Raman spectroscopic study of the structural change of uranium–thorium-mixed oxides before and after oxidation
UO 2 pellets doped with 1, 5 and 10 mol% Th before and after oxidation were analyzed by using Raman spectroscopy to investigate the Th doping effect on the structural changes during oxidation of UO 2 . While the Raman spectra of all sample pellets showed a close-to-perfect fluorite structure before...
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| Published in | Journal of radioanalytical and nuclear chemistry Vol. 316; no. 3; pp. 1295 - 1300 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cham
Springer International Publishing
01.06.2018
Springer Springer Nature B.V |
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| Abstract | UO
2
pellets doped with 1, 5 and 10 mol% Th before and after oxidation were analyzed by using Raman spectroscopy to investigate the Th doping effect on the structural changes during oxidation of UO
2
. While the Raman spectra of all sample pellets showed a close-to-perfect fluorite structure before oxidation, those of oxidized (U
1−
y
Th
y
)O
2+
x
(0.03 ≤
x
≤ 0.06) pellets showed distinct defect structures after oxidation at 1150 °C with CO/CO
2
= 0.001. The increasing relative ratio of first-order longitudinal optical modes of (U
1−
y
Th
y
)O
2+
x
with increasing doping levels should represent the defect structure due to the Th doping effect. |
|---|---|
| AbstractList | UO.sub.2 pellets doped with 1, 5 and 10 mol% Th before and after oxidation were analyzed by using Raman spectroscopy to investigate the Th doping effect on the structural changes during oxidation of UO.sub.2. While the Raman spectra of all sample pellets showed a close-to-perfect fluorite structure before oxidation, those of oxidized (U.sub.1-yTh.sub.y)O.sub.2+x (0.03 [less than or equal to] x [less than or equal to] 0.06) pellets showed distinct defect structures after oxidation at 1150 °C with CO/CO.sub.2 = 0.001. The increasing relative ratio of first-order longitudinal optical modes of (U.sub.1-yTh.sub.y)O.sub.2+x with increasing doping levels should represent the defect structure due to the Th doping effect. UO2 pellets doped with 1, 5 and 10 mol% Th before and after oxidation were analyzed by using Raman spectroscopy to investigate the Th doping effect on the structural changes during oxidation of UO2. While the Raman spectra of all sample pellets showed a close-to-perfect fluorite structure before oxidation, those of oxidized (U1−yThy)O2+x (0.03 ≤ x ≤ 0.06) pellets showed distinct defect structures after oxidation at 1150 °C with CO/CO2 = 0.001. The increasing relative ratio of first-order longitudinal optical modes of (U1−yThy)O2+x with increasing doping levels should represent the defect structure due to the Th doping effect. UO 2 pellets doped with 1, 5 and 10 mol% Th before and after oxidation were analyzed by using Raman spectroscopy to investigate the Th doping effect on the structural changes during oxidation of UO 2 . While the Raman spectra of all sample pellets showed a close-to-perfect fluorite structure before oxidation, those of oxidized (U 1− y Th y )O 2+ x (0.03 ≤ x ≤ 0.06) pellets showed distinct defect structures after oxidation at 1150 °C with CO/CO 2 = 0.001. The increasing relative ratio of first-order longitudinal optical modes of (U 1− y Th y )O 2+ x with increasing doping levels should represent the defect structure due to the Th doping effect. |
| Audience | Academic |
| Author | Kim, Jong-Yun Lee, Jeongmook Lim, Sang Ho Youn, Young-Sang Kim, Jandee |
