Experimental and theoretical insight into the transformation behaviors and risk assessment of Flutamide in UV/O3/PMS system

Nowadays, the widespread existence and potential adverse effects of emerging micropollutants in waters have prompted the search for effective treatment methods. In this study, the feasibility of UV/O3/PMS (peroxymonosulfate, HSO5−) method for the elimination of Flutamide (FLU) was comprehensively in...

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Published inJournal of cleaner production Vol. 375; p. 134167
Main Authors Li, Xiaofan, Wang, Ning, Lv, Guochun, Zhang, Yonglei, Chen, Yanqi, Liu, Xiaoyu, Sun, Xiaomin, Zhu, Fanping
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 15.11.2022
Subjects
Flutamide
Ozone
Peroxymonosulfate
Risk assessment
Transformation
Ozone
Transformation
Flutamide
Peroxymonosulfate
Risk assessment
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Abstract Nowadays, the widespread existence and potential adverse effects of emerging micropollutants in waters have prompted the search for effective treatment methods. In this study, the feasibility of UV/O3/PMS (peroxymonosulfate, HSO5−) method for the elimination of Flutamide (FLU) was comprehensively investigated, with focus on transformation behaviors and risk assessment. The results showed that the UV/O3/PMS method has excellent oxidation capability to FLU with the elimination efficiency of 83.7% within 40 min. In addition, the radical (·OH and SO4−·) oxidation occupies greater advantages in the initiation reaction pathways of FLU compared to non-radical (O3 and 1O2) oxidation. With the participation of H2O2, H2O, O2, and ·OH, eleven transformation products (TPs) are generated through hydroxylation, demethylation, and decomposition reactions. According to the risk assessment results, the toxicity of most TPs gradually decreased, but the residual developmental toxicity could not be ignored. Further, the environmental persistence of FLU was evaluated with respect to natural water and advanced oxidation processes. These findings could help to advance the fundamental understanding of emerging micropollutants in the aquatic environments, and provide a basis for their practical application in water treatment. [Display omitted] •The transformation mechanisms involved in UV/O3/PMS system were elucidated.•·OH and SO4−· are the major contributors to FLU degradation compared to O3 and 1O2.•FLU degradation was caused by hydroxylation, demethylation, and decomposition paths.•UV/O3/PMS is a promising treatment method for O3 or UV-refractory micropollutants.
AbstractList Nowadays, the widespread existence and potential adverse effects of emerging micropollutants in waters have prompted the search for effective treatment methods. In this study, the feasibility of UV/O3/PMS (peroxymonosulfate, HSO5−) method for the elimination of Flutamide (FLU) was comprehensively investigated, with focus on transformation behaviors and risk assessment. The results showed that the UV/O3/PMS method has excellent oxidation capability to FLU with the elimination efficiency of 83.7% within 40 min. In addition, the radical (·OH and SO4−·) oxidation occupies greater advantages in the initiation reaction pathways of FLU compared to non-radical (O3 and 1O2) oxidation. With the participation of H2O2, H2O, O2, and ·OH, eleven transformation products (TPs) are generated through hydroxylation, demethylation, and decomposition reactions. According to the risk assessment results, the toxicity of most TPs gradually decreased, but the residual developmental toxicity could not be ignored. Further, the environmental persistence of FLU was evaluated with respect to natural water and advanced oxidation processes. These findings could help to advance the fundamental understanding of emerging micropollutants in the aquatic environments, and provide a basis for their practical application in water treatment. [Display omitted] •The transformation mechanisms involved in UV/O3/PMS system were elucidated.•·OH and SO4−· are the major contributors to FLU degradation compared to O3 and 1O2.•FLU degradation was caused by hydroxylation, demethylation, and decomposition paths.•UV/O3/PMS is a promising treatment method for O3 or UV-refractory micropollutants.
ArticleNumber 134167
Author Zhang, Yonglei
Liu, Xiaoyu
Sun, Xiaomin
Lv, Guochun
Wang, Ning
Zhu, Fanping
Li, Xiaofan
Chen, Yanqi
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Keywords Ozone
Transformation
Flutamide
Peroxymonosulfate
Risk assessment
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Snippet Nowadays, the widespread existence and potential adverse effects of emerging micropollutants in waters have prompted the search for effective treatment...
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SubjectTerms Flutamide
Ozone
Peroxymonosulfate
Risk assessment
Transformation
Title Experimental and theoretical insight into the transformation behaviors and risk assessment of Flutamide in UV/O3/PMS system
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