Adsorption of Rare Earth Ce3+ and Pr3+ Ions by Hydrophobic Ionic Liquid

This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic pr...

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Published inJournal of environmental and public health Vol. 2021; pp. 1 - 8
Main Authors Devanathan, R., Balaji, G. L., Lakshmipathy, R.
Format Journal Article
LanguageEnglish
Published New York Hindawi 29.05.2021
Hindawi Limited
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Abstract This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic process of sequestration of ions. The Arrhenius activation energies are found to be between 5–40 kJ, suggesting the physisorption process of ions onto IL. The present process is understood to be rapid and exothermic in nature according to thermodynamic experiments. The loading capacity was found to be 179.3 g L−1 and 141.5 g L−1, respectively, for Ce (III) and Pr (III) ions at pH 5 with a contact time of 30 min and dose being 0.1 g L−1. The higher uptake capacity is attributed to the presence of a highly electronegative fluorine atom in the IL. These results highlight the potential application of IL in the sequestration of Ce (III) and Pr (III) ions from any water sources.
AbstractList This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic process of sequestration of ions. The Arrhenius activation energies are found to be between 5–40 kJ, suggesting the physisorption process of ions onto IL. The present process is understood to be rapid and exothermic in nature according to thermodynamic experiments. The loading capacity was found to be 179.3 g L−1 and 141.5 g L−1, respectively, for Ce (III) and Pr (III) ions at pH 5 with a contact time of 30 min and dose being 0.1 g L−1. The higher uptake capacity is attributed to the presence of a highly electronegative fluorine atom in the IL. These results highlight the potential application of IL in the sequestration of Ce (III) and Pr (III) ions from any water sources.
This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic process of sequestration of ions. The Arrhenius activation energies are found to be between 5–40 kJ, suggesting the physisorption process of ions onto IL. The present process is understood to be rapid and exothermic in nature according to thermodynamic experiments. The loading capacity was found to be 179.3 g L −1 and 141.5 g L −1 , respectively, for Ce (III) and Pr (III) ions at pH 5 with a contact time of 30 min and dose being 0.1 g L −1 . The higher uptake capacity is attributed to the presence of a highly electronegative fluorine atom in the IL. These results highlight the potential application of IL in the sequestration of Ce (III) and Pr (III) ions from any water sources.
Author Devanathan, R.
Balaji, G. L.
Lakshmipathy, R.
AuthorAffiliation 1 Department of Chemistry, Thanthai Hans Roever College, Perambalur 621212, Tamilnadu, India
2 School of Advanced Science and Languages, VIT Bhopal University, Bhopal 466114, Madhya Pradesh, India
3 Department of Chemistry, KCG College of Technology, Karapakkam, Chennai 600097, Tamilnadu, India
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Copyright © 2021 R. Devanathan et al. This is an open access article distributed under the Creative Commons Attribution License (the “License”), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. https://creativecommons.org/licenses/by/4.0
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SubjectTerms Adsorbents
Adsorption
Cerium
D-Galactose
Efficiency
Electronegativity
Fluorine
Galactose
Hydrophobicity
Ionic liquids
Ions
Nanomaterials
Optimization
Praseodymium
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Title Adsorption of Rare Earth Ce3+ and Pr3+ Ions by Hydrophobic Ionic Liquid
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