Adsorption of Rare Earth Ce3+ and Pr3+ Ions by Hydrophobic Ionic Liquid
This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic pr...
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Published in | Journal of environmental and public health Vol. 2021; pp. 1 - 8 |
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Language | English |
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29.05.2021
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Abstract | This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic process of sequestration of ions. The Arrhenius activation energies are found to be between 5–40 kJ, suggesting the physisorption process of ions onto IL. The present process is understood to be rapid and exothermic in nature according to thermodynamic experiments. The loading capacity was found to be 179.3 g L−1 and 141.5 g L−1, respectively, for Ce (III) and Pr (III) ions at pH 5 with a contact time of 30 min and dose being 0.1 g L−1. The higher uptake capacity is attributed to the presence of a highly electronegative fluorine atom in the IL. These results highlight the potential application of IL in the sequestration of Ce (III) and Pr (III) ions from any water sources. |
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AbstractList | This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic process of sequestration of ions. The Arrhenius activation energies are found to be between 5–40 kJ, suggesting the physisorption process of ions onto IL. The present process is understood to be rapid and exothermic in nature according to thermodynamic experiments. The loading capacity was found to be 179.3 g L−1 and 141.5 g L−1, respectively, for Ce (III) and Pr (III) ions at pH 5 with a contact time of 30 min and dose being 0.1 g L−1. The higher uptake capacity is attributed to the presence of a highly electronegative fluorine atom in the IL. These results highlight the potential application of IL in the sequestration of Ce (III) and Pr (III) ions from any water sources. This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic process of sequestration of ions. The Arrhenius activation energies are found to be between 5–40 kJ, suggesting the physisorption process of ions onto IL. The present process is understood to be rapid and exothermic in nature according to thermodynamic experiments. The loading capacity was found to be 179.3 g L −1 and 141.5 g L −1 , respectively, for Ce (III) and Pr (III) ions at pH 5 with a contact time of 30 min and dose being 0.1 g L −1 . The higher uptake capacity is attributed to the presence of a highly electronegative fluorine atom in the IL. These results highlight the potential application of IL in the sequestration of Ce (III) and Pr (III) ions from any water sources. |
Author | Devanathan, R. Balaji, G. L. Lakshmipathy, R. |
AuthorAffiliation | 1 Department of Chemistry, Thanthai Hans Roever College, Perambalur 621212, Tamilnadu, India 2 School of Advanced Science and Languages, VIT Bhopal University, Bhopal 466114, Madhya Pradesh, India 3 Department of Chemistry, KCG College of Technology, Karapakkam, Chennai 600097, Tamilnadu, India |
AuthorAffiliation_xml | – name: 1 Department of Chemistry, Thanthai Hans Roever College, Perambalur 621212, Tamilnadu, India – name: 3 Department of Chemistry, KCG College of Technology, Karapakkam, Chennai 600097, Tamilnadu, India – name: 2 School of Advanced Science and Languages, VIT Bhopal University, Bhopal 466114, Madhya Pradesh, India |
Author_xml | – sequence: 1 givenname: R. orcidid: 0000-0002-5414-2528 surname: Devanathan fullname: Devanathan, R. organization: Department of ChemistryThanthai Hans Roever CollegePerambalur 621212TamilnaduIndia – sequence: 2 givenname: G. L. orcidid: 0000-0003-2737-7046 surname: Balaji fullname: Balaji, G. L. organization: Department of ChemistryThanthai Hans Roever CollegePerambalur 621212TamilnaduIndia – sequence: 3 givenname: R. orcidid: 0000-0003-0407-5934 surname: Lakshmipathy fullname: Lakshmipathy, R. organization: Department of ChemistryKCG College of TechnologyKarapakkamChennai 600097TamilnaduIndiakcgcollege.com |
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Cites_doi | 10.1007/s10953-009-9402-7 10.1080/19443994.2015.1072064 10.1016/j.talanta.2011.04.023 10.1016/j.desal.2010.08.011 10.1007/s00706-007-0727-x 10.1007/s10967-013-2560-5 10.1016/j.colcom.2021.100380 10.1016/j.molstruc.2021.130148 10.1016/j.cej.2010.10.046 10.1080/0144235X.2015.1088217 10.1016/j.marchem.2014.01.006 10.1002/ep.12948 10.1016/s0003-2670(03)00660-3 10.1016/j.mineng.2013.10.021 10.1039/ja9961100815 10.1016/j.xinn.2021.100076 10.1016/j.molliq.2015.11.060 |
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Copyright | Copyright © 2021 R. Devanathan et al. Copyright © 2021 R. Devanathan et al. This is an open access article distributed under the Creative Commons Attribution License (the “License”), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. https://creativecommons.org/licenses/by/4.0 Copyright © 2021 R. Devanathan et al. 2021 |
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References | 11 12 13 14 15 16 17 18 19 K. Veronese (2) 2015 C. E. Harland (20) 1994 3 4 5 6 7 8 9 G. B. Haxel (1) 2002 10 |
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Snippet | This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium... |
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SubjectTerms | Adsorbents Adsorption Cerium D-Galactose Efficiency Electronegativity Fluorine Galactose Hydrophobicity Ionic liquids Ions Nanomaterials Optimization Praseodymium |
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Title | Adsorption of Rare Earth Ce3+ and Pr3+ Ions by Hydrophobic Ionic Liquid |
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