Comparison of structures between platinum and palladium complexes of a tetrasilyldisilene

The first η 2 -disilene–palladium complexes were synthesized using two different reactions; the reactions of bis(phosphine)dichloropalladiums with a 1,2-dilithiotetrakis(trialkylsilyl)disilane, which was prepared by the reaction of a stable tetrakis(trialkylsilyl)disilene with lithium (Method A) and...

Full description

Saved in:
Bibliographic Details
Published inCanadian journal of chemistry Vol. 81; no. 11; pp. 1241 - 1245
Main Authors Hashimoto, Hisako, Sekiguchi, Yumiko, Sekiguchi, Yohei, Iwamoto, Takeaki, Kabuto, Chizuko, Kira, Mistuo
Format Journal Article
LanguageEnglish
Published Ottawa, Canada NRC Research Press 01.11.2003
Online AccessGet full text

Cover

Abstract The first η 2 -disilene–palladium complexes were synthesized using two different reactions; the reactions of bis(phosphine)dichloropalladiums with a 1,2-dilithiotetrakis(trialkylsilyl)disilane, which was prepared by the reaction of a stable tetrakis(trialkylsilyl)disilene with lithium (Method A) and the direct reactions of the bis(phosphine)dichloropalladiums with the stable disilene (Method B). Comparison of X-ray structural parameters of the disilene–palladium complexes with those of the corresponding platinum complex has indicated that the palladium complex is a metallacycle but its π-complex character is stronger than that of the platinum complex.Key words: disilene complex, palladium, platinum, X-ray structure, metallacycle, π-complex.
AbstractList The first η 2 -disilene–palladium complexes were synthesized using two different reactions; the reactions of bis(phosphine)dichloropalladiums with a 1,2-dilithiotetrakis(trialkylsilyl)disilane, which was prepared by the reaction of a stable tetrakis(trialkylsilyl)disilene with lithium (Method A) and the direct reactions of the bis(phosphine)dichloropalladiums with the stable disilene (Method B). Comparison of X-ray structural parameters of the disilene–palladium complexes with those of the corresponding platinum complex has indicated that the palladium complex is a metallacycle but its π-complex character is stronger than that of the platinum complex.Key words: disilene complex, palladium, platinum, X-ray structure, metallacycle, π-complex.
Abstract_FL On a réalisé la première synthèse de complexes η 2 -disilène–palladium en faisant appel à deux réactions différentes: la méthode A implique la réaction de dérivés bis(phosphine)dichloropalladium avec un 1,2-dilithiutétrakis(trialkylsilyl)disilane préparé par réaction d'un tétrakis(trialkylsilyl)disilène stable avec du lithium alors que la méthode B implique la réaction directe de dérivés bis(phosphine)dichloropalladium avec le disilène stable. Une comparaison des paramètres structuraux obtenus par diffraction des rayons X pour les complexes disilène–palladium avec ceux du complexe correspondant du platine indique que le complexe du palladium est un métallacycle dont le caractère de complexe π est plus fort que celui du complexe du platine.Mots clés : complexe disilène, palladium, platine, structure par diffraction des rayons X, métallacycle, complexe π.[Traduit par la Rédaction]
