Progress in the extraction and separation of rare earths and related metals with novel extractants: A review

Rare earths (REs) play a key role in high-tech fields and the associated thorium is a vital element for nuclear energy. However, to be used in high-tech industry or nuclear energy, these elements must first be recovered from the deposits and purified. As solvent extraction is the main technology for...

Full description

Saved in:
Bibliographic Details
Published inScience China. Technological sciences Vol. 61; no. 9; pp. 1319 - 1328
Main Authors Kuang, ShengTing, Liao, WuPing
Format Journal Article
LanguageEnglish
Published Beijing Science China Press 01.09.2018
Springer Nature B.V
Subjects
Online AccessGet full text

Cover

Loading…
Abstract Rare earths (REs) play a key role in high-tech fields and the associated thorium is a vital element for nuclear energy. However, to be used in high-tech industry or nuclear energy, these elements must first be recovered from the deposits and purified. As solvent extraction is the main technology for the recovery and purification of the metals, the review mainly presents our recent works on the extraction and separation of tetravalent cerium cation by neutral α-aminophosphonates, the individual rare earth separation by α-aminophosphonic acids, and the continuous preparation of high-purity thorium. The extraction and separation of some other metals are also discussed.
AbstractList Rare earths (REs) play a key role in high-tech fields and the associated thorium is a vital element for nuclear energy. However, to be used in high-tech industry or nuclear energy, these elements must first be recovered from the deposits and purified. As solvent extraction is the main technology for the recovery and purification of the metals, the review mainly presents our recent works on the extraction and separation of tetravalent cerium cation by neutral α-aminophosphonates, the individual rare earth separation by α-aminophosphonic acids, and the continuous preparation of high-purity thorium. The extraction and separation of some other metals are also discussed.
Author Liao, WuPing
Kuang, ShengTing
Author_xml – sequence: 1
  givenname: ShengTing
  surname: Kuang
  fullname: Kuang, ShengTing
  organization: State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, School of Applied Chemistry and Engineering, University of Science and Technology of China
– sequence: 2
  givenname: WuPing
  surname: Liao
  fullname: Liao, WuPing
  email: wpliao@ciac.ac.cn
  organization: State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
BookMark eNp1kE9LAzEQxYMoWGs_gLeA59Vks9ndeCvFf1DQg57DbHa23bLN1iRt9dubdhVPhoHMML_3Bt4FObW9RUKuOLvhjBW3nvNM8ITxMlGpkgk7ISNe5irhirHT2OdFlhQi5edk4v2KxSdKxXg2It2r6xcOvaetpWGJFD-DAxPa3lKwNfW4AQfHsW-oAxcJcGHpj1uHHQSs6RoDdJ7u27Cktt9h92sDNvg7Oo3grsX9JTlrIoeTn39M3h_u32ZPyfzl8Xk2nSdGSBGSpkwVqqJQEvIsh6oqcmOggbLKjZIGS5kiz1EAVmVl6gaqWjKTGqxRQtVkYkyuB9-N6z-26INe9Vtn40md8pTnmRSxxoQPlHG99w4bvXHtGtyX5kwfctVDrjrmqg-5ahY16aDxkbULdH_O_4u-AXZ1fzY
CitedBy_id crossref_primary_10_3390_met13030600
crossref_primary_10_1016_j_seppur_2022_122683
crossref_primary_10_1016_j_mineng_2022_107538
crossref_primary_10_1007_s11431_020_1624_8
crossref_primary_10_1016_j_hydromet_2021_105558
