B=N Bonds and BCN Rings - Reactivity and Charge Density Studies
(F5C6)2BNMe2 (1) was prepared and (F3C)2BNMe2 (2) was resynthesized. The crystal structures of both compounds were determined. In contrast to 2, compound 1 does not react with diazomethanes under carbine insertion into the BN bond. In this way the known (F3C)2BCH(SiMe3)NMe2 (3) was resynthesized fro...
Saved in:
Published in | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 639; no. 11; pp. 2086 - 2095 |
---|---|
Main Authors | , , , , , |
Format | Journal Article |
Language | English German |
Published |
Weinheim
WILEY-VCH Verlag
01.09.2013
WILEY‐VCH Verlag Wiley Subscription Services, Inc |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | (F5C6)2BNMe2 (1) was prepared and (F3C)2BNMe2 (2) was resynthesized. The crystal structures of both compounds were determined. In contrast to 2, compound 1 does not react with diazomethanes under carbine insertion into the BN bond. In this way the known (F3C)2BCH(SiMe3)NMe2 (3) was resynthesized from 2 and its solid‐state structure was determined. The electron densities of compounds 1, 2, and 3 and those of the simpler model compound (F3C)2BCH2NMe2 (4) as well as that of the BN/CC isoelectronic compound (F3C)2CCH2CMe2 (5) for comparison were calculated and their topologies analysed in terms of the Quantum Theory of Atoms in Molecules (QTAIM). Despite 2 has a shorter B–N bond in calculations and in the crystal than 1, the atomic charges and electron density parameters to QTAIM are very similar for both compounds and cannot explain the different reactivity. The three‐membered rings 3 and 4 do not show bond‐critical points for their B–N bonds. The nature of the B–N bond region was also analysed in terms of the source function contributions in QTAIM, which demonstrated the importance of the close proximity of a third atom in three‐membered rings for the charge density topologies in such systems. |
---|---|
AbstractList | (F5C6)2BNMe2 (1) was prepared and (F3C)2BNMe2 (2) was resynthesized. The crystal structures of both compounds were determined. In contrast to 2, compound 1 does not react with diazomethanes under carbine insertion into the BN bond. In this way the known (F3C)2BCH(SiMe3)NMe2 (3) was resynthesized from 2 and its solid‐state structure was determined. The electron densities of compounds 1, 2, and 3 and those of the simpler model compound (F3C)2BCH2NMe2 (4) as well as that of the BN/CC isoelectronic compound (F3C)2CCH2CMe2 (5) for comparison were calculated and their topologies analysed in terms of the Quantum Theory of Atoms in Molecules (QTAIM). Despite 2 has a shorter B–N bond in calculations and in the crystal than 1, the atomic charges and electron density parameters to QTAIM are very similar for both compounds and cannot explain the different reactivity. The three‐membered rings 3 and 4 do not show bond‐critical points for their B–N bonds. The nature of the B–N bond region was also analysed in terms of the source function contributions in QTAIM, which demonstrated the importance of the close proximity of a third atom in three‐membered rings for the charge density topologies in such systems. (F5C6)2BNMe2 (1) was prepared and (F3C)2BNMe2 (2) was resynthesized. The crystal structures of both compounds were determined. In contrast to 2, compound 1 does not react with diazomethanes under carbine insertion into the BN bond. In this way the known (F3C)2BCH(SiMe3)NMe2 (3) was resynthesized from 2 and its solid-state structure was determined. The electron densities of compounds 1, 2, and 3 and those of the simpler model compound (F3C)2BCH2NMe2 (4) as well as that of the BN/CC isoelectronic compound (F3C)2CCH2CMe2 (5) for comparison were calculated and their topologies analysed in terms of the Quantum Theory of Atoms in Molecules (QTAIM). Despite 2 has a shorter B-N bond in calculations and in the crystal than 1, the atomic charges and electron density parameters to QTAIM are very similar for both compounds and cannot explain the different reactivity. The three-membered rings 3 and 4 do not show bond-critical points for their B-N bonds. The nature of the B-N bond region was also analysed in terms of the source function contributions in QTAIM, which demonstrated the importance of the close proximity of a third atom in three-membered rings for the charge density topologies in such systems. [PUBLICATION ABSTRACT] Abstract (F 5 C 6 ) 2 BNMe 2 ( 1 ) was prepared and (F 3 C) 2 BNMe 2 ( 2 ) was resynthesized. The crystal structures of both compounds were determined. In contrast to 2 , compound 1 does not react with diazomethanes under carbine insertion into the BN bond. In this way the known (F 3 C) 2 BCH(SiMe 3 )NMe 2 ( 3 ) was resynthesized from 2 and its solid‐state structure was determined. The electron densities of compounds 1 , 2 , and 3 and those of the simpler model compound (F 3 C) 2 BCH 2 NMe 2 ( 4 ) as well as that of the BN/CC isoelectronic compound (F 3 C) 2 CCH 2 CMe 2 ( 5 ) for comparison were calculated and their topologies analysed in terms of the Quantum Theory of Atoms in Molecules (QTAIM). Despite 2 has a shorter B–N bond in calculations and in the crystal than 1 , the atomic charges and electron density parameters to QTAIM are very similar for both compounds and cannot explain the different reactivity. The three‐membered rings 3 and 4 do not show bond‐critical points for their B–N bonds. The nature of the B–N bond region was also analysed in terms of the source function contributions in QTAIM, which demonstrated the importance of the close proximity of a third atom in three‐membered rings for the charge density topologies in such systems. |
Author | Neumann, Beate Mitzel, Norbert W. Winkelhaus, Daniel Berger, Raphael J. F. Stammler, Hans-Georg Vishnevskiy, Yuri V. |
Author_xml | – sequence: 1 givenname: Daniel surname: Winkelhaus fullname: Winkelhaus, Daniel organization: Universität Bielefeld, Fakultät für Chemie, Lehrstuhl für Anorganische Chemie und Strukturchemie, Universitätsstr. 25, 33615 Bielefeld, Germany – sequence: 2 givenname: Yuri V. surname: Vishnevskiy fullname: Vishnevskiy, Yuri V. organization: Universität Bielefeld, Fakultät für Chemie, Lehrstuhl für Anorganische Chemie und Strukturchemie, Universitätsstr. 25, 33615 Bielefeld, Germany – sequence: 3 givenname: Raphael J. F. surname: Berger fullname: Berger, Raphael J. F. organization: Paris-Lodron Universität Salzburg, FB Materialwissenschaften und Physik, Abteilung Materialchemie, Hellbrunner Str. 34, 5020 Salzburg, Austria – sequence: 4 givenname: Hans-Georg surname: Stammler fullname: Stammler, Hans-Georg organization: Universität Bielefeld, Fakultät für Chemie, Lehrstuhl für Anorganische Chemie und Strukturchemie, Universitätsstr. 25, 33615 Bielefeld, Germany – sequence: 5 givenname: Beate surname: Neumann fullname: Neumann, Beate organization: Universität Bielefeld, Fakultät für Chemie, Lehrstuhl für Anorganische Chemie und Strukturchemie, Universitätsstr. 25, 33615 Bielefeld, Germany – sequence: 6 givenname: Norbert W. surname: Mitzel fullname: Mitzel, Norbert W. email: mitzel@uni-bielefeld.de organization: Universität Bielefeld, Fakultät für Chemie, Lehrstuhl für Anorganische Chemie und Strukturchemie, Universitätsstr. 25, 33615 Bielefeld, Germany |