Author Kira, Mistuo
Iwamoto, Takeaki
Sekiguchi, Yumiko
Kabuto, Chizuko
Hashimoto, Hisako
Sekiguchi, Yohei
Author_xml – sequence: 1
  givenname: Hisako
  surname: Hashimoto
  fullname: Hashimoto, Hisako
– sequence: 2
  givenname: Yumiko
  surname: Sekiguchi
  fullname: Sekiguchi, Yumiko
– sequence: 3
  givenname: Yohei
  surname: Sekiguchi
  fullname: Sekiguchi, Yohei
– sequence: 4
  givenname: Takeaki
  surname: Iwamoto
  fullname: Iwamoto, Takeaki
– sequence: 5
  givenname: Chizuko
  surname: Kabuto
  fullname: Kabuto, Chizuko
– sequence: 6
  givenname: Mistuo
  surname: Kira
  fullname: Kira, Mistuo
BookMark eNp9kE9LxDAQxYOs4O4qfoWcFITqpElpc5TFf7DgRQ-eyjSZYiWbliSr7rc3snvV05vH_N7AvAWb-dETY-cCroWQ-uYTZCGgOWJzoRooZKnFjM0BoCkUqPKELWL8yLaGspqzt9W4mTAMcfR87HlMYWvSNlDkHaUvIs8nh2nw2w1Hb_mEzqEdsjM55-g7gzmGPFEKGAe3c3bIQp5O2XGPLtLZQZfs9f7uZfVYrJ8fnla368LIqkqFtLUG3amml70mrRRQKay2ujSyE5WVdQOV1gS26UjVhjQgos47gUrLWi7Z5f6uCWOMgfp2CsMGw64V0P420uZG8txk8mpP-mDyh4TBvP8DX_wNH6B2sr38Abzrcj4
CitedBy_id crossref_primary_10_1021_ja046354y
crossref_primary_10_1002_anie_201308565
crossref_primary_10_1039_B512414J
crossref_primary_10_1002_anie_202319804
crossref_primary_10_1016_j_jorganchem_2004_05_054
crossref_primary_10_1021_jp3071822
crossref_primary_10_1021_cr900359c
crossref_primary_10_1002_chem_200500429
crossref_primary_10_1002_ange_201411025
crossref_primary_10_1021_ja052593p
crossref_primary_10_1021_jacs_8b11393
crossref_primary_10_1002_anie_201308517
crossref_primary_10_1002_ange_201503069
crossref_primary_10_1021_om070075c
crossref_primary_10_1021_ja401548d
crossref_primary_10_1002_ange_202319804
crossref_primary_10_1002_ange_201308565
crossref_primary_10_1021_ja905654r
crossref_primary_10_1002_ange_201308517
crossref_primary_10_1039_c0dt00180e
crossref_primary_10_1021_ja0464387
crossref_primary_10_1021_ja410528y
crossref_primary_10_1021_ja101654b
crossref_primary_10_1002_anie_201411025
crossref_primary_10_1016_j_ccr_2015_11_007
crossref_primary_10_1021_ja048100i
crossref_primary_10_1021_om200412c
crossref_primary_10_1002_anie_201503069
Cites_doi 10.1021/cr60262a004
10.1021/ja00157a072
10.1021/om010914+
10.1246/bcsj.71.2741
10.1351/pac198456010163
10.1016/S0022-328X(01)01152-4
10.1002/anie.199414891
10.1021/om00059a005
10.1021/ja00220a073
ContentType Journal Article
DBID AAYXX
CITATION
DOI 10.1139/v03-108
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList
CrossRef
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1480-3291
EndPage 1245
ExternalDocumentID 10_1139_v03_108
Genre Article
GroupedDBID 02
0R
1AW
29B
3V.
4.4
4P2
53G
5GY
5RP
88I
8AF
8AO
8FE
8FG
8FH
8FQ
8G5
9M8
AAIKC
ABDBF
ABEFU
ABFLS
ABJCF
ABPPZ
ABPTK
ABUWG
ACDCL
ACGFS
ACGOD
ACIWK
ACNCT
ADKZR
AENEX
AETEA
AFFNX
AFKRA
AGCDD
ALMA_UNASSIGNED_HOLDINGS
AZQEC
BCR
BENPR
BES
BGLVJ
BHPHI
BKSAR
BLC
BPHCQ
CAG
COF
CS3
D1I
D8U
DWQXO
DZ
EAD
EAP
EAS
EBC
EBD
EBS
ECC
EDH
EJD
EMK
EPL
EST
ESX
F5P
GNUQQ
GUQSH
HCIFZ
HH5
HZ
I-F
IAO
IEA
IGS
IOF
ISE
ITC
KB.