crossref_primary_10_1080_10408347_2021_2000851
crossref_primary_10_1007_s10904_023_02872_w
crossref_primary_10_1016_j_molliq_2023_122785
crossref_primary_10_1016_j_cej_2022_136054
crossref_primary_10_1038_s42004_019_0253_x
crossref_primary_10_1016_j_jre_2021_05_003
crossref_primary_10_1007_s10967_023_08769_9
crossref_primary_10_3389_fchem_2020_511502
crossref_primary_10_3390_molecules27113465
crossref_primary_10_1080_15422119_2020_1792930
crossref_primary_10_1016_j_jre_2023_04_016
crossref_primary_10_1016_j_colsurfa_2024_133339
crossref_primary_10_1016_j_colsurfa_2022_129089
crossref_primary_10_1016_j_comptc_2024_114568
crossref_primary_10_3390_separations11010033
crossref_primary_10_1016_j_seppur_2023_123876
crossref_primary_10_1016_j_hydromet_2019_06_002
crossref_primary_10_1016_j_hydromet_2020_105343
crossref_primary_10_1016_j_hydromet_2023_106035
crossref_primary_10_1134_S1070363221010096
crossref_primary_10_1007_s11431_019_1490_y
crossref_primary_10_1016_j_seppur_2024_128599
crossref_primary_10_1007_s12649_019_00783_x
crossref_primary_10_1016_j_hydromet_2024_106264
crossref_primary_10_1016_j_seppur_2024_126952
crossref_primary_10_1080_01614940_2023_2168352
Cites_doi 10.1002/jctb.4035
10.1016/j.cjche.2015.06.001
10.1080/10426507.2012.740691
10.1016/j.jre.2017.09.007
10.1016/0022-1902(70)80131-2
10.1016/j.hydromet.2016.11.009
10.1016/0022-5088(68)90102-1
10.1080/07366299.2017.1292025
10.1038/492031a
10.1016/j.hydromet.2017.04.001
10.1007/s11176-005-0397-5
10.1016/j.hydromet.2017.09.011
10.1016/j.hydromet.2018.04.005
10.1016/S1002-0721(12)60195-1
10.1134/S1070363212010069
10.1080/07366299.2018.1431079
10.1016/S1002-0721(16)60170-9
10.1016/0022-1902(71)80242-7
10.1134/S107036320912007X
10.1016/j.hydromet.2016.04.008
10.1007/s10967-013-2643-3
ContentType Journal Article
Copyright Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018
Copyright Springer Science & Business Media 2018
Copyright_xml – notice: Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018
– notice: Copyright Springer Science & Business Media 2018
DBID AAYXX
CITATION
DOI 10.1007/s11431-018-9295-0
DatabaseName CrossRef
DatabaseTitle CrossRef
DatabaseTitleList

DeliveryMethod fulltext_linktorsrc
Discipline Engineering
EISSN 1869-1900
EndPage 1328
ExternalDocumentID 10_1007_s11431_018_9295_0
GroupedDBID -5B
-5G
-BR
-EM
-Y2
-~C
.VR
06D
0VY
1N0
29~
2B.
2C.
2J2
2JN
2JY
2KG
2KM
2LR
2VQ
2~H
30V
4.4
406
40D
40E
5VR
5VS
8TC
8UJ
92E
92I
92Q
93N
95-
95.
96X
AAAVM
AABHQ
AAFGU
AAHNG
AAIAL
AAJKR
AANZL
AAPBV
AARHV
AARTL
AATNV
AATVU
AAUYE
AAWCG
AAYFA
AAYIU
AAYQN
AAYTO
ABBBX
ABDZT
ABECU
ABFGW
ABFTD
ABFTV
ABHQN
ABJNI
ABJOX
ABKAS
ABKCH
ABKTR
ABMQK
ABNWP
ABQBU
ABSXP
ABTEG
ABTHY
ABTKH
ABTMW
ABWNU
ABXPI
ACBMV
ACBRV
ACBXY
ACBYP
ACGFS
ACHSB
ACHXU
ACIGE
ACIPQ
ACIWK
ACKNC
ACMDZ
ACMLO
ACOKC
ACOMO
ACSNA
ACTTH
ACVWB
ACWMK
ADHIR
ADINQ
ADKNI
ADKPE
ADMDM
ADOXG
ADRFC
ADTPH
ADURQ
ADYFF
ADYOE
ADZKW
AEBTG
AEFTE
AEGAL
AEGNC
AEJHL
AEJRE
AEOHA
AEPYU
AESKC
AESTI
AETLH
AEVLU
AEVTX
AEXYK
AFLOW
AFNRJ
AFQWF
AFUIB
AFWTZ
AFYQB
AFZKB
AGAYW
AGDGC
AGGBP
AGJBK
AGMZJ
AGQMX
AGWIL
AGWZB
AGYKE
AHAVH
AHBYD
AHSBF
AHYZX
AIAKS
AIIXL
AILAN
AIMYW
AITGF
AJBLW
AJDOV
AJRNO
AJZVZ
AKQUC
ALMA_UNASSIGNED_HOLDINGS
ALWAN
AMKLP
AMTXH
AMXSW
AMYLF
AOCGG
ARMRJ
ASPBG
AVWKF
AXYYD
AZFZN
B-.