| Author_xml | – sequence: 1 givenname: Jeongmook surname: Lee fullname: Lee, Jeongmook organization: Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute – sequence: 2 givenname: Jandee surname: Kim fullname: Kim, Jandee organization: Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute – sequence: 3 givenname: Young-Sang surname: Youn fullname: Youn, Young-Sang organization: Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute – sequence: 4 givenname: Jong-Yun surname: Kim fullname: Kim, Jong-Yun organization: Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Department of Radiochemistry & Nuclear Nonproliferation, University of Science & Technology – sequence: 5 givenname: Sang Ho orcidid: 0000-0002-8583-5677 surname: Lim fullname: Lim, Sang Ho email: slim@kaeri.re.kr organization: Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Department of Radiochemistry & Nuclear Nonproliferation, University of Science & Technology |
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| Cites_doi | 10.1016/j.jnucmat.2014.02.029 10.1002/jrs.5092 10.1103/PhysRevB.73.085118 10.1080/18811248.1983.9733384 10.1016/j.apsusc.2016.10.010 10.1016/S0022-3115(03)00248-4 10.1002/jrs.3054 10.1016/j.cattod.2006.07.040 10.1016/j.jnucmat.2010.08.005 10.1016/0022-3115(87)90274-1 10.1111/jace.13559 10.1016/j.jnucmat.2010.01.004 10.1039/JR9540003324 10.1016/0022-3115(66)90073-0 10.1039/C6CP03800J 10.1111/j.1151-2916.1988.tb05919.x 10.1149/2.047403jes 10.1038/nmat4226 10.1038/nmat4224 10.1039/b925495a 10.1016/S0022-3115(00)00035-0 10.1016/0022-3115(82)90138-6 10.1021/ic301100c 10.4028/www.scientific.net/KEM.277-279.654 10.2113/gselements.2.6.343 10.1366/13-07172 10.1016/j.jnucmat.2017.01.004 10.1366/0003702904417472 10.1016/0022-3115(85)90460-X 10.1016/j.tca.2017.04.014 10.1016/0022-5088(90)90465-V |
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| Keywords | Oxidation Defect structure Uranium oxide Raman spectroscopy Actinide oxide Mixed oxide |
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| References | Kleykamp (CR1) 1985; 131 Ewing (CR4) 2015; 14 Graves (CR20) 1990; 44 Ugajin (CR30) 1983; 20 Begun, Haire, Wilmarth, Peterson (CR21) 1990; 162 Ha, Kim, Park, Kim (CR15) 2005; 277–279 Desgranges, Baldinozzi, Simon, Guimbretière, Canizares (CR27) 2012; 43 Elorrieta, Bonales, Rodríguez-Villagra, Baonza, Cobos (CR28) 2016; 18 Talip, Peuget, Magnin, Berardo, Valot, Vauchy (CR10) 2017; 48 Talip, Wiss, Raison, Paillier, Manara, Somers (CR6) 2015; 98 Cakir, Eloirdi, Huber, Konings, Gouder (CR16) 2017; 393 Bruno, Ewing (CR2) 2006; 2 Jégou, Caraballo, De Bonfils, Broudic, Peuget, Vercouter (CR18) 2010; 399 Lindemer, Sutton (CR31) 1988; 71 Konings, Wiss, Beneš (CR3) 2015; 14 Livneh, Sterer (CR23) 2006; 73 He, Shoesmith (CR25) 2010; 12 Böhler, Welland, Prieur, Cakir, Vitova, Pruessmann (CR9) 2014; 448 Rao, Bhagat, Salke, Kumar (CR11) 2014; 68 Anderson, Edgington, Roberts, Wait (CR12) 1954 Razdan, Shoesmith (CR5) 2013; 161 Cohen, Berman (CR13) 1966; 18 Anthonysamy, Joseph, Gnanasekaran, Rao (CR14) 2000; 280 Allen, Butler (CR19) 1987; 144 Pai, Sahu, Pai, Jain, Jagannath (CR17) 2017; 654 Ugajin (CR29) 1982; 110 Desgranges, Pontillon, Matheron, Marcet, Simon, Guimbretière (CR24) 2012; 51 Jégou, Caraballo, Peuget, Roudil, Desgranges, Magnin (CR8) 2010; 405 Lee, Kim, Youn, Kim, Ha, Kim (CR7) 2017; 486 Manara, Renker (CR22) 2003; 321 Senanayake, Waterhouse, Chan, Madey, Mullins, Idriss (CR26) 2007; 120 J Lee (5829_CR7) 2017; 486 M Ugajin (5829_CR30) 1983; 20 TB Lindemer (5829_CR31) 1988; 71 JS Anderson (5829_CR12) 1954 SD Senanayake (5829_CR26) 2007; 120 JM Elorrieta (5829_CR28) 2016; 18 T Livneh (5829_CR23) 2006; 73 R Böhler (5829_CR9) 2014; 448 D Manara (5829_CR22) 