Access to new Janus head ligands: linking sulfur diimides and phosphanes for hemilabile tripodal scorpionates

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 40; no. 8; pp. 1662 - 1671
• Main Authors: Meinholz, Margret M, Pandey, Sushil K, Deuerlein, Stephan M, Stalke, Dietmar
• Format: Journal Article
• Language: English
• Published: England 01.01.2011
• Subjects: Diimide; Janus; Ligands; Lithium; Magnesium; Nitrogen atoms; Sulfur

Reactions of lithium dialkyl/phenyl phosphanylmethylides, RR'PCH(X)Li (R, R' = Me, Et, Ph and R = Me, R' = Ph; X = H or Me), with sulfur diimides S(NR'')2 (R'' = (t)Bu or SiMe3) in an equimolar ratio yielded Janus head complexes with the structural motif [Li{RR...