BDATZ
CAG
CCEZO
CEKLB
CHBEP
COF
CSCUP
CW9
DDRTE
DNIVK
DPUIP
EBLON
EBS
EIOEI
EJD
ESBYG
FA0
FEDTE
FERAY
FFXSO
FIGPU
FINBP
FNLPD
FRRFC
FSGXE
FWDCC
GGCAI
GGRSB
GJIRD
GNWQR
GQ6
GQ7
HG6
HMJXF
HRMNR
HVGLF
HZ~
IJ-
IKXTQ
IWAJR
IXD
I~Z
J-C
JBSCW
JZLTJ
KOV
LLZTM
MA-
N2Q
NB0
NPVJJ
NQJWS
O9J
P9P
PF0
PT4
QOS
R89
RIG
ROL
RSV
S16
S3B
SAP
SCL
SEG
SHX
SISQX
SJYHP
SNE
SNPRN
SNX
SOHCF
SOJ
SPISZ
SRMVM
SSLCW
STPWE
SZN
TCJ
TGP
TR2
TSG
TUC
U2A
UG4
UNUBA
UOJIU
UTJUX
UZXMN
VC2
VFIZW
W23
W48
WK8
YLTOR
Z5O
Z7R
Z7S
Z7V
Z7X
Z7Y
Z7Z
Z83
Z85
Z88
ZMTXR
~A9
-SC
-S~
0R~
AACDK
AAJBT
AASML
AAXDM
AAYXX
ABAKF
ACAOD
ACDTI
ACZOJ
AEFQL
AEMSY
AGQEE
AGRTI
AIGIU
CAJEC
CITATION
CJPJV
H13
Q--
U1G
U5M
ID FETCH-LOGICAL-c353t-f829e97795a646abb76ccafa8b6c95ce852e16e3aeb8bcdfabd50c2cede5abf43
IEDL.DBID AGYKE
ISSN 1674-7321
IngestDate Thu Oct 10 17:57:27 EDT 2024
Thu Sep 12 17:02:41 EDT 2024
Sat Dec 16 12:00:25 EST 2023
IsPeerReviewed true
IsScholarly true
Issue 9
Keywords extractants
extraction
separation
thorium
rare earths
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c353t-f829e97795a646abb76ccafa8b6c95ce852e16e3aeb8bcdfabd50c2cede5abf43
PQID 2121645345
PQPubID 2043625
PageCount 10
ParticipantIDs proquest_journals_2121645345
crossref_primary_10_1007_s11431_018_9295_0
springer_journals_10_1007_s11431_018_9295_0
PublicationCentury 2000
PublicationDate 2018-09-01
PublicationDateYYYYMMDD 2018-09-01
PublicationDate_xml – month: 09
  year: 2018
  text: 2018-09-01
  day: 01
PublicationDecade 2010
PublicationPlace Beijing
PublicationPlace_xml – name: Beijing
– name: Heidelberg
PublicationTitle Science China. Technological sciences
PublicationTitleAbbrev Sci. China Technol. Sci
PublicationYear 2018
Publisher Science China Press
Springer Nature B.V
Publisher_xml – name: Science China Press
– name: Springer Nature B.V
References Zhao, Zhang, Li (CR17) 2018; 36
Kuang, Zhang, Li (CR15) 2017; 167
Li, Lu, Bai (CR37) 2012; 30
Ashley, Parks, Nuttall (CR28) 2012; 492
Liao, Zhang, Li (CR20) 2014
Cherkasov, Vasil’ev, Garifzyanov (CR11) 2008; 78
Jagodic, Herak, Radoševic (CR3) 1968; 15
Li, Wang, Liao (CR32) 2012
Cherkasov, Garifzyanov, Leont’ev (CR1) 2009; 79
Christensen, Prater (CR29) 1960
Koshimoto, Oshima, Ohto (CR12) 2011; 18
Kuang, Zhang, Li (CR18) 2018; 36
Herak, Jagodic, Herak (CR5) 1967
Liao, Zhang, Wang (CR34) 2013
Garifzyanov, Zakharov, Kryukov (CR9) 2005; 75