2003; 321 RC Ewing (5829_CR4) 2015; 14 S Anthonysamy (5829_CR14) 2000; 280 Z Talip (5829_CR10) 2017; 48 I Cohen (5829_CR13) 1966; 18 RV Pai (5829_CR17) 2017; 654 M Razdan (5829_CR5) 2013; 161 Z Talip (5829_CR6) 2015; 98 RJM Konings (5829_CR3) 2015; 14 PR Graves (5829_CR20) 1990; 44 H He (5829_CR25) 2010; 12 Y-K Ha (5829_CR15) 2005; 277–279 C Jégou (5829_CR8) 2010; 405 GM Begun (5829_CR21) 1990; 162 H Kleykamp (5829_CR1) 1985; 131 L Desgranges (5829_CR27) 2012; 43 GC Allen (5829_CR19) 1987; 144 L Desgranges (5829_CR24) 2012; 51 J Bruno (5829_CR2) 2006; 2 R Rao (5829_CR11) 2014; 68 M Ugajin (5829_CR29) 1982; 110 P Cakir (5829_CR16) 2017; 393 C Jégou (5829_CR18) 2010; 399 |
| References_xml | – volume: 448 start-page: 330 year: 2014 end-page: 339 ident: CR9 article-title: Recent advances in the study of the UO –PuO phase diagram at high temperatures publication-title: J Nucl Mater doi: 10.1016/j.jnucmat.2014.02.029 contributor: fullname: Pruessmann – volume: 48 start-page: 765 year: 2017 end-page: 772 ident: CR10 article-title: Raman microspectroscopic studies of unirradiated homogeneous (U Pu )O : the effects of Pu content, non-stoichiometry, self-radiation damage and secondary phases publication-title: J Raman Spectrosc doi: 10.1002/jrs.5092 contributor: fullname: Vauchy – volume: 73 start-page: 85118 year: 2006 ident: CR23 article-title: Effect of pressure on the resonant multiphonon Raman scattering in UO publication-title: Phys Rev B doi: 10.1103/PhysRevB.73.085118 contributor: fullname: Sterer – volume: 20 start-page: 228 year: 1983 end-page: 236 ident: CR30 article-title: Measurements of O/U ratio and oxygen potential for UO (0 ≤ ≤ 0.1) publication-title: J Nucl Sci Technol doi: 10.1080/18811248.1983.9733384 contributor: fullname: Ugajin – volume: 393 start-page: 204 year: 2017 end-page: 211 ident: CR16 article-title: Thorium effect on the oxidation of uranium: photoelectron spectroscopy (XPS/UPS) and cyclic voltammetry (CV) investigation on (U Th )O ( = 0 to 1) thin films publication-title: Appl Surf Sci doi: 10.1016/j.apsusc.2016.10.010 contributor: fullname: Gouder – volume: 321 start-page: 233 year: 2003 end-page: 237 ident: CR22 article-title: Raman spectra of stoichiometric and hyperstoichiometric uranium dioxide publication-title: J Nucl Mater doi: 10.1016/S0022-3115(03)00248-4 contributor: fullname: Renker – volume: 43 start-page: 455 year: 2012 end-page: 458 ident: CR27 article-title: Raman spectrum of U O : a new interpretation of damage lines in UO publication-title: J Raman Spectrosc doi: 10.1002/jrs.3054 contributor: fullname: Canizares – volume: 120 start-page: 151 year: 2007 end-page: 157 ident: CR26 article-title: The reactions of water vapour on the surfaces of stoichiometric and reduced uranium dioxide: a high resolution XPS study publication-title: Catal Today doi: 10.1016/j.cattod.2006.07.040 contributor: fullname: Idriss – volume: 405 start-page: 235 year: 2010 end-page: 243 ident: CR8 article-title: Raman spectroscopy characterization of actinide oxides (U Pu )O : resistance to oxidation by the laser beam and examination of defects publication-title: J Nucl Mater doi: 10.1016/j.jnucmat.2010.08.005 contributor: fullname: Magnin – volume: 144 start-page: 17 year: 1987 end-page: 19 ident: CR19 article-title: Characterisation of uranium oxides by micro-Raman spectroscopy publication-title: J Nucl Mater doi: 10.1016/0022-3115(87)90274-1 contributor: fullname: Butler – volume: 98 start-page: 2278 year: 2015 end-page: 2285 ident: CR6 article-title: Raman and X-ray studies of uranium–lanthanum-mixed oxides before and after air oxidation publication-title: J Am Ceram Soc doi: 10.1111/jace.13559 contributor: fullname: Somers – volume: 399 start-page: 68 year: 2010 end-page: 80 ident: CR18 article-title: Oxidizing dissolution of spent MOX47 fuel subjected to water radiolysis: solution chemistry and surface characterization by Raman spectroscopy publication-title: J Nucl Mater doi: 10.1016/j.jnucmat.2010.01.004 contributor: fullname: Vercouter – year: 1954 ident: CR12 article-title: The oxides of uranium. Part IV. The system UO –ThO –O publication-title: J Chem Soc doi: 10.1039/JR9540003324 contributor: fullname: Wait – volume: 18 start-page: 77 year: 1966 end-page: 107 ident: CR13 article-title: A metallographic and X-ray study of the limits of oxygen solubility in the UO -ThO system publication-title: J Nucl Mater doi: 10.1016/0022-3115(66)90073-0 contributor: fullname: Berman – volume: 18 start-page: 28209 year: 2016 end-page: 28216 ident: CR28 article-title: A detailed Raman and X-ray study of UO oxides and related structure transitions publication-title: Phys Chem Chem Phys doi: 10.1039/C6CP03800J contributor: fullname: Cobos – volume: 71 start-page: 553 year: 1988 end-page: 561 ident: CR31 article-title: Study of nonstoichiometry of (U Gd O ) publication-title: J Am Ceram Soc doi: 10.1111/j.1151-2916.1988.tb05919.x contributor: fullname: Sutton – volume: 161 start-page: H105 year: 2013 end-page: H113 ident: CR5 article-title: Influence of trivalent-dopants on the structural and electrochemical properties of uranium dioxide (UO ) publication-title: J Electrochem Soc doi: 10.1149/2.047403jes contributor: fullname: Shoesmith – volume: 14 start-page: 252 year: 2015 end-page: 257 ident: CR4 article-title: Long-term storage of spent nuclear fuel publication-title: Nat Mater doi: 10.1038/nmat4226 contributor: fullname: Ewing – volume: 14 start-page: 247 year: 2015 end-page: 252 ident: CR3 article-title: Predicting material release during a nuclear reactor accident publication-title: Nat Mater doi: 10.1038/nmat4224 contributor: fullname: Beneš – volume: 12 start-page: 8108 year: 2010 end-page: 8117 ident: CR25 article-title: Raman spectroscopic studies of defect structures and phase transition in hyper-stoichiometric UO publication-title: Phys Chem Chem Phys doi: 10.1039/b925495a contributor: fullname: Shoesmith – volume: 280 start-page: 25 year: 2000 end-page: 32 ident: CR14 article-title: Studies on the kinetics of oxidation of urania ± thoria solid solutions in air publication-title: J Nucl Mater doi: 10.1016/S0022-3115(00)00035-0 contributor: fullname: Rao – volume: 110 start-page: 140 year: 1982 end-page: 146 ident: CR29 article-title: Oxygen potentials of (Th, U)O solid solutions publication-title: J Nucl Mater doi: 10.1016/0022-3115(82)90138-6 contributor: fullname: Ugajin – volume: 51 start-page: 9147 year: 2012 end-page: 9149 ident: CR24 article-title: Miscibility gap in the U–Nd–O phase diagram: a new approach of nuclear oxides in the environment? publication-title: Inorg Chem doi: 10.1021/ic301100c contributor: fullname: Guimbretière – volume: 277–279 start-page: 654 year: 2005 end-page: 659 ident: CR15 article-title: Effect of a tetravalnet dopant, Th on the oxidation of uranium dioxide publication-title: Key Eng Mater doi: 10.4028/www.scientific.net/KEM.277-279.654 contributor: fullname: Kim – volume: 2 start-page: 343 year: 2006 end-page: 349 ident: CR2 article-title: Spent nuclear fuel publication-title: Elements doi: 10.2113/gselements.2.6.343 contributor: fullname: Ewing – volume: 68 start-page: 44 year: 2014 end-page: 48 ident: CR11 article-title: Raman spectroscopic investigation of thorium dioxide-uranium dioxide (ThO –UO ) fuel materials publication-title: Appl Spectrosc doi: 10.1366/13-07172 contributor: fullname: Kumar – volume: 486 start-page: 216 year: 2017 end-page: 221 ident: CR7 article-title: Raman study on structure of U Gd O ( = 0.005, 0.01, 0.03, 0.05 and 0.1) solid solutions publication-title: J Nucl Mater doi: 10.1016/j.jnucmat.2017.01.004 contributor: fullname: Kim – volume: 44 start-page: 1665 year: 1990 end-page: 1667 ident: CR20 article-title: Raman microprobe spectroscopy of uranium dioxide single crystals and ion implanted polycrystals publication-title: Appl Spectrosc doi: 10.1366/0003702904417472 contributor: fullname: Graves – volume: 131 start-page: 221 year: 1985 end-page: 246 ident: CR1 article-title: The chemical state of the fission products in oxide fuels publication-title: J Nucl Mater doi: 10.1016/0022-3115(85)90460-X contributor: fullname: Kleykamp – volume: 654 start-page: 8 year: 2017 end-page: 17 ident: CR17 article-title: Oxidation and thermo physical studies of non-stoichiometric thorium uranium oxides prepared by gel combustion method publication-title: Thermochim Acta doi: 10.1016/j.tca.2017.04.014 contributor: fullname: Jagannath – volume: 162 start-page: 129 year: 1990 end-page: 133 ident: CR21 article-title: Raman spectra of some actinide dioxides and of EuF publication-title: J Less Common Met doi: 10.1016/0022-5088(90)90465-V contributor: fullname: Peterson – volume: 405 start-page: 235 year: 2010 ident: 5829_CR8 publication-title: J Nucl Mater doi: 10.1016/j.jnucmat.2010.08.005 contributor: fullname: C Jégou – volume: 12 start-page: 8108 year: 2010 ident: 5829_CR25 publication-title: Phys Chem Chem Phys doi: 10.1039/b925495a contributor: fullname: H He – volume: 399 start-page: 68 year: 2010 ident: 5829_CR18 publication-title: J Nucl Mater doi: 10.1016/j.jnucmat.2010.01.004 contributor: fullname: C Jégou – volume: 277–279 start-page: 654 year: 2005 ident: 5829_CR15 publication-title: Key Eng Mater doi: 10.4028/www.scientific.net/KEM.277-279.654 contributor: fullname: Y-K Ha – volume: 144 start-page: 17 year: 1987 ident: 5829_CR19 publication-title: J Nucl Mater doi: 10.1016/0022-3115(87)90274-1 contributor: fullname: GC Allen – volume: 44 start-page: 1665 year: 1990 ident: 5829_CR20 publication-title: Appl Spectrosc doi: 10.1366/0003702904417472 contributor: fullname: PR Graves – volume: 162 start-page: 129 year: 1990 ident: 5829_CR21 publication-title: J Less Common Met doi: 10.1016/0022-5088(90)90465-V contributor: fullname: GM Begun – volume: 73 start-page: 85118 year: 2006 ident: 5829_CR23 publication-title: Phys Rev B doi: 10.1103/PhysRevB.73.085118 contributor: fullname: T Livneh – volume: 486 start-page: 216 year: 2017 ident: 5829_CR7 publication-title: J Nucl Mater doi: 10.1016/j.jnucmat.2017.01.004 contributor: fullname: J Lee – volume: 43 start-page: 455 year: 2012 ident: 5829_CR27 publication-title: J Raman Spectrosc doi: 10.1002/jrs.3054 contributor: fullname: L Desgranges – year: 1954 ident: 5829_CR12 publication-title: J Chem Soc doi: 10.1039/JR9540003324 contributor: fullname: JS Anderson – volume: 68 start-page: 44 year: 2014 ident: 5829_CR11 publication-title: Appl Spectrosc doi: 10.1366/13-07172 contributor: fullname: R Rao – volume: 280 start-page: 25 year: 2000 ident: 5829_CR14 publication-title: J Nucl Mater doi: 10.1016/S0022-3115(00)00035-0 contributor: fullname: S Anthonysamy – volume: 321 start-page: 233 year: 2003 ident: 5829_CR22 publication-title: J Nucl Mater doi: 10.1016/S0022-3115(03)00248-4 contributor: fullname: D Manara – volume: 120 start-page: 151 year: 2007 ident: 5829_CR26 publication-title: Catal