Synthesis of nanometer scale oxide-based titania films by a two-dimensional sol–gel process at the air–liquid interface
The present study focuses upon the synthesis of nanometer scale oxide-based titania films from tetrabutoxy titanium according to a two-dimensional sol–gel process at the air–liquid interface. First, surface pressure–area isotherms of the tetrabutoxy titanium were measured at 22.0±0.5°C on various su...
Saved in:
Published in | Colloids and surfaces. A, Physicochemical and engineering aspects Vol. 149; no. 1; pp. 89 - 98 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
15.04.1999
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | The present study focuses upon the synthesis of nanometer scale oxide-based titania films from tetrabutoxy titanium according to a two-dimensional sol–gel process at the air–liquid interface. First, surface pressure–area isotherms of the tetrabutoxy titanium were measured at 22.0±0.5°C on various subphases: pure water (pH=5.5), aqueous acetylacetone (0.01
M, pH=4,6), aqueous acetic acid (0.01
M, pH=3.3) and glycerol. At the same time, UV–vis absorption spectra were directly recorded at the interface at variable surface pressures. Brewster angle microscopy served to observe the film topology on the different subphases. The results are interpreted in terms of the formation of a macroscopic network interconnecting the titania atoms. On the aqueous acetic acid and the glycerol subphases, the film showed to be more complex and stronger interconnected, i.e. involving two networks made of oxide and ligand bridges. In the case of the aqueous acetylacetone subphase, the resulting coating appears much less interconnected. |
---|---|
AbstractList | The present study focuses upon the synthesis of nanometer scale oxide-based titania films from tetrabutoxy titanium according to a two-dimensional sol–gel process at the air–liquid interface. First, surface pressure–area isotherms of the tetrabutoxy titanium were measured at 22.0±0.5°C on various subphases: pure water (pH=5.5), aqueous acetylacetone (0.01
M, pH=4,6), aqueous acetic acid (0.01
M, pH=3.3) and glycerol. At the same time, UV–vis absorption spectra were directly recorded at the interface at variable surface pressures. Brewster angle microscopy served to observe the film topology on the different subphases. The results are interpreted in terms of the formation of a macroscopic network interconnecting the titania atoms. On the aqueous acetic acid and the glycerol subphases, the film showed to be more complex and stronger interconnected, i.e. involving two networks made of oxide and ligand bridges. In the case of the aqueous acetylacetone subphase, the resulting coating appears much less interconnected. |
Author | Puccetti, G Leblanc, R.M Facca, F |
Author_xml | – sequence: 1 givenname: F surname: Facca fullname: Facca, F – sequence: 2 givenname: G surname: Puccetti fullname: Puccetti, G – sequence: 3 givenname: R.M surname: Leblanc fullname: Leblanc, R.M |
BookMark | eNqFkMtOwzAQRS1UJNrCJyB5CYuAHcdxskKo4iVVYlFYW449BqPELnZ4VGz4B_6QLyFtEVtWs7hzz4zOBI188IDQISUnlNDydEHqXGRCcHFUV8eEsLzKqh00ppVgWcF4PULjv5U9NEnpiRBScFGP0cdi5ftHSC7hYLFXPnTQQ8RJqxZweHcGskYlMLh3vfJOYevaLuFmhRXu30JmXAc-ueBVi1Novz-_HqDFyxg0pIRVjwc6Vi4OQeueX5zBzg8HrNKwj3atahMc_M4pur-8uJtdZ_Pbq5vZ-TzTjBd9ZnllGyGasmENt6Rm3DDS2AZobS0FwTQhxpZ5mVtd8LqCsqSaWqPynFkxOJgivuXqGFKKYOUyuk7FlaRErg3KjUG51iPrSm4MymronW17MDz36iDKpB14DcZF0L00wf1D-AEaOX80 |