BookMark | eNqFkMFPwjAUhxuDiYBePS_xPGz31nU9GAND0UgwAsaES9N2HQ5xw3ao-NcLzhBvnl7ye9_3XvJroUZRFgahU4I7BOPg_EtK3QkwCTAOYzhATUID4gMLeQM1t1noB0DgCLWcW2CMCaa0iS57FyOvVxap82SRer1k5I3zYu483xsbqav8Pa82P6vkWdq58fqmcLtoUq3T3LhjdJjJpTMnv7ONHq-vpsmNP7wf3Cbdoa-BUvCp0lHAIGPKRDziMYVMczDKQEikooowmWaKmUwRTUkUsjgioIByomKeBhra6Ky-u7Ll29q4SizKtS22LwUJATMSA2dbqlNT2pbOWZOJlc1fpd0IgsWuJLErSexL2gq8Fj7ypdn8Q4tZt5v8df3azV1lPveutC8iYsCoeBoNxOShjwd3Uyxm8A01_nlp |
CitedBy_id | crossref_primary_10_1039_D1SC02947A crossref_primary_10_1016_j_ccr_2015_02_001 crossref_primary_10_1039_D1OB00520K crossref_primary_10_1002_anie_201402567 crossref_primary_10_1039_C7DT00554G crossref_primary_10_1002_ange_201402567 crossref_primary_10_1002_anie_201406564 crossref_primary_10_1016_j_cplett_2019_136860 crossref_primary_10_1002_ange_201406564 crossref_primary_10_1021_ja410088y crossref_primary_10_1039_C5DT02010G crossref_primary_10_1002_anie_201505665 crossref_primary_10_1002_ange_201505665 |
Cites_doi | 10.1016/S0022-1139(00)85090-3 10.1002/ejic.201100779 10.1002/chem.200400069 10.1002/ange.200805751 10.1002/9783527610709 10.1002/chem.201200442 10.1021/cr00088a005 10.1002/cber.19650980225 10.1016/S0022-328X(97)00710-9 10.1002/chem.200204626 10.1021/ja052865o 10.1021/ja00353a035 10.1002/chem.200400663 10.1002/ange.19971092422 10.1002/chem.201102687 10.1021/ja01016a012 10.1016/0022-328X(89)80001-4 10.1002/ange.19931050319 10.1016/0166-1280(88)80248-3 10.1002/chem.200600057 10.1002/chem.200500359 10.1021/jp906341r 10.1002/chem.200801351 10.1002/(SICI)1099-0682(19990202)1999:2<255::AID-EJIC255>3.0.CO;2-F 10.1063/1.445134 10.1515/znb-2003-0807 10.1016/0009-2614(89)85118-8 10.1002/(SICI)1521-3765(19980416)4:4<692::AID-CHEM692>3.0.CO;2-0 10.1021/om980673e 10.1021/ar950115l 10.1039/a806012f 10.1093/oso/9780198551683.001.0001 10.1016/S0040-4039(01)80208-2 10.1039/c2dt30924f 10.5560/ZNB.2012-0091 10.1021/ja980933j 10.1002/ange.200705257 10.1107/S0108767307043930 10.1021/jp100995n 10.1002/chem.201200264 10.1021/ja994542w 10.1016/S0022-1139(00)80938-0 |
ContentType | Journal Article |
Copyright | Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
Copyright_xml | – notice: Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim – notice: Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim |
DBID | BSCLL AAYXX CITATION |
DOI | 10.1002/zaac.201200483 |
DatabaseName | Istex CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | CrossRef |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1521-3749 |
EndPage | 2095 |
ExternalDocumentID | 3065819121 10_1002_zaac_201200483 ZAAC201200483 ark_67375_WNG_SQD0GKT0_Z |
Genre | article |
GrantInformation_xml | – fundername: Fonds der Chemischen Industrie – fundername: Deutsche Forschungsgemeinschaft |
GroupedDBID | -~X .3N .GA .Y3 05W 0R~ 10A 123 1L6 1OB 1OC 1ZS 31~ 33P 3SF 3WU 4.4 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5VS 66C 6TJ 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AASGY AAXRX AAZKR ABCQN ABCUV ABDBF ABHUG ABIJN ABJNI ABLJU ABTAH ACAHQ ACBWZ ACCFJ ACCUC ACCZN ACGFS ACIWK ACNCT ACPOU ACSCC ACXBN ACXME ACXQS ADAWD ADBBV ADDAD ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN AEEZP AEGXH AEIGN AEIMD AENEX AEQDE AETEA AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFVGU AFZJQ AGJLS AHBTC AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ATUGU AUFTA AZBYB AZFZN AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BSCLL BTSUX BY8 D-E D-F DCZOG DPXWK DR1 DR2 DRFUL DRSTM DU5 EBS EJD F00 F01 F04 FEDTE G-S G.N G8K GNP GODZA H.T H.X HBH HHY HHZ HVGLF HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LW6 LYRES M21 MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OHT P2P P2W P2X P4D PALCI Q.N QB0 QRW R.K RIWAO RJQFR RNS ROL RWI RWK RX1 RYL SAMSI SUPJJ TN5 TUS UB1 V2E W8V W99 WBFHL WBKPD WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XV2 YNT ZCG ZY4 ZZTAW ~02 ~IA ~WT AITYG HGLYW OIG AAYXX CITATION |
