Effects of filtered cathodic vacuum arc deposition (FCVAD) conditions on photovoltaic TiO2 films

Titanium dioxide (TiO2) films for photovoltaic applications were synthesized using filtered cathodic vacuum arc deposition (FCVAD) technique. Various deposition conditions were tested for an optimal film formation. The conditions included the oxygen (O2) pressure which was varied from a base pressur...

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Published inApplied surface science Vol. 310; pp. 266 - 271
Main Authors ARAMWIT, C, INTARASIRI, S, BOOTKUL, D, TIPPAWAN, U, SUPSERMPOL, B, SEANPHINIT, N, RUANGKUL, W, YU, L. D
Format Conference Proceeding Journal Article
LanguageEnglish
Published Amsterdam Elsevier 01.08.2014
Subjects
Annealing
Arc deposition
Atomic force microscopy
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Deposition
Exact sciences and technology
Photovoltaic cells
Physics
Scanning electron microscopy
Solar cells
Titanium dioxide
Oxygen
Inorganic compounds
Anatase
Film
Oxygen (O
Transition element compounds
)
pressure
Titanium oxide
Titanium dioxide (TiO
Vacuum deposition
Filtered cathodic vacuum arc deposition (FCVAD)
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Abstract Titanium dioxide (TiO2) films for photovoltaic applications were synthesized using filtered cathodic vacuum arc deposition (FCVAD) technique. Various deposition conditions were tested for an optimal film formation. The conditions included the oxygen (O2) pressure which was varied from a base pressure 10-5 to 10-4, 10-3, 10-2 and 10-1 Torr, sample holder bias varied using 0 or -250V, deposition time varied from 10, 20 to 30min, and deposition distance varied from 1 to 3cm. The deposited films were also annealed and compared with unannealed ones. The films under various conditions were characterized using optical microscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDS) and Raman spectroscopy techniques. The film transparency increased and thickness decreased to a nanoscale with increasing of the O2 pressure. The transparent deposited films contained stoichiometric titanium and oxygen under the medium O2 pressure. The as-deposited films were TiO2 containing some rutile but no anatase which needed annealing to form.
AbstractList Titanium dioxide (TiO2) films for photovoltaic applications were synthesized using filtered cathodic vacuum arc deposition (FCVAD) technique. Various deposition conditions were tested for an optimal film formation. The conditions included the oxygen (O2) pressure which was varied from a base pressure 10-5 to 10-4, 10-3, 10-2 and 10-1 Torr, sample holder bias varied using 0 or -250V, deposition time varied from 10, 20 to 30min, and deposition distance varied from 1 to 3cm. The deposited films were also annealed and compared with unannealed ones. The films under various conditions were characterized using optical microscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDS) and Raman spectroscopy techniques. The film transparency increased and thickness decreased to a nanoscale with increasing of the O2 pressure. The transparent deposited films contained stoichiometric titanium and oxygen under the medium O2 pressure. The as-deposited films were TiO2 containing some rutile but no anatase which needed annealing to form.
Author INTARASIRI, S
SEANPHINIT, N
BOOTKUL, D
YU, L. D
ARAMWIT, C
TIPPAWAN, U
SUPSERMPOL, B
RUANGKUL, W
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Keywords Oxygen
Inorganic compounds
Anatase
Film
Oxygen (O
Transition element compounds
)
pressure
Titanium oxide
Titanium dioxide (TiO
Vacuum deposition
Filtered cathodic vacuum arc deposition (FCVAD)
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Snippet Titanium dioxide (TiO2) films for photovoltaic applications were synthesized using filtered cathodic vacuum arc deposition (FCVAD) technique. Various...
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SubjectTerms Annealing
Arc deposition
Atomic force microscopy
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Deposition
Exact sciences and technology
Photovoltaic cells
Physics
Scanning electron microscopy
Solar cells
Titanium dioxide
Title Effects of filtered cathodic vacuum arc deposition (FCVAD) conditions on photovoltaic TiO2 films
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