CitedBy_id | crossref_primary_10_1016_j_optmat_2005_01_013 crossref_primary_10_1021_la0303299 crossref_primary_10_1016_j_jphotochem_2010_06_016 crossref_primary_10_1016_S0927_7757_02_00142_5 crossref_primary_10_1016_j_jcis_2012_10_054 crossref_primary_10_1002_1521_4095_20020116_14_2_151__AID_ADMA151_3_0_CO_2_N crossref_primary_10_1007_s10971_019_04949_w crossref_primary_10_1016_j_physb_2004_11_013 crossref_primary_10_1021_cm0208152 |
Cites_doi | 10.1021/la00096a022 10.1007/978-1-4615-2750-3_2 10.1021/ja00108a035 10.1103/PhysRevE.48.3692 10.1021/ja00197a018 10.1351/pac199264111703 10.1080/02786829408959737 10.1063/1.355142 10.1007/BF00659455 10.1021/la960256b 10.1016/0079-6786(88)90005-2 10.1016/0025-5408(94)90099-X 10.1021/la00007a053 |
ContentType | Journal Article |
Copyright | 1999 Elsevier Science B.V. |
Copyright_xml | – notice: 1999 Elsevier Science B.V. |
DBID | AAYXX CITATION |
DOI | 10.1016/S0927-7757(98)00328-8 |
DatabaseName | CrossRef |
DatabaseTitle | CrossRef |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Engineering Chemistry |
EISSN | 1873-4359 |
EndPage | 98 |
ExternalDocumentID | 10_1016_S0927_7757_98_00328_8 S0927775798003288 |
GroupedDBID | --- --K --M -~X .~1 0R~ 1B1 1~. 1~5 29F 4.4 457 4G. 53G 5GY 5VS 7-5 71M 8P~ 9JN AABNK AABXZ AACTN AAEDT AAEDW AAEPC AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AAQXK AARLI AAXUO ABFNM ABMAC ABNEU ABNUV ABXDB ABXRA ABYKQ ACDAQ ACFVG ACGFS ACNCT ACNNM ACRLP ADBBV ADECG ADEWK ADEZE ADMUD AEBSH AEKER AEZYN AFKWA AFRZQ AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHPOS AI. AIEXJ AIKHN AITUG AIVDX AJBFU AJOXV AJSZI AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ ASPBG AVWKF AXJTR AZFZN BBWZM BKOJK BLXMC CS3 EBS EFJIC EFLBG EJD ENUVR EO8 EO9 EP2 EP3 F5P FDB FEDTE FGOYB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HLY HVGLF HZ~ IHE J1W KOM LX7 M41 MAGPM MO0 N9A NDZJH O-L O9- OAUVE OGIMB OZT P-8 P-9 P2P PC. Q38 R2- RIG RNS ROL RPZ SCB SCE SDF SDG SDP SES SEW SPC SPD SSG SSK SSM SSQ SSZ T5K VH1 WH7 WUQ ~02 ~G- AAXKI AAYXX CITATION |
ID | FETCH-LOGICAL-c354t-f58fb77b6b3b5f0935d30bfbe19ff1e73c00df6262fc4598e661c1fda223f7873 |
IEDL.DBID | .~1 |
ISSN | 0927-7757 |
IngestDate | Thu Sep 12 17:51:49 EDT 2024 Fri Feb 23 02:28:43 EST 2024 |
IsDoiOpenAccess | false |
IsOpenAccess | true |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 1 |
Keywords | Sol–gel process Titania Nanometer scale films |
Language | English |
LinkModel | DirectLink |
MergedId | FETCHMERGED-LOGICAL-c354t-f58fb77b6b3b5f0935d30bfbe19ff1e73c00df6262fc4598e661c1fda223f7873 |
OpenAccessLink | https://doi.org/10.1016/s0927-7757(98)00328-8 |
PageCount | 10 |
ParticipantIDs | crossref_primary_10_1016_S0927_7757_98_00328_8 elsevier_sciencedirect_doi_10_1016_S0927_7757_98_00328_8 |
PublicationCentury | 1900 |
PublicationDate | 1999-04-15 |
PublicationDateYYYYMMDD | 1999-04-15 |
PublicationDate_xml | – month: 04 year: 1999 text: 1999-04-15 day: 15 |
PublicationDecade | 1990 |
