Elimination of trichloroanisoles by UV/H2O2: Kinetics, degradation mechanism, water matrix effects and toxicity assessment

The elimination of 2,3,6-trichloroanisole (2,3,6-TCA), which produces a musty-earthy off-odor in water, by an ultraviolet (UV)/H2O2 process was assessed. The removal of 88.1% of 2,3,6-TCA in ultrapure water (UPW) was achieved using an initial 2,3,6-TCA concentration of 1 μg L−1 (4.73 nM), a H2O2 con...

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Published inChemosphere (Oxford) Vol. 230; pp. 258 - 267
Main Authors Zhu, Huanhuan, Jia, Ruibao, Sun, Shaohua, Feng, Guixue, Wang, Mingquan, Zhao, Qinghua, Xin, Xiaodong, Zhou, Anran
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.09.2019
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Abstract The elimination of 2,3,6-trichloroanisole (2,3,6-TCA), which produces a musty-earthy off-odor in water, by an ultraviolet (UV)/H2O2 process was assessed. The removal of 88.1% of 2,3,6-TCA in ultrapure water (UPW) was achieved using an initial 2,3,6-TCA concentration of 1 μg L−1 (4.73 nM), a H2O2 concentration of 20 mg L−1 (0.588 mM), a UV intensity of 1.44 mW cm−2 and a pH of 8.2. The reaction was found to be pseudo first order with a rate constant (kobs) of 0.0340 min−1. Both the removal efficiency and kobs increased significantly upon increasing the H2O2 concentration from 10 to 50 mg L−1. The second order rate constant (kHO·,2,3,6-TCA) in competition kinetic trials was determined to be 8.17 × 107 M−1s−1. Degradation products generated during both the UV photolysis and UV/H2O2 treatment of 2,3,6-TCA solutions were analyzed using ultrahigh resolution gas chromatography/mass spectrometry, and the degradation mechanism was proposed. The toxicities of water solutions during both processes were assessed via a luminescence method in conjunction with Vibrio fischeri. The pH and Cl−, HCO3− and natural organic matter concentrations of the aqueous medium were all found to significantly affect the removal of 2,3,6-TCA. The degradation rates of trichloroanisoles (TCAs) in real-world water samples demonstrated that UV/H2O2 has significant potential with regard to controlling TCAs as pollutants in water. [Display omitted] •2,3,6-trichloroanisole as trichloroanisole T&O compound was firstly studied.•UV/H2O2 was of great validity to control trichloroanisole pollution.•Ultrahigh resolution GC/MS facilitated degradation mechanism investigation.•Toxic degradation products generated during both UV photolysis and indirect oxidation.
AbstractList The elimination of 2,3,6-trichloroanisole (2,3,6-TCA), which produces a musty-earthy off-odor in water, by an ultraviolet (UV)/H2O2 process was assessed. The removal of 88.1% of 2,3,6-TCA in ultrapure water (UPW) was achieved using an initial 2,3,6-TCA concentration of 1 μg L−1 (4.73 nM), a H2O2 concentration of 20 mg L−1 (0.588 mM), a UV intensity of 1.44 mW cm−2 and a pH of 8.2. The reaction was found to be pseudo first order with a rate constant (kobs) of 0.0340 min−1. Both the removal efficiency and kobs increased significantly upon increasing the H2O2 concentration from 10 to 50 mg L−1. The second order rate constant (kHO·,2,3,6-TCA) in competition kinetic trials was determined to be 8.17 × 107 M−1s−1. Degradation products generated during both the UV photolysis and UV/H2O2 treatment of 2,3,6-TCA solutions were analyzed using ultrahigh resolution gas chromatography/mass spectrometry, and the degradation mechanism was proposed. The toxicities of water solutions during both processes were assessed via a luminescence method in conjunction with Vibrio fischeri. The pH and Cl−, HCO3− and natural organic matter concentrations of the aqueous medium were all found to significantly affect the removal of 2,3,6-TCA. The degradation rates of trichloroanisoles (TCAs) in real-world water samples demonstrated that UV/H2O2 has significant potential with regard to controlling TCAs as pollutants in water. [Display omitted] •2,3,6-trichloroanisole as trichloroanisole T&O compound was firstly studied.•UV/H2O2 was of great validity to control trichloroanisole pollution.•Ultrahigh resolution GC/MS facilitated degradation mechanism investigation.•Toxic degradation products generated during both UV photolysis and indirect oxidation.
Author Jia, Ruibao
Feng, Guixue
Wang, Mingquan
Xin, Xiaodong
Zhao, Qinghua
Sun, Shaohua
Zhou, Anran
Zhu, Huanhuan
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Keywords Water matrix effects
Trichloroanisoles
Degradation mechanism
Kinetics
Toxicity assessment
Advanced oxidation process
Language English
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Snippet The elimination of 2,3,6-trichloroanisole (2,3,6-TCA), which produces a musty-earthy off-odor in water, by an ultraviolet (UV)/H2O2 process was assessed. The...
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StartPage 258
SubjectTerms Advanced oxidation process
Degradation mechanism
Kinetics
Toxicity assessment
Trichloroanisoles
Water matrix effects
Title Elimination of trichloroanisoles by UV/H2O2: Kinetics, degradation mechanism, water matrix effects and toxicity assessment
URI https://dx.doi.org/10.1016/j.chemosphere.2019.05.052
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