Today doi: 10.1016/j.cattod.2006.07.040 contributor: fullname: SD Senanayake – volume: 2 start-page: 343 year: 2006 ident: 5829_CR2 publication-title: Elements doi: 10.2113/gselements.2.6.343 contributor: fullname: J Bruno – volume: 18 start-page: 77 year: 1966 ident: 5829_CR13 publication-title: J Nucl Mater doi: 10.1016/0022-3115(66)90073-0 contributor: fullname: I Cohen – volume: 71 start-page: 553 year: 1988 ident: 5829_CR31 publication-title: J Am Ceram Soc doi: 10.1111/j.1151-2916.1988.tb05919.x contributor: fullname: TB Lindemer – volume: 161 start-page: H105 year: 2013 ident: 5829_CR5 publication-title: J Electrochem Soc doi: 10.1149/2.047403jes contributor: fullname: M Razdan – volume: 98 start-page: 2278 year: 2015 ident: 5829_CR6 publication-title: J Am Ceram Soc doi: 10.1111/jace.13559 contributor: fullname: Z Talip – volume: 393 start-page: 204 year: 2017 ident: 5829_CR16 publication-title: Appl Surf Sci doi: 10.1016/j.apsusc.2016.10.010 contributor: fullname: P Cakir – volume: 51 start-page: 9147 year: 2012 ident: 5829_CR24 publication-title: Inorg Chem doi: 10.1021/ic301100c contributor: fullname: L Desgranges – volume: 131 start-page: 221 year: 1985 ident: 5829_CR1 publication-title: J Nucl Mater doi: 10.1016/0022-3115(85)90460-X contributor: fullname: H Kleykamp – volume: 20 start-page: 228 year: 1983 ident: 5829_CR30 publication-title: J Nucl Sci Technol doi: 10.1080/18811248.1983.9733384 contributor: fullname: M Ugajin – volume: 14 start-page: 247 year: 2015 ident: 5829_CR3 publication-title: Nat Mater doi: 10.1038/nmat4224 contributor: fullname: RJM Konings – volume: 654 start-page: 8 year: 2017 ident: 5829_CR17 publication-title: Thermochim Acta doi: 10.1016/j.tca.2017.04.014 contributor: fullname: RV Pai – volume: 18 start-page: 28209 year: 2016 ident: 5829_CR28 publication-title: Phys Chem Chem Phys doi: 10.1039/C6CP03800J contributor: fullname: JM Elorrieta – volume: 448 start-page: 330 year: 2014 ident: 5829_CR9 publication-title: J Nucl Mater doi: 10.1016/j.jnucmat.2014.02.029 contributor: fullname: R Böhler – volume: 110 start-page: 140 year: 1982 ident: 5829_CR29 publication-title: J Nucl Mater doi: 10.1016/0022-3115(82)90138-6 contributor: fullname: M Ugajin – volume: 48 start-page: 765 year: 2017 ident: 5829_CR10 publication-title: J Raman Spectrosc doi: 10.1002/jrs.5092 contributor: fullname: Z Talip – volume: 14 start-page: 252 year: 2015 ident: 5829_CR4 publication-title: Nat Mater doi: 10.1038/nmat4226 contributor: fullname: RC Ewing |
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pellets doped with 1, 5 and 10 mol% Th before and after oxidation were analyzed by using Raman spectroscopy to investigate the Th doping effect on the... UO.sub.2 pellets doped with 1, 5 and 10 mol% Th before and after oxidation were analyzed by using Raman spectroscopy to investigate the Th doping effect on the... UO2 pellets doped with 1, 5 and 10 mol% Th before and after oxidation were analyzed by using Raman spectroscopy to investigate the Th doping effect on the... |
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| SubjectTerms | Carbon dioxide Chemistry Chemistry and Materials Science Diagnostic Radiology Doping Fluorite Hadrons Heavy Ions Inorganic Chemistry Mixed oxides Nuclear Chemistry Nuclear energy Nuclear Physics Oxidation Oxidation-reduction reactions Oxides Pellets Physical Chemistry Raman spectra Raman spectroscopy Spectrum analysis Thorium Uranium Uranium dioxide |
| Title | Raman spectroscopic study of the structural change of uranium–thorium-mixed oxides before and after oxidation |
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