PublicationTitle | Colloids and surfaces. A, Physicochemical and engineering aspects |
PublicationYear | 1999 |
Publisher | Elsevier B.V |
Publisher_xml | – name: Elsevier B.V |
References | Ariga, Okahata (BIB14) 1989; 111 J. Livage, F. Babonneau, C. Sanchez, in: L.C. Klein (Ed.), Sol–Gel Optics — Processing and Applications, Kluwer, Norwell MA, 1994, p. 39–58. Mattlevic, Zhong, Partch (BIB4) 1995; 22 Moriguchi, Maeda, Teraoka, Kagawa (BIB10) 1995; 117 G.L. Gaines, Jr., Insoluble Monolayers at Liquid–Gas Interfaces, Wiley, New York, 1966. C.J. Pouchert, The Aldrich Library of Infrared Spectra Aldrich Chemical, Milwaukee, WI, 1981. Lindèn, Slote, Rosenholm (BIB12) 1996; 12 Matijevic (BIB8) 1992; 64 Leon, Vincent, Cawdery (BIB9) 1994; 272 Kolosov, Suzuki, Yamanaka (BIB5) 1993; 71 Sjoblom, Stakkestad, Ebeltoft, Friberg, Claesson (BIB11) 1995; 11 Barboux-Doeuff, Sanchez (BIB15) 1994; 29 Ebelmen (BIB1) 1844; 21 Okahata, Yokobori, Ebara, Ebato, Ariga (BIB13) 1990; 6 C.J. Brinker, G. Scherrer, Sol–Gel Science, Academic Press, San Diego, CA, 1990. Livage, Henri, Sanchez (BIB18) 1988; 18 D.C. Bradley, R.C. Mehrotra, D.P. Gaur, Metal Alkoxides, Academic Press, New York, 1978. L.C. Klein, Sol–Gel Technology of Thin Films, Fibers, Preforms, Electronics and Specialty Shapes, Noyes, Park Ridge, NJ, 1988. Kallala, Sanchez, Cabane (BIB6) 1993; 48 Blanchard, Barboux-Doeuff, Maquet, Sanchez (BIB16) 1995; 19 Leon (10.1016/S0927-7757(98)00328-8_BIB9) 1994; 272 Okahata (10.1016/S0927-7757(98)00328-8_BIB13) 1990; 6 10.1016/S0927-7757(98)00328-8_BIB17 10.1016/S0927-7757(98)00328-8_BIB2 Ebelmen (10.1016/S0927-7757(98)00328-8_BIB1) 1844; 21 10.1016/S0927-7757(98)00328-8_BIB3 Livage (10.1016/S0927-7757(98)00328-8_BIB18) 1988; 18 Lindèn (10.1016/S0927-7757(98)00328-8_BIB12) 1996; 12 Kallala (10.1016/S0927-7757(98)00328-8_BIB6) 1993; 48 10.1016/S0927-7757(98)00328-8_BIB19 10.1016/S0927-7757(98)00328-8_BIB20 Moriguchi (10.1016/S0927-7757(98)00328-8_BIB10) 1995; 117 Matijevic (10.1016/S0927-7757(98)00328-8_BIB8) 1992; 64 Mattlevic (10.1016/S0927-7757(98)00328-8_BIB4) 1995; 22 Ariga (10.1016/S0927-7757(98)00328-8_BIB14) 1989; 111 Kolosov (10.1016/S0927-7757(98)00328-8_BIB5) 1993; 71 Barboux-Doeuff (10.1016/S0927-7757(98)00328-8_BIB15) 1994; 29 Blanchard (10.1016/S0927-7757(98)00328-8_BIB16) 1995; 19 Sjoblom (10.1016/S0927-7757(98)00328-8_BIB11) 1995; 11 10.1016/S0927-7757(98)00328-8_BIB7 |
References_xml | – volume: 21 start-page: 502 year: 1844 ident: BIB1 publication-title: C.R. Acad. Sci. contributor: fullname: Ebelmen – volume: 18 start-page: 259 year: 1988 ident: BIB18 publication-title: Prog. Solid State Chem. contributor: fullname: Sanchez – volume: 22 start-page: 162 year: 1995 end-page: 171 ident: BIB4 publication-title: Aerosol Sci. Technol. contributor: fullname: Partch – volume: 272 start-page: 427 year: 1994 end-page: 432 ident: BIB9 publication-title: Colloid Polym. Sci. contributor: fullname: Cawdery – volume: 71 start-page: 6407 year: 1993 end-page: 6413 ident: BIB5 publication-title: J. Appl. Phys. contributor: fullname: Yamanaka – volume: 64 start-page: 1703 year: 1992 end-page: 1707 ident: BIB8 publication-title: Pure Appl. Chem. contributor: fullname: Matijevic – volume: 19 start-page: 929 year: 1995 end-page: 941 ident: