Thermally-responsive, nonflammable phosphonium ionic liquid electrolytes for lithium metal batteries: operating at 100 degrees celsius

Rechargeable batteries such as Li ion/Li metal batteries are widely used in the electronics market but the chemical instability of the electrolyte limits their use in more demanding environmental conditions such as in automotive, oil exploration, or mining applications. In this study, a series of al...

Full description

Saved in:
Bibliographic Details
Published inChemical science (Cambridge) Vol. 6; no. 11; pp. 6601 - 6606
Main Authors Lin, X, Kavian, R, Lu, Y, Hu, Q, Shao-Horn, Y, Grinstaff, M W
Format Journal Article
LanguageEnglish
Published England 01.11.2015
Subjects
Electric batteries
Electrolytes
Instability
Ionic liquids
Lithium
Lithium batteries
Rechargeable batteries
Stability
Online AccessGet full text

Cover

Abstract Rechargeable batteries such as Li ion/Li metal batteries are widely used in the electronics market but the chemical instability of the electrolyte limits their use in more demanding environmental conditions such as in automotive, oil exploration, or mining applications. In this study, a series of alkyl phosphonium ionic liquid electrolyte are described with high thermal stability and solubility for LiTFSI. A lithium metal battery (LMB) containing a tailored phosphonium ionic liquid/LiTFSI electrolyte operates at 100 °C with good specific capacities and cycling stability. Substantial capacity is maintained during 70 cycles or 30 days. Instant on-off battery operation is realized the significant temperature dependence of the electrolyte material, demonstrating the robustness and potential for use at high temperature.
AbstractList Rechargeable batteries such as Li ion/Li metal batteries are widely used in the electronics market but the chemical instability of the electrolyte limits their use in more demanding environmental conditions such as in automotive, oil exploration, or mining applications. In this study, a series of alkyl phosphonium ionic liquid electrolyte are described with high thermal stability and solubility for LiTFSI. A lithium metal battery (LMB) containing a tailored phosphonium ionic liquid/LiTFSI electrolyte operates at 100 °C with good specific capacities and cycling stability. Substantial capacity is maintained during 70 cycles or 30 days. Instant on-off battery operation is realized via the significant temperature dependence of the electrolyte material, demonstrating the robustness and potential for use at high temperature.
Rechargeable batteries such as Li ion/Li metal batteries are widely used in the electronics market but the chemical instability of the electrolyte limits their use in more demanding environmental conditions such as in automotive, oil exploration, or mining applications. In this study, a series of alkyl phosphonium ionic liquid electrolyte are described with high thermal stability and solubility for LiTFSI. A lithium metal battery (LMB) containing a tailored phosphonium ionic liquid/LiTFSI electrolyte operates at 100 °C with good specific capacities and cycling stability. Substantial capacity is maintained during 70 cycles or 30 days. Instant on-off battery operation is realized via the significant temperature dependence of the electrolyte material, demonstrating the robustness and potential for use at high temperature.
Rechargeable batteries such as Li ion/Li metal batteries are widely used in the electronics market but the chemical instability of the electrolyte limits their use in more demanding environmental conditions such as in automotive, oil exploration, or mining applications. In this study, a series of alkyl phosphonium ionic liquid electrolyte are described with high thermal stability and solubility for LiTFSI. A lithium metal battery (LMB) containing a tailored phosphonium ionic liquid/LiTFSI electrolyte operates at 100 °C with good specific capacities and cycling stability. Substantial capacity is maintained during 70 cycles or 30 days. Instant on-off battery operation is realized the significant temperature dependence of the electrolyte material, demonstrating the robustness and potential for use at high temperature.
Rechargeable batteries such as Li ion/Li metal batteries are widely used in the electronics market but the chemical instability of the electrolyte limits their use in more demanding environmental conditions such as in automotive, oil exploration, or mining applications. In this study, a series of alkyl phosphonium ionic liquid electrolyte are described with high thermal stability and solubility for LiTFSI. A lithium metal battery (LMB) containing a tailored phosphonium ionic liquid/LiTFSI electrolyte operates at 100 degree C with good specific capacities and cycling stability. Substantial capacity is maintained during 70 cycles or 30 days. Instant on-off battery operation is realized viathe significant temperature dependence of the electrolyte material, demonstrating the robustness and potential for use at high temperature.
