269-7491(89)90120-6 10.1016/j.biortech.2005.02.027 10.1016/j.biortech.2007.01.015 10.1016/j.chemosphere.2005.04.068 |
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| Keywords | experimental studies models adsorption diffusion shells heavy metals hazardous wastes aqueous solutions thermodynamics Pistachio shell Heavy metal pH ions leachate kinetics particles correlation coefficient zinc |
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| Snippet | In this study, the removal of zinc(II) ion from an aqueous solution by pistachio shells (PS) is investigated. The dynamic behavior of the adsorption is... Abstract In this study, the removal of zinc(II) ion from an aqueous solution by pistachio shells (PS) is investigated. The dynamic behavior of the adsorption... |
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| SubjectTerms | Adsorption Earth sciences Earth, ocean, space Exact sciences and technology Heavy metal Hydrology Hydrology. Hydrogeology Kinetics Pistachio shell Zinc |
| Title | Use of Pistachio Shells as an Adsorbent for the Removal of Zinc(II) Ion |
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