BIB16 publication-title: New J. Chem. contributor: fullname: Sanchez – volume: 11 start-page: 2652 year: 1995 end-page: 2660 ident: BIB11 publication-title: Langmuir contributor: fullname: Claesson – volume: 29 start-page: 1 year: 1994 end-page: 13 ident: BIB15 publication-title: Mater. Res. Bull. contributor: fullname: Sanchez – volume: 12 start-page: 4449 year: 1996 end-page: 4454 ident: BIB12 publication-title: Langmuir contributor: fullname: Rosenholm – volume: 117 start-page: 1139 year: 1995 end-page: 1140 ident: BIB10 publication-title: J. Am. Chem. Soc. contributor: fullname: Kagawa – volume: 111 start-page: 5618 year: 1989 end-page: 5622 ident: BIB14 publication-title: J. Am. Chem. Soc. contributor: fullname: Okahata – volume: 48 start-page: 3692 year: 1993 end-page: 3704 ident: BIB6 publication-title: Phys. Rev. E contributor: fullname: Cabane – volume: 6 start-page: 1148 year: 1990 end-page: 1153 ident: BIB13 publication-title: Langmuir contributor: fullname: Ariga – volume: 6 start-page: 1148 year: 1990 ident: 10.1016/S0927-7757(98)00328-8_BIB13 publication-title: Langmuir doi: 10.1021/la00096a022 contributor: fullname: Okahata – ident: 10.1016/S0927-7757(98)00328-8_BIB7 doi: 10.1007/978-1-4615-2750-3_2 – volume: 117 start-page: 1139 year: 1995 ident: 10.1016/S0927-7757(98)00328-8_BIB10 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00108a035 contributor: fullname: Moriguchi – volume: 48 start-page: 3692 year: 1993 ident: 10.1016/S0927-7757(98)00328-8_BIB6 publication-title: Phys. Rev. E doi: 10.1103/PhysRevE.48.3692 contributor: fullname: Kallala – volume: 111 start-page: 5618 year: 1989 ident: 10.1016/S0927-7757(98)00328-8_BIB14 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja00197a018 contributor: fullname: Ariga – ident: 10.1016/S0927-7757(98)00328-8_BIB2 – volume: 64 start-page: 1703 year: 1992 ident: 10.1016/S0927-7757(98)00328-8_BIB8 publication-title: Pure Appl. Chem. doi: 10.1351/pac199264111703 contributor: fullname: Matijevic – ident: 10.1016/S0927-7757(98)00328-8_BIB20 – ident: 10.1016/S0927-7757(98)00328-8_BIB3 – volume: 22 start-page: 162 year: 1995 ident: 10.1016/S0927-7757(98)00328-8_BIB4 publication-title: Aerosol Sci. Technol. doi: 10.1080/02786829408959737 contributor: fullname: Mattlevic – volume: 71 start-page: 6407 year: 1993 ident: 10.1016/S0927-7757(98)00328-8_BIB5 publication-title: J. Appl. Phys. doi: 10.1063/1.355142 contributor: fullname: Kolosov – volume: 272 start-page: 427 year: 1994 ident: 10.1016/S0927-7757(98)00328-8_BIB9 publication-title: Colloid Polym. Sci. doi: 10.1007/BF00659455 contributor: fullname: Leon – volume: 12 start-page: 4449 year: 1996 ident: 10.1016/S0927-7757(98)00328-8_BIB12 publication-title: Langmuir doi: 10.1021/la960256b contributor: fullname: Lindèn – volume: 19 start-page: 929 year: 1995 ident: 10.1016/S0927-7757(98)00328-8_BIB16 publication-title: New J. Chem. contributor: fullname: Blanchard – volume: 18 start-page: 259 year: 1988 ident: 10.1016/S0927-7757(98)00328-8_BIB18 publication-title: Prog. Solid State Chem. doi: 10.1016/0079-6786(88)90005-2 contributor: fullname: Livage – volume: 21 start-page: 502 year: 1844 ident: 10.1016/S0927-7757(98)00328-8_BIB1 publication-title: C.R. Acad. Sci. contributor: fullname: Ebelmen – volume: 29 start-page: 1 year: 1994 ident: 10.1016/S0927-7757(98)00328-8_BIB15 publication-title: Mater. Res. Bull. doi: 10.1016/0025-5408(94)90099-X contributor: fullname: Barboux-Doeuff – ident: 10.1016/S0927-7757(98)00328-8_BIB17 – ident: 10.1016/S0927-7757(98)00328-8_BIB19 – volume: 11 start-page: 2652 year: 1995 ident: 10.1016/S0927-7757(98)00328-8_BIB11 publication-title: Langmuir doi: 10.1021/la00007a053 contributor: fullname: Sjoblom |
SSID | ssj0004579 |
Score | 1.6615673 |
Snippet | The present study focuses upon the synthesis of nanometer scale oxide-based titania films from tetrabutoxy titanium according to a two-dimensional sol–gel... |
SourceID | crossref elsevier |
SourceType | Aggregation Database Publisher |
StartPage | 89 |
SubjectTerms | Nanometer scale films Sol–gel process Titania |
Title | Synthesis of nanometer scale oxide-based titania films by a two-dimensional sol–gel process at the air–liquid interface |
URI | https://dx.doi.org/10.1016/S0927-7757(98)00328-8 |
Volume | 149 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Nb9QwELWq9gAcqlJAlI9qDhzg4G4SO7F9rFZUC4heSqXeIn8NsrRNlt1UbVUJ8R_4h_wS7CSrLhLiwNWJR5FnPPOszHsm5I3LeZ4roynKAim3uqLSpBYrZRkKx1nV8ys-n1azc_7xorzYItM1Fya1VY65f8jpfbYeRybjak4WIUzOMlUIIUqhIuZhhUyEXx6LUYzpo-_5hmL4qLdXCJrevmfxDBb6wbdKvuuNUPn3-rRRc072yO4IFuF4-J7HZMs3--TBdH1H2z55tCEn-ITcnd02Ec-twgpahEY37WVqdoFV9IOH9iY4T1PVcpCYZU3QgGF-uQJzCxq665a6JPU_yHRAjMlfP35-9XNYDFwC0B1E66DDMj6Yh29XwUFSm1iitv4pOT95_2U6o-PlCtSykncUS4lGCFMZZkpMv0MdywwanyvE3Atms8xhPO4UaHmppI-F3ObodMQTGHc5e0a2m7bxzwkgrxjT2qbjCle80joTTkdo4izTVpgDcrRe0noxaGjU981l0Qd18kGtZN37oJYHRK4Xvv4jGOqY5_899cX_T31JHg6aDJzm5Suy3S2v_OuIODpz2IfUIdk5_vBpdvobcFfU1w |
link.rule.ids | 315,786,790,4521,24144,27957,27958,45620,45714 |
linkProvider | Elsevier |
linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3NTtwwELYoPVAOVQutoL9z6KEczCaxE9tHtCraUuACSNws_1aWlmTZDWpRparv0Dfsk2AnWbGVqh64OvEomhnPfFZmvkHog81pngutsOeFx9SoCnOdSqyEIZ5ZSqquv-LktJpc0KPL8nINjZe9MKmscoj9fUzvovWwMhq0OZqFMDrLRMEYK5mImIcUnD9CjxOcT_Mb9n_mK5ThA-FewXB6_b6NpxfRLX4UfK-Tgvm_E9RK0jl8hp4OaBEO-g96jtZcvYU2xsshbVtoc4VPcBv9OLutI6BbhAU0HmpVN1ep2gUW0RAOmu_BOpzSloXUWlYHBT5Mrxagb0FB-63BNnH99zwdEJ3yz6_fX90UZn0zAagWonRQYR4fTMP1TbCQ6CbmXhn3Al0cfjofT_AwXQEbUtIW-5J7zZiuNNGlT_9DLcm01y4X3ueOEZNl1sf7TuENLQV3MZOb3FsVAYWPx5y8ROt1U7sdBJ5WhChl0n2FCloplTGrIjaxhijD9C7aX6pUznoSDXlfXRZtIJMNpOCys4Hku4gvFS__8gYZA_3_t756-Nb3aGNyfnIsjz-ffnmNnvQEDRTn5Ru03s5v3NsIP1r9rnOvO32u1mk |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Synthesis+of+nanometer+scale+oxide-based+titania+films+by+a+two-dimensional+sol%E2%80%93gel+process+at+the+air%E2%80%93liquid+interface&rft.jtitle=Colloids+and+surfaces.+A%2C+Physicochemical+and+engineering+aspects&rft.au=Facca%2C+F&rft.au=Puccetti%2C+G&rft.au=Leblanc%2C+R.M&rft.date=1999-04-15&rft.pub=Elsevier+B.V&rft.issn=0927-7757&rft.eissn=1873-4359&rft.volume=149&rft.issue=1&rft.spage=89&rft.epage=98&rft_id=info:doi/10.1016%2FS0927-7757%2898%2900328-8&rft.externalDocID=S0927775798003288 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0927-7757&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0927-7757&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0927-7757&client=summon |