L7B
LK5
M2O
M2P
M2Q
M3C
M3G
M7R
MBDVC
MV1
MVM
MYA
NRXXU
O9-
OVD
P2P
PADUT
PCBAR
PDBOC
PQEST
PQQKQ
PQUKI
PRG
PRINS
PROAC
QF4
QM9
QN7
QO4
QRP
R.V
RIG
RNS
RRP
SJN
TAE
TN5
TUS
TWZ
U5U
WH7
X
XHC
XJT
ZCG
ZE2
-DZ
-~X
00T
0R~
6J9
6TJ
AAMNW
AAYOK
AAYXX
ABJNI
ACGFO
AEGXH
AIAGR
CCPQU
CITATION
DATHI
HZ~
ICQ
IPNFZ
ISN
ISR
ML-
OK1
ONR
PV9
RZL
TEORI
XOL
~02
ID FETCH-LOGICAL-c355t-3d7909b48f3f9e9440e21d9d92c3b15d3780599e0d8be47ce90aaa93b11a49373
ISSN 0008-4042
IngestDate Fri Aug 23 00:47:46 EDT 2024
Wed Nov 11 00:32:59 EST 2020
Thu May 23 14:20:01 EDT 2019
IsPeerReviewed true
IsScholarly true
Issue 11
Language English
LinkModel OpenURL
MergedId FETCHMERGED-LOGICAL-c355t-3d7909b48f3f9e9440e21d9d92c3b15d3780599e0d8be47ce90aaa93b11a49373
PageCount 5
ParticipantIDs nrcresearch_primary_10_1139_v03_108
crossref_primary_10_1139_v03_108
PublicationCentury 2000
PublicationDate 20031101
2003-11-01
PublicationDateYYYYMMDD 2003-11-01
PublicationDate_xml – month: 11
  year: 2003
  text: 20031101
  day: 01
PublicationDecade 2000
PublicationPlace Ottawa, Canada
PublicationPlace_xml – name: Ottawa, Canada
PublicationTitle Canadian journal of chemistry
PublicationTitleAlternate Revue canadienne de chimie
PublicationYear 2003
Publisher NRC Research Press
Publisher_xml – name: NRC Research Press
References Kira T. (p_13/p_13_1) 1994; 33
Kira T. (p_10/p_10_1); 910
(p_2/p_2_1) 1984; 56
Pan J.T. (p_12/p_12_1) 1992; 11
Iwamoto H. (p_14/p_14_1) 1998; 71
Berry J.H. (p_4/p_4_1) 1990; 112
Doyle P.E. (p_9/p_9_1) 1960; 6
Hashimoto Y. (p_6/p_6_1) 2002; 21
(p_7/p_7_1) 1951; 18
Sakaki S. (p_8/p_8_1) 2001; 635
(p_1/p_1_1) 1969; 69
Zarate C.A. (p_5/p_5_1) 1988; 110
References_xml – volume: 69
  start-page: 799
  year: 1969
  ident: p_1/p_1_1
  publication-title: Hartley. Chem. Rev.
  doi: 10.1021/cr60262a004
– volume: 112
  start-page: 452
  year: 1990
  ident: p_4/p_4_1
  publication-title: J. Carroll. J. Am. Chem. Soc.
  doi: 10.1021/ja00157a072
  contributor:
    fullname: Berry J.H.
– volume: 21
  start-page: 454
  year: 2002
  ident: p_6/p_6_1
  publication-title: Kira. Organometallics
  doi: 10.1021/om010914+
  contributor:
    fullname: Hashimoto Y.
– volume: 6
  start-page: 218
  year: 1960
  ident: p_9/p_9_1
  publication-title: Jpnassen. Inorg. Synth.
  contributor:
    fullname: Doyle P.E.
– volume: 71
  start-page: 2741
  year: 1998
  ident: p_14/p_14_1
  publication-title: Kira. Bull. Chem. Soc. Jpn.
  doi: 10.1246/bcsj.71.2741
  contributor:
    fullname: Iwamoto H.
– volume: 56
  start-page: 163
  year: 1984
  ident: p_2/p_2_1
  publication-title: West. Pure Appl. Chem.
  doi: 10.1351/pac198456010163
– volume: 18
  start-page: C71
  year: 1951
  ident: p_7/p_7_1
  publication-title: Dewer. Bull. Soc. Chim. Fr.
– volume: 910
  ident: p_10/p_10_1
  publication-title: Sakurai. Chem. Lett.
  contributor:
    fullname: Kira T.