ID | FETCH-LOGICAL-c3553-5bc6273f7be6969853fc93ebe341ab5b17adfb7efb1c516478613b3591b89d2c3 |
IEDL.DBID | DR2 |
ISSN | 0044-2313 |
IngestDate | Thu Aug 29 12:51:40 EDT 2024 Thu Sep 26 15:32:52 EDT 2024 Sat Aug 24 00:45:51 EDT 2024 Wed Jan 17 05:02:31 EST 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 11 |
Language | English German |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c3553-5bc6273f7be6969853fc93ebe341ab5b17adfb7efb1c516478613b3591b89d2c3 |
Notes | In Memoriam Richard F. W. Bader Deutsche Forschungsgemeinschaft Fonds der Chemischen Industrie istex:C583F191E4D71BCF246EAAC32DD6503BBB9EA6B4 Supporting Information for this article is available on the WWW under http://dx.doi.org/10.1002/zaac.201200483 or from the author. ark:/67375/WNG-SQD0GKT0-Z ArticleID:ZAAC201200483 or from the author. http://dx.doi.org/10.1002/zaac.201200483 Supporting Information for this article is available on the WWW under |
PQID | 1430718397 |
PQPubID | 1006443 |
PageCount | 10 |
ParticipantIDs | proquest_journals_1430718397 crossref_primary_10_1002_zaac_201200483 wiley_primary_10_1002_zaac_201200483_ZAAC201200483 istex_primary_ark_67375_WNG_SQD0GKT0_Z |
PublicationCentury | 2000 |
PublicationDate | 2013-09 September 2013 2013-09-00 20130901 |
PublicationDateYYYYMMDD | 2013-09-01 |
PublicationDate_xml | – month: 09 year: 2013 text: 2013-09 |
PublicationDecade | 2010 |
PublicationPlace | Weinheim |
PublicationPlace_xml | – name: Weinheim |
PublicationTitle | Zeitschrift für anorganische und allgemeine Chemie (1950) |
PublicationTitleAlternate | Z. anorg. allg. Chem |
PublicationYear | 2013 |
Publisher | WILEY-VCH Verlag WILEY‐VCH Verlag Wiley Subscription Services, Inc |
Publisher_xml | – name: WILEY-VCH Verlag – name: WILEY‐VCH Verlag – name: Wiley Subscription Services, Inc |
References | D. J. Parks , W. E. Piers , G. P. A. Yap , Organometallics 1998 , 17 , 5492 -5503 . K. Vojinović , L. J. McLachlan , S. L. Hinchley , D. W. H. Rankin , N. W. Mitzel , Chem. Eur. J. 2004 , 10 , 3033 -3042 . U. Flierler , M. Burzler , D. Leusser , J. Henn , H. Ott , H. Braunschweig , D. Stalke , Angew. Chem. 2008 , 120 , 4393 -4397 ; Angew. Chem. Int. Ed. 2008 , 47 , 4321 -4325 . A. E. Reed , F. Weinhold , Chem. Rev. 1988 , 88 , 899 -926 . N. W. Mitzel , K. Vojinović , R. Fröhlich , T. Foerster , D. W. H. Rankin , J. Am. Chem. Soc. 2005 , 127 , 13705 -13713 H. Bürger , M. Grunwald , G. Pawelke , J. Fluorine Chem. 1986 , 31 , 89 -98 ; a value of δ(11B) = 30.2 ppm was reported for 2, but no solvent specified for this NMR experiment. N. W. Mitzel , U. Losehand , A. Wu , D. Cremer , D. W. H. Rankin , J. Am. Chem. Soc. 2000 , 122 , 4471 -4482 D. J. Brauer , H. Bürger , S. Buchheim-Spiegel , G. Pawelke , Eur. J. Inorg. Chem. 1999 , 255 -261 . A. P. M. Robertson , G. R. Whittell , A. Staubitz , K. Lee , A. J. Lough , I. Manners , Eur. J. Inorg. Chem. 2011 , 5279 -5287 . M. v. Hopffgarten , G. Frenking , Chem. Eur. J. 2008 , 14 , 10227 -10231 . K. R. Leopold , M. Canagaratna , J. A. Phillips , Acc. Chem. Res. 1997 , 30 , 57 -64 . P. L. A. Popelier , Atoms in Molecules - An Introduction , Prentice Hall , 2000 W. Scherer , W. Hieringer , M. Spiegler , P. Sirsch , G. S. McGrady , A. J. Downs , A. Haaland , B. Pedersen , Chem. Commun. 