Interaction of conducting polymers, polyaniline and polypyrrole, with organic dyes: polymer morphology control, dye adsorption and photocatalytic decomposition

Conducting polymers, such as polyaniline and polypyrrole, have frequently been discussed in the literature due to ease of preparation and high application potential. These polymers have been observed to interact with organic dyes because of the similarity in the conjugated molecular structure of bot...

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Published inChemical papers Vol. 74; no. 1; pp. 1 - 54
Main Author Stejskal, Jaroslav
Format Journal Article
LanguageEnglish
Published Cham Springer International Publishing 01.01.2020
Springer Nature B.V
Subjects
Adsorption
Biochemistry
Biotechnology
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Conducting polymers
Conductivity
Decomposition
Dyes
Electroactivity
Industrial Chemistry/Chemical Engineering
Materials Science
Medicinal Chemistry
Molecular structure
Morphology
Photocatalysis
Pollutants
Polyanilines
Polymers
Polypyrroles
Review
Water pollution
Adsorption
Conducting polymer
Water pollution treatment
Organic dyes
Photocatalytic decomposition
Nanotubes
Online AccessGet full text

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Abstract Conducting polymers, such as polyaniline and polypyrrole, have frequently been discussed in the literature due to ease of preparation and high application potential. These polymers have been observed to interact with organic dyes because of the similarity in the conjugated molecular structure of both moieties. The interaction manifests itself in three fundamental directions that have been so far treated separately. The first is represented by the conductivity enhancement and morphology control when using organic dyes as templates in polypyrrole preparation. The adsorption of dyes on conducting polymers is the second field oriented at the water pollution treatment. Finally, the photocatalytic decomposition of organic dyes aims at the similar environmental target. The last two applications do not require the presence of conductivity which, on the other hand, is a key parameter of conducting polymers. The future design of advanced adsorbents, however, has to exploit both the conductivity and electroactivity in the control of pollutant adsorption or degradation. For this reason, all these interactions and their practical impact are considered in the present review.
AbstractList Conducting polymers, such as polyaniline and polypyrrole, have frequently been discussed in the literature due to ease of preparation and high application potential. These polymers have been observed to interact with organic dyes because of the similarity in the conjugated molecular structure of both moieties. The interaction manifests itself in three fundamental directions that have been so far treated separately. The first is represented by the conductivity enhancement and morphology control when using organic dyes as templates in polypyrrole preparation. The adsorption of dyes on conducting polymers is the second field oriented at the water pollution treatment. Finally, the photocatalytic decomposition of organic dyes aims at the similar environmental target. The last two applications do not require the presence of conductivity which, on the other hand, is a key parameter of conducting polymers. The future design of advanced adsorbents, however, has to exploit both the conductivity and electroactivity in the control of pollutant adsorption or degradation. For this reason, all these interactions and their practical impact are considered in the present review.
Author Stejskal, Jaroslav
Author_xml – sequence: 1
  givenname: Jaroslav
  orcidid: 0000-0001-9350-9647
  surname: Stejskal
  fullname: Stejskal, Jaroslav
  email: stejskal@imc.cas.cz
  organization: Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic
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Water pollution treatment
Organic dyes
Photocatalytic decomposition
Nanotubes
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Snippet Conducting polymers, such as polyaniline and polypyrrole, have frequently been discussed in the literature due to ease of preparation and high application...
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SubjectTerms Adsorption
Biochemistry
Biotechnology
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Conducting polymers
Conductivity
Decomposition
Dyes
Electroactivity
Industrial Chemistry/Chemical Engineering
Materials Science
Medicinal Chemistry
Molecular structure
Morphology
Photocatalysis
Pollutants
Polyanilines
Polymers
Polypyrroles
Review
Water pollution
Title Interaction of conducting polymers, polyaniline and polypyrrole, with organic dyes: polymer morphology control, dye adsorption and photocatalytic decomposition
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