Author Lu, Y
Shao-Horn, Y
Lin, X
Kavian, R
Hu, Q
Grinstaff, M W
Author_xml – sequence: 1
  givenname: X
  surname: Lin
  fullname: Lin, X
  email: mgrin@bu.edu
  organization: Departments of Chemistry and Biomedical Engineering , Boston University , Boston , MA 02215 , USA . Email: mgrin@bu.edu
– sequence: 2
  givenname: R
  surname: Kavian
  fullname: Kavian, R
  organization: Department of Materials Science and Engineering , Massachusetts Institute of Technology , Cambridge , MA 02139 , USA
– sequence: 3
  givenname: Y
  surname: Lu
  fullname: Lu, Y
  organization: Department of Materials Science and Engineering , Massachusetts Institute of Technology , Cambridge , MA 02139 , USA
– sequence: 4
  givenname: Q
  surname: Hu
  fullname: Hu, Q
  organization: Department of Materials Science and Engineering , Massachusetts Institute of Technology , Cambridge , MA 02139 , USA
– sequence: 5
  givenname: Y
  surname: Shao-Horn
  fullname: Shao-Horn, Y
  organization: Department of Materials Science and Engineering , Massachusetts Institute of Technology , Cambridge , MA 02139 , USA
– sequence: 6
  givenname: M W
  orcidid: 0000-0002-5453-3668
  surname: Grinstaff
  fullname: Grinstaff, M W
  email: mgrin@bu.edu
  organization: Departments of Chemistry and Biomedical Engineering , Boston University , Boston , MA 02215 , USA . Email: mgrin@bu.edu
BackLink https://www.ncbi.nlm.nih.gov/pubmed/28757963$$D View this record in MEDLINE/PubMed
BookMark eNqFkUtLxDAQx4MoPvfiB5AcRazm0aSpN1l8geBBPZe0ne5G0qabpMJ-AT-38bVXB4YZwm8emf8B2h7cAAgdU3JBCS8vGxEaQgVVegvtM5LTTApebm9yRvbQLIQ3koxzKlixi_aYKkRRSr6PPl6W4Htt7TrzEEY3BPMO5zgN6azue11bwOPSheSDmXpsUmiwNavJtBgsNNE7u44QcOd8eo_LL6qHqC2udYzgDYQr7EbwOpphgXXElBDcwsJDqmrABjOFI7TTaRtg9hsP0evtzcv8Pnt8unuYXz9mDRcyZqylkjIo0q8EEUpxQvOCNi1T0OWC5nUu664tWqaLloLUsuSkU0rXsoaS1JIfotOfvqN3qwlCrHoT0g5WD-CmUNGS5UpJlU71L1ooyRjjSiT07AdtvAvBQ1eN3vTarytKqi-Vqrl4nn-rdJ3gk9--U91Du0H_NOGfJ0GQJQ
CitedBy_id crossref_primary_10_1016_j_molliq_2023_122524
crossref_primary_10_1039_D1EE03292E
crossref_primary_10_1007_s00216_018_0878_0
crossref_primary_10_1016_j_jelechem_2018_09_038
crossref_primary_10_1016_j_electacta_2019_03_110
crossref_primary_10_1016_j_ensm_2020_07_018
crossref_primary_10_1016_j_jct_2018_02_013
crossref_primary_10_1615_AnnualRevHeatTransfer_2023049032
crossref_primary_10_1002_batt_202100025
crossref_primary_10_1016_j_egypro_2018_09_044
crossref_primary_10_1002_celc_202300009
crossref_primary_10_1016_j_nanoen_2019_103927
crossref_primary_10_1002_aenm_201702265
crossref_primary_10_1016_j_nanoen_2018_07_009
crossref_primary_10_1002_cjoc_202200588
crossref_primary_10_1002_anie_202308724
crossref_primary_10_1021_acsami_6b02620
crossref_primary_10_1016_j_ensm_2020_03_025
crossref_primary_10_1038_s41578_020_0218_9
crossref_primary_10_1016_j_colsurfa_2021_127848
crossref_primary_10_1007_s10973_023_12037_z
crossref_primary_10_1002_smm2_1185
crossref_primary_10_1016_j_ensm_2021_08_030
crossref_primary_10_1039_C7CS00464H
crossref_primary_10_1002_ange_202308724
crossref_primary_10_1007_s11426_021_1235_2
crossref_primary_10_1039_D1CP03549E
crossref_primary_10_1002_adma_202311912