1998 , 2471 -2472 . J. Poater , M. Solà , F. M. Bickelhaupt , Chem. Eur. J. 2006 , 12 , 2902 -2905 W. H. E. Schwarz , H. Schmidbaur , Chem. Eur. J. 2012 , 18 , 4470 -4479 . J. E. Carpenter , F. J. Weinhold , THEOCHEM 1988 , 169 , 41 -62 D. Wojciech , J. Fluorine Chem. 1984 , 26 , 379 -394 . A. Ansorge , D. J. Brauer , H. Bürger , T. Hagen , G. Pawelke , Angew. Chem. 1993 , 105 , 429 -430 ; Angew. Chem. Int. Ed. Engl. 1993 , 32 , 384 -385 . R. F. W. Bader , Atoms in Molecules: A Quantum Theory , Clarendon Press , Oxford , 1990 A. Haaland , D. J. Shorokov , N. V. Tverdova , Chem. Eur. J. 2004 , 10 , 4416 -4421 D. Winkelhaus , B. Neumann , H.-G. Stammler , R. J. F. Berger , Y. V. Vishnevskiy , N. W. Mitzel , Chem. Eur. J. 2012 , 18 , 9312 -9320 H. J. Becher , H. Diehl , Chem. Ber. 1965 , 98 , 526 -532 . L. Pauling , The Nature of the Chemical Bond , 3rd ed. , Cornell University Press , Ithaca , 1960 N. W. Mitzel , U. Losehand , Angew. Chem. 1997 , 109 , 2897 -2899 ; Angew. Chem. Int. Ed. Engl. 1997 , 36 , 2807 -2809 . N. W. Mitzel , U. Losehand , J. Am. Chem. Soc. 1998 , 120 , 7320 -7327 S. Mebs , S. Grabowsky , D. Förster , R. Kickbusch , M. Hartl , L. L. Daemen , W. Morgenroth , P. Luger , B. Paulus , D. Lentz , J. Phys. Chem. A 2010 , 114 , 10185 -10196 . P. L. A. Popelier , G. Logothetis , J. Organomet. Chem. 1998 , 555 , 101 -111 G. S. Kyker , E. P. Schram , J. Am. Chem. Soc. 1968 , 90 , 3672 -3677 D. Winkelhaus , B. Neumann , H.-G. Stammler , N. W. Mitzel , Dalton Trans. 2012 , 41 , 8609 -8614 R.Ahlrichs, M. Bär , M. Häser , H. Horn , C. Kölmel , Chem. Phys. Lett. 1989 , 162 , 165 -169 . N. W. Mitzel , Z. Naturforsch. B 2003 , 58 , 759 -763 . N. W. Mitzel , Chem. Eur. J. 1998 , 4 , 692 -698 S. Grimme , C. Mück-Lichtenfeld , G. Erker , G. Kehr , H. Wang , H. Beckers , H. Willner , Angew. Chem. 2009 , 121 , 2629 -2633 ; Angew. Chem. Int. Ed. 2009 , 48 , 2592 -2595 . I. Ruppert , K. Schlich , W. Volbach , Tetrahedron Lett. 1984 , 25 , 2195 -2198 . R. F. W. Bader , T. S. Slee , D. Cremer , E. J. Kraka , J. Am. Chem. Soc. 1983 , 105 , 5061 -5068 . G. M. Sheldrick , Acta Crystallogr., Sect. A 2008 , 64 , 112 -122 . N. W. Mitzel , K. Vojinović , T. Foerster , H. E. Robertson , K. B. Borisenko , D. W. H. Rankin , Chem. Eur. J. 2005 , 11 , 5114 -5125 . D. Winkelhaus , B. Neumann , N. W. Mitzel , Z. Naturforsch. B 2012 , 67 , 589 -593 . C. F. Matta , R. J. Boyd , The Quantum Theory of Atoms in Molecules , Wiley-VCH , Weinheim , 2007 A. E. Reed , F. Weinhold , J. Chem. Phys. 1983 , 78 , 4066 -4073 Y. V. Vishnevskiy , M. A. Abaev , A. N. Rykov , M. E. Gurskii , P. A. Belyakov , S. Y. Erdyakov , Y. N. Bubnov , N. W. Mitzel , Chem. Eur. J. 2012 , 18 , 10585 -10594 . C. F. Matta , J. Hernandez-Trujillo , T.-H. Tang , R. F. W. Bader , Chem. Eur. J. 2003 , 9 , 1940 -1951 . D. J. Brauer , H. Bürger , F. Dörrenbach , G. Pawelke , W. Weuter , J. Organomet. Chem. 1989 , 378 , 125 -137 . R. F. W. Bader , J. Phys. Chem. A 2009 , 113 , 10391 -10396 1965; 98 2006; 12 1984; 25 1984; 26 1986; 31 2011 1989; 378 1988; 169 1998 2008; 14 2003; 58 2007 2009; 113 1989; 162 1998; 555 2012; 18 1993; 105 2008; 120 1983; 78 1999 2004; 10 1983; 105 1998; 17 1997; 109 1990 2000 1997; 30 2010; 114 2005; 127 2003; 9 2009; 121 1988; 88 1968; 90 1960 2000; 122 2013 2008; 64 2012; 67 1998; 4 2005; 11 1998; 120 2012; 41 e_1_2_6_51_2 e_1_2_6_30_2 Pauling L. (e_1_2_6_1_2) 1960 Bader R. F. W. (e_1_2_6_7_2) 1990 e_1_2_6_19_2 e_1_2_6_13_2 e_1_2_6_34_2 e_1_2_6_11_2 e_1_2_6_32_2 e_1_2_6_17_2 e_1_2_6_38_2 e_1_2_6_55_2 e_1_2_6_15_2 e_1_2_6_36_2 e_1_2_6_57_2 e_1_2_6_20_2 e_1_2_6_41_2 e_1_2_6_9_2 e_1_2_6_3_2 e_1_2_6_5_2 e_1_2_6_24_2 e_1_2_6_47_2 e_1_2_6_22_2 e_1_2_6_49_2 e_1_2_6_28_2 e_1_2_6_43_2 e_1_2_6_26_2 e_1_2_6_45_2 e_1_2_6_50_2 e_1_2_6_52_2 e_1_2_6_31_2 e_1_2_6_18_2 Popelier P. L. A. (e_1_2_6_8_2) 2000 e_1_2_6_12_2 e_1_2_6_35_2 e_1_2_6_58_2 e_1_2_6_10_2 e_1_2_6_33_2 e_1_2_6_16_2 e_1_2_6_39_2 e_1_2_6_54_2 e_1_2_6_14_2 e_1_2_6_37_2 e_1_2_6_56_2 e_1_2_6_42_2 Rankin D. W. H. (e_1_2_6_53_2) 2013 e_1_2_6_40_2 e_1_2_6_29_2 e_1_2_6_4_2 e_1_2_6_6_2 e_1_2_6_23_2 e_1_2_6_48_2 e_1_2_6_2_2 e_1_2_6_21_2 e_1_2_6_27_2 e_1_2_6_44_2 e_1_2_6_25_2 e_1_2_6_46_2 |