– volume: 635
  start-page: 173
  year: 2001
  ident: p_8/p_8_1
  publication-title: Sugimoto. J. Organomet. Chem.
  doi: 10.1016/S0022-328X(01)01152-4
  contributor:
    fullname: Sakaki S.
– volume: 33
  start-page: 1489
  year: 1994
  ident: p_13/p_13_1
  publication-title: Sakurai. Angew. Chem. Int. Ed. Engl.
  doi: 10.1002/anie.199414891
  contributor:
    fullname: Kira T.
– volume: 11
  start-page: 3495
  year: 1992
  ident: p_12/p_12_1
  publication-title: Fink. Organometallics
  doi: 10.1021/om00059a005
  contributor:
    fullname: Pan J.T.
– volume: 110
  start-page: 4068
  year: 1988
  ident: p_5/p_5_1
  publication-title: J. Youngs. J. Am. Chem. Soc.
  doi: 10.1021/ja00220a073
  contributor:
    fullname: Zarate C.A.
SSID ssj0007025
Score 1.8331664
Snippet The first η 2 -disilene–palladium complexes were synthesized using two different reactions; the reactions of bis(phosphine)dichloropalladiums with a...
SourceID crossref
nrcresearch
SourceType Aggregation Database
Enrichment Source
Publisher
StartPage 1241
Title Comparison of structures between platinum and palladium complexes of a tetrasilyldisilene
URI http://www.nrcresearchpress.com/doi/abs/10.1139/v03-108
Volume 81
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Lb9swDBbW7rDuMOyJtXsJ6G6BM8uSZ-k4BOuCAduhSIH2FMgSvRhJnaBx122_fpTlV9AUaHvxS5ZgiJ8pUiA_EvIxUaFmkJkggzAORMJFIK1WgdYCrVmGCAldcvKPn5_HJ-L7aXzahRVV2SVlOjT_tuaV3Eeq-Azl6rJk7yDZdlB8gNcoXzyihPF4KxmP-kUEB54K9hL95y76ykW6uVj3ig7A7ZnbHO-qOHL44_lm9aCE8kKv88Xfhc3xBMV2_oIeyYRpysR1Cmw9c1KvNl7H-VrPl-3eDczzX67kSqXtL8_zm5qWM8hbpF7pZrSJngOauRvbE7zO02ujN45HbQzhRlSJ18YS_VfPrjUEr4CFxHUh8hW8Gg3ti7o0SGQ9fYvWCeut3Xgbb18XuKNV_V3F4ckd8jBKVOxcdXn0rV23kzDy9S7qr_Ip1q7rp7rjhu3yuLgwNSHTrGeSTJ6SJ7UvQb94YDwjD6B4Th6NGtm8IGcdQOgyox1AaA0Q2gCEIkBoCxDaAsR10_Q6QF6Sk6Ovk9E4qGtpBAYtyjLgFv9KlQqZ8UyBEiKEiFllVWR4ymLLXW0LpSC0MgWRGMB_WGuFbUwLNGH5K7JbLAt4TWgSAdMWDX8JUjDBlBFhpkXGIqvQPzb7hDazNF15ypRp5WpyNcWJdJS0--SwN3s3v_Vh21t163Rls4NbjfOG7HXIfEt2cbLhHZqSZfq-QsB_qeV7KQ
link.rule.ids 315,786,790,27957,27958
linkProvider ProQuest
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Comparison+of+structures+between+platinum+and+palladium+complexes+of+a+tetrasilyldisilene&rft.jtitle=Canadian+journal+of+chemistry&rft.au=Hashimoto%2C+Hisako&rft.au=Sekiguchi%2C+Yumiko&rft.au=Sekiguchi%2C+Yohei&rft.au=Iwamoto%2C+Takeaki&rft.date=2003-11-01&rft.pub=NRC+Research+Press&rft.issn=0008-4042&rft.eissn=1480-3291&rft.volume=81&rft.issue=11&rft.spage=1241&rft.epage=1245&rft_id=info:doi/10.1139%2Fv03-108
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0008-4042&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0008-4042&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0008-4042&client=summon