crossref_primary_10_1016_j_ensm_2020_06_027
crossref_primary_10_1016_j_jpowsour_2016_08_119
crossref_primary_10_3390_molecules27154729
crossref_primary_10_1016_j_ssnmr_2017_05_004
crossref_primary_10_1021_acs_jpcc_7b01929
crossref_primary_10_1002_tcr_202200075
crossref_primary_10_1039_C6CS00012F
Cites_doi 10.1038/ncomms7362
10.1002/aenm.201400993
10.1016/j.jpowsour.2007.06.133
10.1016/j.jpowsour.2007.10.078
10.1038/nmat2297
10.1038/35104644
10.1038/424635b
10.1038/srep02572
10.1149/1.3208048
10.1002/(SICI)1521-4095(199804)10:6<439::AID-ADMA439>3.0.CO;2-I
10.1021/ja3091438
10.1038/nmat1368
10.1038/nmat3602
10.1021/cr030203g
10.1016/j.jpowsour.2009.06.089
10.1039/c0cs00081g
10.1016/j.ssi.2005.06.020
10.1149/2.056308jes
10.1126/science.1212741
10.1016/0167-2738(83)90083-8
10.1021/ja502133j
10.1149/2.022310jes
10.1016/j.jpowsour.2011.03.001
10.1039/c1ee01388b
10.1021/cr020731c
10.1002/anie.201307137
10.1038/451652a
10.1071/CH08558
10.1016/j.jpowsour.2006.02.018
10.1016/j.jpowsour.2009.08.089
10.1111/j.1467-9310.1992.tb00812.x
10.1039/c1ee01598b
10.1016/j.elecom.2007.07.003
10.1016/j.electacta.2006.03.016
10.1039/C3EE40795K
10.1038/nnano.2010.116
10.1016/0378-7753(91)80109-B
10.1016/j.electacta.2004.04.041
10.1287/mnsc.30.6.727
10.1021/am5033605
10.1002/anie.201405910
10.1021/ma3019624
10.1021/cm901452z
10.1073/pnas.1314615111
10.1149/1.2164726
10.1038/nmat2448
10.1149/1.1838106
10.1016/j.jpowsour.2014.01.005
10.1016/j.jpowsour.2009.05.048
10.1016/j.tca.2007.09.003
10.1002/adma.201003587
10.1016/S1388-2481(03)00137-1
10.1016/j.jpowsour.2009.11.048
10.1016/S0167-2738(02)00080-2
ContentType Journal Article
DBID NPM
AAYXX
CITATION
7SR
8BQ
8FD
JG9
7X8
DOI 10.1039/c5sc01518a
DatabaseName PubMed
CrossRef
Engineered Materials Abstracts
METADEX
Technology Research Database
Materials Research Database
MEDLINE - Academic
DatabaseTitle PubMed
CrossRef
Materials Research Database
Engineered Materials Abstracts
Technology Research Database
METADEX
MEDLINE - Academic
DatabaseTitleList MEDLINE - Academic
CrossRef
PubMed
Materials Research Database
Database_xml – sequence: 1
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 2041-6539
EndPage 6606
ExternalDocumentID 10_1039_C5SC01518A
28757963
Genre Journal Article
GroupedDBID -JG
0-7
0R~
53G
705
7~J
AAEMU
AAFWJ
AAIWI
AAJAE
AARTK
AAXHV
ABEMK
ABPDG
ABXOH
ACGFS
ACIWK
ADBBV
ADMRA
AEFDR
AENEX
AESAV
AFLYV
AGEGJ
AGRSR
AGSTE
AHGCF
AKBGW
ALMA_UNASSIGNED_HOLDINGS
ANBJS
ANUXI
AOIJS
APEMP
AUDPV
AZFZN
BCNDV
BLAPV
BSQNT
C6K
D0L
EE0
EF-
F5P
GROUPED_DOAJ
H13
HYE
HZ~
H~N
NPM
O-G
O9-
OK1
PGMZT
R7C
R7D
RAOCF
RCNCU
RNS
ROL
RPM
RRC
RSCEA
RVUXY
SKA
SKF
SKH
SKJ
SKM
SKR
SKZ
SLC
SLF
SLH
SMJ
AAWGC
AAYXX
ABASK
ABGFH
AETIL
AFPKN
AFVBQ
AHGXI
ANLMG
ASPBG
AVWKF
CAG
CITATION
COF
ECGLT
FEDTE
HVGLF
J3G
J3H
J3I
L-8
ROYLF
RPMJG
7SR
8BQ
8FD
JG9
7X8
ID FETCH-LOGICAL-c356t-2d1612e752050588301471cd28ef4514b46bfd7d2a7d1e6a6930f88ab6be90b63
ISSN 2041-6520
IngestDate Sat Oct 26 06:02:02 EDT 2024
Fri Oct 25 21:37:18 EDT 2024
Fri Aug 23 02:07:38 EDT 2024
Sat Nov 02 12:23:15 EDT 2024
IsDoiOpenAccess false
IsOpenAccess true
IsPeerReviewed true
IsScholarly true
Issue 11