References_xml | – volume: 58 start-page: 759 year: 2003 end-page: 763 publication-title: Z. Naturforsch. B – volume: 14 start-page: 10227 year: 2008 end-page: 10231 publication-title: Chem. Eur. J. – volume: 378 start-page: 125 year: 1989 end-page: 137 publication-title: J. Organomet. Chem. – volume: 18 start-page: 4470 year: 2012 end-page: 4479 publication-title: Chem. Eur. J. – year: 1960 – volume: 555 start-page: 101 year: 1998 end-page: 111 publication-title: J. Organomet. Chem. – volume: 88 start-page: 899 year: 1988 end-page: 926 publication-title: Chem. Rev. – volume: 78 start-page: 4066 year: 1983 end-page: 4073 publication-title: J. Chem. Phys. – volume: 9 start-page: 1940 year: 2003 end-page: 1951 publication-title: Chem. Eur. J. – volume: 67 start-page: 589 year: 2012 end-page: 593 publication-title: Z. Naturforsch. B – year: 2007 – volume: 127 start-page: 13705 year: 2005 end-page: 13713 publication-title: J. Am. Chem. Soc. – volume: 18 start-page: 9312 year: 2012 end-page: 9320 publication-title: Chem. Eur. J. – start-page: 5279 year: 2011 end-page: 5287 publication-title: Eur. J. Inorg. Chem. – volume: 26 start-page: 379 year: 1984 end-page: 394 publication-title: J. Fluorine Chem. – volume: 18 start-page: 10585 year: 2012 end-page: 10594 publication-title: Chem. Eur. J. – volume: 64 start-page: 112 year: 2008 end-page: 122 publication-title: Acta Crystallogr., Sect. A – year: 2000 – volume: 12 start-page: 2902 year: 2006 end-page: 2905 publication-title: Chem. Eur. J. – volume: 120 start-page: 7320 year: 1998 end-page: 7327 publication-title: J. Am. Chem. Soc. – volume: 120 start-page: 4393 year: 2008 end-page: 4397 publication-title: Angew. Chem. – volume: 25 start-page: 2195 year: 1984 end-page: 2198 publication-title: Tetrahedron Lett. – volume: 98 start-page: 526 year: 1965 end-page: 532 publication-title: Chem. Ber. – year: 1990 – volume: 169 start-page: 41 year: 1988 end-page: 62 publication-title: THEOCHEM – volume: 122 start-page: 4471 year: 2000 end-page: 4482 publication-title: J. Am. Chem. Soc. – volume: 113 start-page: 10391 year: 2009 end-page: 10396 publication-title: J. Phys. Chem. A – volume: 10 start-page: 3033 year: 2004 end-page: 3042 publication-title: Chem. Eur. J. – start-page: 255 year: 1999 end-page: 261 publication-title: Eur. J. Inorg. Chem. – volume: 11 start-page: 5114 year: 2005 end-page: 5125 publication-title: Chem. Eur. J. – volume: 90 start-page: 3672 year: 1968 end-page: 3677 publication-title: J. Am. Chem. Soc. – volume: 10 start-page: 4416 year: 2004 end-page: 4421 publication-title: Chem. Eur. J. – volume: 121 start-page: 2629 year: 2009 end-page: 2633 publication-title: Angew. Chem. – volume: 30 start-page: 57 year: 1997 end-page: 64 publication-title: Acc. Chem. Res. – volume: 109 start-page: 2897 year: 1997 end-page: 2899 publication-title: Angew. Chem. – volume: 162 start-page: 165 year: 1989 end-page: 169 publication-title: Chem. Phys. Lett. – volume: 31 start-page: 89 year: 1986 end-page: 98 publication-title: J. Fluorine Chem. – volume: 4 start-page: 692 year: 1998 end-page: 698 publication-title: Chem. Eur. J. – volume: 41 start-page: 8609 year: 2012 end-page: 8614 publication-title: Dalton Trans. – volume: 17 start-page: 5492 year: 1998 end-page: 5503 publication-title: Organometallics – volume: 114 start-page: 10185 year: 2010 end-page: 10196 publication-title: J. Phys. Chem. A – start-page: 2471 year: 1998 end-page: 2472 publication-title: Chem. Commun. – volume: 105 start-page: 429 year: 1993 end-page: 430 publication-title: Angew. Chem. – volume: 105 start-page: 5061 year: 1983 end-page: 5068 publication-title: J. Am. Chem. Soc. – year: 2013 – ident: e_1_2_6_19_2 – ident: e_1_2_6_40_2 doi: 10.1016/S0022-1139(00)85090-3 – ident: e_1_2_6_2_2 – ident: e_1_2_6_45_2 doi: 10.1002/ejic.201100779 – ident: e_1_2_6_31_2 doi: 10.1002/chem.200400069 – ident: e_1_2_6_13_2 – ident: e_1_2_6_15_2 doi: 10.1002/ange.200805751 – ident: e_1_2_6_56_2 doi: 10.1002/9783527610709 – ident: e_1_2_6_36_2 doi: 10.1002/chem.201200442 – ident: e_1_2_6_5_2 doi: 10.1021/cr00088a005 – ident: e_1_2_6_44_2 doi: 10.1002/cber.19650980225 – volume-title: The Nature of the Chemical Bond year: 1960 ident: e_1_2_6_1_2 contributor: fullname: Pauling L. – ident: e_1_2_6_11_2 doi: 10.1016/S0022-328X(97)00710-9 – ident: e_1_2_6_9_2 doi: 10.1002/chem.200204626 – ident: e_1_2_6_25_2 doi: 10.1021/ja052865o – ident: e_1_2_6_54_2 doi: 10.1021/ja00353a035 – ident: e_1_2_6_17_2 doi: 10.1002/chem.200400663 – ident: e_1_2_6_28_2 doi: 10.1002/ange.19971092422 – ident: e_1_2_6_21_2 doi: 10.1002/chem.201102687 – ident: e_1_2_6_33_2 – ident: e_1_2_6_43_2 doi: 10.1021/ja01016a012 – ident: e_1_2_6_46_2 doi: 10.1016/0022-328X(89)80001-4 – ident: e_1_2_6_16_2 – ident: e_1_2_6_32_2 doi: 10.1002/ange.19931050319 – ident: e_1_2_6_10_2 – ident: e_1_2_6_3_2 doi: 10.1016/0166-1280(88)80248-3 – ident: e_1_2_6_14_2 doi: 10.1002/chem.200600057 – ident: e_1_2_6_22_2 doi: 10.1002/chem.200500359 – ident: e_1_2_6_24_2 – ident: e_1_2_6_20_2 doi: 10.1021/jp906341r – ident: e_1_2_6_18_2 doi: 10.1002/chem.200801351 – ident: e_1_2_6_47_2 doi: 10.1002/(SICI)1099-0682(19990202)1999:2<255::AID-EJIC255>3.0.CO;2-F – ident: e_1_2_6_50_2 – ident: e_1_2_6_4_2 doi: 10.1063/1.445134 – ident: e_1_2_6_6_2 – ident: e_1_2_6_23_2 doi: 10.1515/znb-2003-0807 – ident: e_1_2_6_49_2 doi: 10.1016/0009-2614(89)85118-8 – ident: e_1_2_6_30_2 doi: 10.1002/(SICI)1521-3765(19980416)4:4<692::AID-CHEM692>3.0.CO;2-0 – ident: e_1_2_6_38_2 doi: 10.1021/om980673e – ident: e_1_2_6_51_2 doi: 10.1021/ar950115l – ident: e_1_2_6_12_2 doi: 10.1039/a806012f – volume-title: Atoms in Molecules: A Quantum Theory year: 1990 ident: e_1_2_6_7_2 doi: 10.1093/oso/9780198551683.001.0001 contributor: fullname: Bader R. F. W. – ident: e_1_2_6_34_2 – ident: e_1_2_6_41_2 doi: 10.1016/S0040-4039(01)80208-2 – ident: e_1_2_6_35_2 doi: 10.1039/c2dt30924f – ident: e_1_2_6_48_2 – ident: e_1_2_6_37_2 doi: 10.5560/ZNB.2012-0091 – ident: e_1_2_6_42_2 – ident: e_1_2_6_27_2 doi: 10.1021/ja980933j – ident: e_1_2_6_57_2 doi: 10.1002/ange.200705257 – ident: e_1_2_6_58_2 doi: 10.1107/S0108767307043930 – ident: e_1_2_6_29_2 – ident: e_1_2_6_52_2 doi: 10.1021/jp100995n – ident: e_1_2_6_55_2 doi: 10.1002/chem.201200264 – ident: e_1_2_6_26_2 doi: 10.1021/ja994542w – volume-title: Atoms in Molecules – An Introduction year: 2000 ident: e_1_2_6_8_2 contributor: fullname: Popelier P. L. A. – ident: e_1_2_6_39_2 doi: 10.1016/S0022-1139(00)80938-0 – volume-title: Structural Methods in Molecular Inorganic Chemistry year: 2013 ident: e_1_2_6_53_2 contributor: fullname: Rankin D. W. H. |
SSID | ssj0001055 |
Score | 2.0868871 |
