Theoretical aspects of 2D electrochemical phase formation

• Published in: Journal of solid state electrochemistry Vol. 25; no. 2; pp. 689 - 694
• Main Authors: Isaev, Vladimir A., Grishenkova, Olga V., Zaikov, Yury P.
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.02.2021; Springer Nature B.V
• Subjects: Analytical Chemistry; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Crystallization; Current density; Electrochemistry; Energy Storage; Morphology; Nucleation; Original Paper; Physical Chemistry; 2D deposit layer; Electrodeposition; Nucleation; Growth

Two-dimensional electrochemical phase formation as a result of nucleation, growth, and overlap of disk-shaped nuclei of a new phase on the electrode surface is analyzed. This problem is considered based on the Kolmogorov-Johnson-Mehl-Avrami (KJMA) theory. General formulae applicable for any type of...