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c356t-2d1612e752050588301471cd28ef4514b46bfd7d2a7d1e6a6930f88ab6be90b63
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ORCID 0000-0002-5453-3668
OpenAccessLink https://pubs.rsc.org/en/content/articlepdf/2015/sc/c5sc01518a
PMID 28757963
PQID 1786222385
PQPubID 23500
PageCount 6
ParticipantIDs proquest_miscellaneous_1924886803
proquest_miscellaneous_1786222385
crossref_primary_10_1039_C5SC01518A
pubmed_primary_28757963
PublicationCentury 2000
PublicationDate 2015-11-01
PublicationDateYYYYMMDD 2015-11-01
PublicationDate_xml – month: 11
  year: 2015
  text: 2015-11-01
  day: 01
PublicationDecade 2010
PublicationPlace England
PublicationPlace_xml – name: England
PublicationTitle Chemical science (Cambridge)
PublicationTitleAlternate Chem Sci
PublicationYear 2015
References Martin (C5SC01518A-(cit60)/*[position()=1]) 1994
Armand (C5SC01518A-(cit17)/*[position()=1]) 2009; 8
Xu (C5SC01518A-(cit15)/*[position()=1]) 2004; 104
Lu (C5SC01518A-(cit55)/*[position()=1]) 2015; 5
Hammami (C5SC01518A-(cit14)/*[position()=1]) 2003; 424
Chapman (C5SC01518A-(cit46)/*[position()=1]) 2012
Simon (C5SC01518A-(cit11)/*[position()=1]) 2008; 7
Shen (C5SC01518A-(cit49)/*[position()=1]) 2005; 1
Galiński (C5SC01518A-(cit19)/*[position()=1]) 2006; 51
Borges (C5SC01518A-(cit57)/*[position()=1]) 2013; 3
Scrosati (C5SC01518A-(cit7)/*[position()=1]) 2010; 195
Cheng (C5SC01518A-(cit13)/*[position()=1]) 2011; 23
Aricò (C5SC01518A-(cit2)/*[position()=1]) 2005; 4
Novák (C5SC01518A-(cit28)/*[position()=1]) 1991; 35
Matsui (C5SC01518A-(cit54)/*[position()=1]) 2008; 177
Quartarone (C5SC01518A-(cit31)/*[position()=1]) 2011; 40
Howlett (C5SC01518A-(cit42)/*[position()=1]) 2006; 153
Kroon (C5SC01518A-(cit38)/*[position()=1]) 2007; 465
Tarascon (C5SC01518A-(cit6)/*[position()=1]) 2001; 414
Lee (C5SC01518A-(cit12)/*[position()=1]) 2010; 5
Scrosati (C5SC01518A-(cit10)/*[position()=1]) 2011; 4
Matsumoto (C5SC01518A-(cit34)/*[position()=1]) 2006; 160
Fuller (C5SC01518A-(cit37)/*[position()=1]) 1997; 144
Qian (C5SC01518A-(cit51)/*[position()=1]) 2015; 6
Hu (C5SC01518A-(cit27)/*[position()=1]) 2011; 196
Wonga (C5SC01518A-(cit22)/*[position()=1]) 2014; 111
Garcia (C5SC01518A-(cit33)/*[position()=1]) 2004; 49
Whittingham (C5SC01518A-(cit45)/*[position()=1]) 2004; 104
Tsunashima (C5SC01518A-(cit41)/*[position()=1]) 2007; 9
Gebresilassie Eshetu (C5SC01518A-(cit26)/*[position()=1]) 2014; 53
Bhatt (C5SC01518A-(cit43)/*[position()=1]) 2013; 160
Khurana (C5SC01518A-(cit23)/*[position()=1]) 2014; 136
Etacheri (C5SC01518A-(cit8)/*[position()=1]) 2011; 4
Wongittharom (C5SC01518A-(cit35)/*[position()=1]) 2014; 6
Lewandowski (C5SC01518A-(cit30)/*[position()=1]) 2009; 194
Sakaebe (C5SC01518A-(cit32)/*[position()=1]) 2003; 5
Meyer (C5SC01518A-(cit16)/*[position()=1]) 1998; 10
Aricò (C5SC01518A-(cit4)/*[position()=1]) 2005; 4
Fergus (C5SC01518A-(cit44)/*[position()=1]) 2010; 195
Lin (C5SC01518A-(cit40)/*[position()=1]) 2012; 45
Paillard (C5SC01518A-(cit24)/*[position()=1]) 2009; 156
Nakagawa (C5SC01518A-(cit25)/*[position()=1]) 2007; 174
Dunn (C5SC01518A-(cit1)/*[position()=1]) 2011; 334
