Construction of MOF-derived plum-like NiCo@C composite with enhanced multi-polarization for high-efficiency microwave absorption

[Display omitted] Nowadays, facing the inevitable electromagnetic (EM) pollution caused by many electronic products, it is urgent to develop high-performance microwave absorbing materials. In particular, the bimetallic carbon-based composites derived from MOFs exhibit excellent microwave absorption...

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Published inJournal of colloid and interface science Vol. 609; pp. 224 - 234
Main Authors Cheng, Runrun, Wang, Yan, Di, Xiaochuang, Lu, Zhao, Wang, Ping, Ma, Mingliang, Ye, Jinrui
Format Journal Article
LanguageEnglish
Published United States Elsevier Inc 01.03.2022
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Abstract [Display omitted] Nowadays, facing the inevitable electromagnetic (EM) pollution caused by many electronic products, it is urgent to develop high-performance microwave absorbing materials. In particular, the bimetallic carbon-based composites derived from MOFs exhibit excellent microwave absorption potential due to their simple preparation, low cost, adjustable morphology and magnetoelectric synergy mechanism. In this work, we successfully prepared plum-like NiCo@C composite by simple solvothermal method and carbonization treatment, which displays strong absorption (-55.4 dB) and wide effective absorption band (EAB, 7.2 GHz) when the loading is 20 wt%. The plum-like structure greatly enriches the non-uniform interface and the structural anisotropy contributes to the dissipation of electromagnetic waves. At the same time, the band hybridization and magnetic coupling of NiCo@C contribute to the coordination of EM characteristics. Overall, this work proves the feasibility of NiCo@C hierarchical composite in the field of microwave absorbing, and provides insight for the development of high-performance absorbers.
AbstractList Nowadays, facing the inevitable electromagnetic (EM) pollution caused by many electronic products, it is urgent to develop high-performance microwave absorbing materials. In particular, the bimetallic carbon-based composites derived from MOFs exhibit excellent microwave absorption potential due to their simple preparation, low cost, adjustable morphology and magnetoelectric synergy mechanism. In this work, we successfully prepared plum-like NiCo@C composite by simple solvothermal method and carbonization treatment, which displays strong absorption (-55.4 dB) and wide effective absorption band (EAB, 7.2 GHz) when the loading is 20 wt%. The plum-like structure greatly enriches the non-uniform interface and the structural anisotropy contributes to the dissipation of electromagnetic waves. At the same time, the band hybridization and magnetic coupling of NiCo@C contribute to the coordination of EM characteristics. Overall, this work proves the feasibility of NiCo@C hierarchical composite in the field of microwave absorbing, and provides insight for the development of high-performance absorbers.
[Display omitted] Nowadays, facing the inevitable electromagnetic (EM) pollution caused by many electronic products, it is urgent to develop high-performance microwave absorbing materials. In particular, the bimetallic carbon-based composites derived from MOFs exhibit excellent microwave absorption potential due to their simple preparation, low cost, adjustable morphology and magnetoelectric synergy mechanism. In this work, we successfully prepared plum-like NiCo@C composite by simple solvothermal method and carbonization treatment, which displays strong absorption (-55.4 dB) and wide effective absorption band (EAB, 7.2 GHz) when the loading is 20 wt%. The plum-like structure greatly enriches the non-uniform interface and the structural anisotropy contributes to the dissipation of electromagnetic waves. At the same time, the band hybridization and magnetic coupling of NiCo@C contribute to the coordination of EM characteristics. Overall, this work proves the feasibility of NiCo@C hierarchical composite in the field of microwave absorbing, and provides insight for the development of high-performance absorbers.
Author Ye, Jinrui
Cheng, Runrun
Ma, Mingliang
Lu, Zhao
Wang, Ping
Di, Xiaochuang
Wang, Yan
Author_xml – sequence: 1
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  surname: Cheng
  fullname: Cheng, Runrun
  organization: School of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710021, PR China
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  givenname: Yan
  surname: Wang
  fullname: Wang, Yan
  email: wangyan287580632@126.com
  organization: School of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710021, PR China
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  givenname: Xiaochuang
  surname: Di
  fullname: Di, Xiaochuang
  organization: School of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710021, PR China
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  givenname: Zhao
  surname: Lu
  fullname: Lu, Zhao
  organization: School of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710021, PR China
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  givenname: Ping
  surname: Wang
  fullname: Wang, Ping
  organization: School of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710021, PR China
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  givenname: Mingliang
  surname: Ma
  fullname: Ma, Mingliang
  organization: School of Civil Engineering, Qingdao University of Technology, Qingdao 266033, PR China
– sequence: 7
  givenname: Jinrui
  surname: Ye
  fullname: Ye, Jinrui
  organization: Institute of Science and Technology of Beihang University, Beijing 100191, PR China
BackLink https://www.ncbi.nlm.nih.gov/pubmed/34896826$$D View this record in MEDLINE/PubMed
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Keywords Synergistic effect
Electromagnetic absorption
Metal-organic framework (MOF)
Plum-like NiCo@C
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Snippet [Display omitted] Nowadays, facing the inevitable electromagnetic (EM) pollution caused by many electronic products, it is urgent to develop high-performance...
Nowadays, facing the inevitable electromagnetic (EM) pollution caused by many electronic products, it is urgent to develop high-performance microwave absorbing...
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SubjectTerms Electromagnetic absorption
Metal-organic framework (MOF)
Plum-like NiCo@C
Synergistic effect
Title Construction of MOF-derived plum-like NiCo@C composite with enhanced multi-polarization for high-efficiency microwave absorption
URI https://dx.doi.org/10.1016/j.jcis.2021.11.197
https://www.ncbi.nlm.nih.gov/pubmed/34896826
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