Snippet | (F5C6)2BNMe2 (1) was prepared and (F3C)2BNMe2 (2) was resynthesized. The crystal structures of both compounds were determined. In contrast to 2, compound 1... Abstract (F 5 C 6 ) 2 BNMe 2 ( 1 ) was prepared and (F 3 C) 2 BNMe 2 ( 2 ) was resynthesized. The crystal structures of both compounds were determined. In... |
SourceID | proquest crossref wiley istex |
SourceType | Aggregation Database Publisher |
StartPage | 2086 |
SubjectTerms | Boron Chemical bonding Electron density Nitrogen Three-membered rings |
Title | B=N Bonds and BCN Rings - Reactivity and Charge Density Studies |
URI | https://api.istex.fr/ark:/67375/WNG-SQD0GKT0-Z/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fzaac.201200483 https://www.proquest.com/docview/1430718397/abstract/ |
Volume | 639 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV29TsMwELYQDLDwjygU5AHBlDZxftwMDG1Ki0CqRAGBWCzbcRiQCqKthDrxDrwhT8Kdk5SWBQnGOHGc3Nm-7-zzd4QcxZFkWqba4TIIncCXnqMyVzuAfg3nhmklbZRvLzq_DS7uw_uZU_w5P8R0wQ1Hhp2vcYBLNax_k4ZOpEQKQo9ZVnSYhJFND1FR_5s_CrM_5lvMgQNAxi9ZG11Wn68-Z5WWUMBvc5BzFrhay9NZI7L85jzg5Kk2Hqmanvygc_zPT62T1QKW0mbejzbIghlskuWkzAa3RZqt0x7FHMRDKgcpbSU92sdFdvr5_kH7Bo9HYBYKexO38B8NbWNsPBQVoYrb5LZzdpOcO0X6BUcDCPGdUOkIwE3GlYniKAa7nunYB6WD4ZMqVB6Xaaa4yZSnQ6QlawA0UH4Ye6oRp0z7O2Rx8Dwwu4QqKAliDr6eCQOtskZqOIO3eTF4N8blFXJSil-85CwbIudTZgJFIqYiqZBjq53pY_L1CWPTeCjuel1xfdV2u5c3rniokGqpPlEMyyH4OTClISaEFpnVwy_NiYdmM5le7f2l0j5ZYTaFBsalVcni6HVsDgDIjNSh7axff-3oHQ |
link.rule.ids | 315,786,790,1382,27957,27958,46329,46753 |
linkProvider | Wiley-Blackwell |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3NTtwwEB5RONALFCjqAgUfED0FEieONwcOy_KzBRqJZVERF8t2nB6QFgSLhDjxDrwhT8KMs1lYLkj0GCeOkxmP_Y09_gZgPUs1t7qwgdSJCJJYR4EpQxsg-nVSOm6N9lG-edo5Sw7PRR1NSGdhKn6I0YIbWYYfr8nAaUF665U19EFr4iCMuKdF_wJTaPPCe1XdVwYpyv9YbTInAUKZuOZtDPnWeP2xeWmKRHw_BjrfQlc_9-zPgqm_ugo5udy8G5hN-_CO0PG_fusbzAyRKWtVXWkOJlx_HqbbdUK4BWjtbOeM0hDfMt0v2E47Z11aZ2fPj0-s6-iEBCWi8DdpF_-fY7sUHo9Fw2jF73C2v9drd4JhBobAIg6JA2FsivimlMalWZrh1F7aLEa949ynjTCR1EVppCtNZAUxkzURHZhYZJFpZgW38SJM9q_67gcwgyVJJtHdcyKxpmwWTnJ8W5Shg-NC2YBftfzVdUW0oSpKZa5IJGokkgZsePWMHtM3lxSeJoX6mx-o05Pd8OCoF6qLBqzU-lNDy7xFVwdHNYKF2CL3ivigOXXRarVHV0ufqbQG053en2N1_Ds_Woav3GfUoDC1FZgc3Ny5n4hrBmbV99wXKmDsPw |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LTxsxEB5RIrVcgL7UtEB9QO1pYdf7cPbAIQ8SCtUK0kRFXCzb6-UQKY0gSIhT_wP_kF_CjDebEC6V6HG96_XujO35xh5_A7CbJooblRtPqCj2olAFni584yH6tUJYbrRyUb5ZcjSMjs_j8yen-Et-iPmCG40MN1_TAJ_kxf6CNPROKaIgDLhjRX8FtSgJOfXrTn9BIEXpH8s95shDJBNWtI0-31-uv2SWaiTh2yXM-RS5OtPT3QBVfXQZcTLau5nqPXP3jM_xf_5qE9ZnuJQ1y470Flbs-B28aVfp4N5Ds3WQMUpCfM3UOGetdsb6tMrOHv7es76l8xGUhsLdpD38S8s6FByPRbNYxQ8w7B4O2kfeLP-CZxCFhF6sTYLophDaJmmSomEvTBqi1tHyKR3rQKi80MIWOjAx8ZI1EBvoME4D3UhzbsKPsDr-M7afgGksiVKBzp6NI6OLRm4Fx7cFKbo31hd1-F6JX05Kmg1ZEipzSSKRc5HU4ZvTzvwxdTWi4DQRy99ZT_466_i9k4EvL-qwValPzsblNTo6OKcRKMQWudPDP5qTF81me371-SWVvsLr005X_vyRnXyBNe7SaVCM2hasTq9u7DaCmqnecf32EWut6u4 |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=B%3DN+Bonds+and+BCN+Rings+%E2%80%93+Reactivity+and+Charge+Density+Studies&rft.jtitle=Zeitschrift+f%C3%BCr+anorganische+und+allgemeine+Chemie+%281950%29&rft.au=Winkelhaus%2C+Daniel&rft.au=Vishnevskiy%2C+Yuri+V.&rft.au=Berger%2C+Raphael+J.+F.&rft.au=Stammler%2C+Hans%E2%80%90Georg&rft.date=2013-09-01&rft.pub=WILEY%E2%80%90VCH+Verlag&rft.issn=0044-2313&rft.eissn=1521-3749&rft.volume=639&rft.issue=11&rft.spage=2086&rft.epage=2095&rft_id=info:doi/10.1002%2Fzaac.201200483&rft.externalDBID=10.1002%252Fzaac.201200483&rft.externalDocID=ZAAC201200483 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0044-2313&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0044-2313&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0044-2313&client=summon |