Armand (C5SC01518A-(cit18)/*[position()=1]) 1983; 9
Bouchet (C5SC01518A-(cit21)/*[position()=1]) 2013; 12
Feng (C5SC01518A-(cit53)/*[position()=1]) 2014; 255
Fraser (C5SC01518A-(cit39)/*[position()=1]) 2009; 62
Zmud (C5SC01518A-(cit59)/*[position()=1]) 1984; 30
Yoon (C5SC01518A-(cit50)/*[position()=1]) 2013; 160
Mun (C5SC01518A-(cit29)/*[position()=1]) 2009; 194
Goodenough (C5SC01518A-(cit9)/*[position()=1]) 2013; 135
Goodenough (C5SC01518A-(cit5)/*[position()=1]) 2010; 22
Zheng (C5SC01518A-(cit36)/*[position()=1]) 2005; 176
Aurbach (C5SC01518A-(cit56)/*[position()=1]) 2002; 148
Armand (C5SC01518A-(cit3)/*[position()=1]) 2008; 451
Rothwell (C5SC01518A-(cit58)/*[position()=1]) 1992; 22
Lu (C5SC01518A-(cit20)/*[position()=1]) 2014; 53
Xu (C5SC01518A-(cit52)/*[position()=1]) 2014; 7
Hensley (C5SC01518A-(cit48)/*[position()=1]) 1998
References_xml – volume: 6
  start-page: 6362
  year: 2015
  ident: C5SC01518A-(cit51)/*[position()=1]
  publication-title: Nat. Commun.
  doi: 10.1038/ncomms7362
  contributor:
    fullname: Qian
– volume: 5
  start-page: 1400993
  year: 2015
  ident: C5SC01518A-(cit55)/*[position()=1]
  publication-title: Adv. Energy Mater.
  doi: 10.1002/aenm.201400993
  contributor:
    fullname: Lu
– volume: 174
  start-page: 1021
  year: 2007
  ident: C5SC01518A-(cit25)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2007.06.133
  contributor:
    fullname: Nakagawa
– volume: 177
  start-page: 184
  year: 2008
  ident: C5SC01518A-(cit54)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2007.10.078
  contributor:
    fullname: Matsui
– volume: 7
  start-page: 845
  year: 2008
  ident: C5SC01518A-(cit11)/*[position()=1]
  publication-title: Nat. Mater.
  doi: 10.1038/nmat2297
  contributor:
    fullname: Simon
– volume: 414
  start-page: 359
  year: 2001
  ident: C5SC01518A-(cit6)/*[position()=1]
  publication-title: Nature
  doi: 10.1038/35104644
  contributor:
    fullname: Tarascon
– volume: 424
  start-page: 635
  year: 2003
  ident: C5SC01518A-(cit14)/*[position()=1]
  publication-title: Nature
  doi: 10.1038/424635b
  contributor:
    fullname: Hammami
– start-page: 42
  volume-title: Oilfield Review
  year: 1998
  ident: C5SC01518A-(cit48)/*[position()=1]
  contributor:
    fullname: Hensley
– volume: 3
  start-page: 2572
  year: 2013
  ident: C5SC01518A-(cit57)/*[position()=1]
  publication-title: Sci. Rep.
  doi: 10.1038/srep02572
  contributor:
    fullname: Borges
– volume: 156
  start-page: A891
  year: 2009
  ident: C5SC01518A-(cit24)/*[position()=1]
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1.3208048
  contributor:
    fullname: Paillard
– volume: 10
  start-page: 439
  year: 1998
  ident: C5SC01518A-(cit16)/*[position()=1]
  publication-title: Adv. Mater.
  doi: 10.1002/(SICI)1521-4095(199804)10:6<439::AID-ADMA439>3.0.CO;2-I
  contributor:
    fullname: Meyer
– volume: 135
  start-page: 1167
  year: 2013
  ident: C5SC01518A-(cit9)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja3091438
  contributor:
    fullname: Goodenough
– volume: 4
  start-page: 366
  year: 2005
  ident: C5SC01518A-(cit2)/*[position()=1]
  publication-title: Nat. Mater.
  doi: 10.1038/nmat1368
  contributor:
    fullname: Aricò
– volume: 12
  start-page: 450
  year: 2013
  ident: C5SC01518A-(cit21)/*[position()=1]
  publication-title: Nat. Mater.
  doi: 10.1038/nmat3602
  contributor:
    fullname: Bouchet
– volume: 104
  start-page: 4303
  year: 2004
  ident: C5SC01518A-(cit15)/*[position()=1]
  publication-title: Chem. Rev.
  doi: 10.1021/cr030203g
  contributor:
    fullname: Xu
– volume: 194
  start-page: 601
  year: 2009
  ident: C5SC01518A-(cit30)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2009.06.089
  contributor:
    fullname: Lewandowski
– volume: 40
  start-page: 2525
  year: 2011
  ident: C5SC01518A-(cit31)/*[position()=1]
  publication-title: Chem. Soc. Rev.
  doi: 10.1039/c0cs00081g
  contributor:
    fullname: Quartarone
– volume: 176
  start-page: 2219
  year: 2005
  ident: C5SC01518A-(cit36)/*[position()=1]
  publication-title: Solid State Ionics
  doi: 10.1016/j.ssi.2005.06.020
  contributor:
    fullname: Zheng
– volume: 160
  start-page: A1171
  year: 2013
  ident: C5SC01518A-(cit43)/*[position()=1]
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/2.056308jes
  contributor:
    fullname: Bhatt
– volume: 334
  start-page: 928
  year: 2011
  ident: C5SC01518A-(cit1)/*[position()=1]
  publication-title: Science
  doi: 10.1126/science.1212741
  contributor:
    fullname: Dunn
– volume: 9
  start-page: 745
  year: 1983
  ident: C5SC01518A-(cit18)/*[position()=1]
  publication-title: Solid State Ionics
  doi: 10.1016/0167-2738(83)90083-8
  contributor:
    fullname: Armand
– volume: 136
  start-page: 7395
  year: 2014
  ident: C5SC01518A-(cit23)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja502133j
  contributor:
    fullname: Khurana
– volume: 160
  start-page: A1629
  year: 2013
  ident: C5SC01518A-(cit50)/*[position()=1]
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/2.022310jes
  contributor:
    fullname: Yoon
– volume: 196
  start-page: 5604
  year: 2011
  ident: C5SC01518A-(cit27)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2011.03.001
  contributor:
    fullname: Hu
– volume: 4
  start-page: 3287
  year: 2011
  ident: C5SC01518A-(cit10)/*[position()=1]
  publication-title: Energy Environ. Sci.
  doi: 10.1039/c1ee01388b
  contributor:
    fullname: Scrosati
– volume: 104
  start-page: 4271
  year: 2004
  ident: C5SC01518A-(cit45)/*[position()=1]
  publication-title: Chem. Rev.
  doi: 10.1021/cr020731c
  contributor:
    fullname: Whittingham
– volume: 53
  start-page: 488
  year: 2014
  ident: C5SC01518A-(cit20)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201307137
  contributor:
    fullname: Lu
– volume: 451
  start-page: 652
  year: 2008
  ident: C5SC01518A-(cit3)/*[position()=1]
  publication-title: Nature
  doi: 10.1038/451652a
  contributor:
    fullname: Armand
– volume: 62
  start-page: 309
  year: 2009
  ident: C5SC01518A-(cit39)/*[position()=1]
  publication-title: Aust. J. Chem.
  doi: 10.1071/CH08558
  contributor:
    fullname: Fraser
– volume: 160
  start-page: 1308
  year: 2006
  ident: C5SC01518A-(cit34)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2006.02.018
  contributor:
    fullname: Matsumoto
– volume: 195
  start-page: 939
  year: 2010
  ident: C5SC01518A-(cit44)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2009.08.089
  contributor:
    fullname: Fergus
– volume: 22
  start-page: 221
  year: 1992
  ident: C5SC01518A-(cit58)/*[position()=1]
  publication-title: R&D Management
  doi: 10.1111/j.1467-9310.1992.tb00812.x
  contributor:
    fullname: Rothwell
– volume: 4
  start-page: 3243
  year: 2011
  ident: C5SC01518A-(cit8)/*[position()=1]
  publication-title: Energy Environ. Sci.
  doi: 10.1039/c1ee01598b
  contributor:
    fullname: Etacheri
– volume: 9
  start-page: 2353
  year: 2007
  ident: C5SC01518A-(cit41)/*[position()=1]
  publication-title: Electrochem. Commun.
  doi: 10.1016/j.elecom.2007.07.003
  contributor:
    fullname: Tsunashima
– volume: 51
  start-page: 5567
  year: 2006
  ident: C5SC01518A-(cit19)/*[position()=1]
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2006.03.016
  contributor:
    fullname: Galiński
– volume: 7
  start-page: 513
  year: 2014
  ident: C5SC01518A-(cit52)/*[position()=1]
  publication-title: Energy Environ. Sci.
  doi: 10.1039/C3EE40795K
  contributor:
    fullname: Xu
– volume: 5
  start-page: 531
  year: 2010
  ident: C5SC01518A-(cit12)/*[position()=1]
  publication-title: Nat. Nanotechnol.
  doi: 10.1038/nnano.2010.116
  contributor:
    fullname: Lee
– volume: 35
  start-page: 235
  year: 1991
  ident: C5SC01518A-(cit28)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/0378-7753(91)80109-B
  contributor:
    fullname: Novák
– volume: 49
  start-page: 4583
  year: 2004
  ident: C5SC01518A-(cit33)/*[position()=1]
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2004.04.041
  contributor:
    fullname: Garcia
– volume: 30
  start-page: 727
  year: 1984
  ident: C5SC01518A-(cit59)/*[position()=1]
  publication-title: Manag. Sci.
  doi: 10.1287/mnsc.30.6.727
  contributor:
    fullname: Zmud
– volume: 6
  start-page: 17564
  year: 2014
  ident: C5SC01518A-(cit35)/*[position()=1]
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/am5033605
  contributor:
    fullname: Wongittharom
– volume: 4
  start-page: 366
  year: 2005
  ident: C5SC01518A-(cit4)/*[position()=1]
  publication-title: Nat. Mater.
  doi: 10.1038/nmat1368
  contributor:
    fullname: Aricò
– volume: 53
  start-page: 13342
  year: 2014
  ident: C5SC01518A-(cit26)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201405910
  contributor:
    fullname: Gebresilassie Eshetu
– volume: 45
  start-page: 9500
  year: 2012
  ident: C5SC01518A-(cit40)/*[position()=1]
  publication-title: Macromolecules
  doi: 10.1021/ma3019624
  contributor:
    fullname: Lin
– volume: 22
  start-page: 587
  year: 2010
  ident: C5SC01518A-(cit5)/*[position()=1]
  publication-title: Chem. Mater.
  doi: 10.1021/cm901452z
  contributor:
    fullname: Goodenough
– volume: 1
  start-page: 89
  year: 2005
  ident: C5SC01518A-(cit49)/*[position()=1]
  publication-title: Pet. Explor. Dev.
  contributor:
    fullname: Shen
– volume: 111
  start-page: 3327
  year: 2014
  ident: C5SC01518A-(cit22)/*[position()=1]
  publication-title: Proc. Natl. Acad. Sci. U. S. A.
  doi: 10.1073/pnas.1314615111
  contributor:
    fullname: Wonga
– volume: 153
  start-page: A595
  year: 2006
  ident: C5SC01518A-(cit42)/*[position()=1]
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1.2164726
  contributor:
    fullname: Howlett
– volume: 8
  start-page: 621
  year: 2009
  ident: C5SC01518A-(cit17)/*[position()=1]
  publication-title: Nat. Mater.
  doi: 10.1038/nmat2448
  contributor:
    fullname: Armand
– volume: 144
  start-page: 3881
  year: 1997
  ident: C5SC01518A-(cit37)/*[position()=1]
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1.1838106
  contributor:
    fullname: Fuller
– volume: 255
  start-page: 294
  year: 2014
  ident: C5SC01518A-(cit53)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2014.01.005
  contributor:
    fullname: Feng
– volume-title: IEEE International Conference on Nanotechnology, 12th
  year: 2012
  ident: C5SC01518A-(cit46)/*[position()=1]
  contributor:
    fullname: Chapman
– volume: 194
  start-page: 1068
  year: 2009
  ident: C5SC01518A-(cit29)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2009.05.048
  contributor:
    fullname: Mun
– volume: 465
  start-page: 40
  year: 2007
  ident: C5SC01518A-(cit38)/*[position()=1]
  publication-title: Thermochim. Acta
  doi: 10.1016/j.tca.2007.09.003
  contributor:
    fullname: Kroon
– volume: 23
  start-page: 1695
  year: 2011
  ident: C5SC01518A-(cit13)/*[position()=1]
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201003587
  contributor:
    fullname: Cheng
– volume-title: Managing Innovation and Entrepreneurship in Technology-based Firms
  year: 1994
  ident: C5SC01518A-(cit60)/*[position()=1]
  contributor:
    fullname: Martin
– volume: 5
  start-page: 594
  year: 2003
  ident: C5SC01518A-(cit32)/*[position()=1]
  publication-title: Electrochem. Commun.
  doi: 10.1016/S1388-2481(03)00137-1
  contributor:
    fullname: Sakaebe
– volume: 195
  start-page: 2419
  year: 2010
  ident: C5SC01518A-(cit7)/*[position()=1]
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2009.11.048
  contributor:
    fullname: Scrosati
– volume: 148
  start-page: 405
  year: 2002
  ident: C5SC01518A-(cit56)/*[position()=1]
  publication-title: Solid State Ionics
  doi: 10.1016/S0167-2738(02)00080-2
  contributor:
    fullname: Aurbach
SSID ssj0000331527
Score 2.3765128
Snippet Rechargeable batteries such as Li ion/Li metal batteries are widely used in the electronics market but the chemical instability of the electrolyte limits their...
SourceID proquest
crossref
pubmed
SourceType Aggregation Database
Index Database
StartPage 6601
SubjectTerms Electric batteries
Electrolytes
Instability
Ionic liquids
Lithium
Lithium batteries
Rechargeable batteries
Stability
Title Thermally-responsive, nonflammable phosphonium ionic liquid electrolytes for lithium metal batteries: operating at 100 degrees celsius
URI https://www.ncbi.nlm.nih.gov/pubmed/28757963
https://search.proquest.com/docview/1786222385
https://search.proquest.com/docview/1924886803
Volume 6
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3Lb9MwGLfKdoALGu8ymIzgVgKJEzsJt6naNKFqCGhROEVx7GiR-mJNJg1x5u_ms2OnRipocIkay3USfz99L38PhF4BbsKU8wK4X5F4EYhIj1NJPUJFFMi0VLXvVLTFOTubRe8zmg0GP9zskoa_Kb_vzCv5H6rCGNBVZcn-A2X7RWEAfgN94QoUhutNaQx8dT6_9i5NqOuV9k8uVa5HsVjotKj1xWqjAtDrdjGqdb-bef2trcXIdMCZXyvXq4o2BI38Qs1aSJUhyXXlzbqLmVutVfFlndDYjALfHwkJhjr8rwTZWhvngS14YGsQ2JQhdVBsU8Mcz8OkK1-Q9Ty_uKrNqVQ_pd2KCI09dfvR9VQE1KTs9QyN-FHgMUq6cxjpjnUFjSxHZi7wAoe9MmbWk_aW7RQDgD-gXUk3JbxGkDjCzh7wn3_IT2eTST49yaa30D4BNgX8cf_Tl1n2tffR-WFouv72r24r3Ibp2-3yv-s0fzBUtMIyPUB3jaWBjzvY3EMDubyPbo9tg78H6Ocu-LzGLniwAx6swYM78GAXPBjAgw14sAYP7sHzDvfQwUWDATrYQAcb6DxEs9OT6fjMM205vDKkrPGIACuByBh2A9TnJFFGeRyUgiSyikD_5hHjlYgFKWIRSFaoZptVkhSccZn6nIWP0B58inyCcCqiipUJ2ORBGVEaFxWNeMgEqLmRgGWH6KXd2HzdVV_JddREmOZj-nmst_94iF7YPc9hC9WJV7GUq3aTBzEY7KAAJ_Qvc1ICQowlfjhEjzuC9c8iqt0DiKinN3jCIbqzBf0ztNdctvI5KKwNP9KOniODrl-r0ZqQ
link.rule.ids 315,783,787,867,27936,27937
linkProvider Royal Society of Chemistry
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Thermally-responsive%2C+nonflammable+phosphonium+ionic+liquid+electrolytes+for+lithium+metal+batteries%3A+operating+at+100+degrees+celsius&rft.jtitle=Chemical+science+%28Cambridge%29&rft.au=Lin%2C+X&rft.au=Kavian%2C+R&rft.au=Lu%2C+Y&rft.au=Hu%2C+Q&rft.date=2015-11-01&rft.issn=2041-6520&rft.eissn=2041-6539&rft.volume=6&rft.issue=11&rft.spage=6601&rft.epage=6606&rft_id=info:doi/10.1039%2Fc5sc01518a&rft.externalDBID=NO_FULL_TEXT
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2041-6520&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2041-6520&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2041-6520&client=summon