Jagodic, Herak, Šipalo (CR6) 1971; 33
Jagodic, Herak (CR7) 1970; 32
Wei, Li, Zhang (CR14) 2017; 35
Li, Wang, Liao (CR33) 2016
Lu, Bi, Bai (CR36) 2013; 88
Liao, Kuang, Wu (CR23) 2017
Chen (CR24) 2017
Davletshina, Garifzyanov, Cherkasov (CR10) 2013; 188
Cherkasov, Garifzyanov, Bazanova (CR8) 2012; 82
Liao, Kuang, Xue (CR21) 2016
Chen, Zhang, Kuang (CR16) 2017; 169
Liao, Wang, Sun (CR35) 2012
Lu, Wei, Zhang (CR38) 2016; 163
Li, Wang, Liao (CR31) 2011
Herak, Jagodic (CR4) 1964
Liao, Li, Zhang (CR39) 2014
Lu, Zhang, Li (CR13) 2017; 35
Liao, Lu, Zhang (CR19) 2014
Liao, Chen, Zhang (CR25) 2016
Sasaki, Matsuo, Oshima (CR2) 2016; 24
Wang, Li, Liao (CR30) 2013; 298
Kuang, Zhang, Li (CR27) 2017; 174
Liao, Zhang, Li (CR26) 2016
Le, Kuang, Zhang (CR22) 2018; 178
V Jagodic (9295_CR6) 1971; 33
S Chen (9295_CR24) 2017
Y Lu (9295_CR36) 2013; 88
Y Lu (9295_CR13) 2017; 35
W Liao (9295_CR21) 2016
M Herak (9295_CR4) 1964
D Li (9295_CR31) 2011
W Liao (9295_CR23) 2017
D Li (9295_CR33) 2016
R A Cherkasov (9295_CR1) 2009; 79
C C Christensen (9295_CR29) 1960
W Liao (9295_CR26) 2016
Y Sasaki (9295_CR2) 2016; 24
S Kuang (9295_CR27) 2017; 174
Y Lu (9295_CR38) 2016; 163
W Liao (9295_CR34) 2013
S Chen (9295_CR16) 2017; 169
W Le (9295_CR22) 2018; 178
R A Cherkasov (9295_CR8) 2012; 82
Q Zhao (9295_CR17) 2018; 36
V Jagodic (9295_CR3) 1968; 15
R A Cherkasov (9295_CR11) 2008; 78
A Koshimoto (9295_CR12) 2011; 18
W Liao (9295_CR39) 2014
W Liao (9295_CR19) 2014
A R Garifzyanov (9295_CR9) 2005; 75
H Wei (9295_CR14) 2017; 35
N Davletshina (9295_CR10) 2013; 188
Y Wang (9295_CR30) 2013; 298
S Kuang (9295_CR18) 2018; 36
S Kuang (9295_CR15) 2017; 167
W Liao (9295_CR25) 2016
S F Ashley (9295_CR28) 2012; 492
H Herak (9295_CR5) 1967
V Jagodic (9295_CR7) 1970; 32
W Liao (9295_CR20) 2014
D Li (9295_CR32) 2012
W Liao (9295_CR35) 2012
Y Li (9295_CR37) 2012; 30
References_xml – volume: 88
  start-page: 1836
  year: 2013
  end-page: 1840
  ident: CR36
  article-title: Extraction and separation of thorium and rare earths from nitrate medium with p-phosphorylated calixarene
  publication-title: J Chem Technol Biotechnol
  doi: 10.1002/jctb.4035
  contributor:
    fullname: Bai
– year: 2016
  ident: CR21
  publication-title: Use and method of neutral phosphine extractant used for extracting and separating cerium (IV) or thorium (IV)
  contributor:
    fullname: Xue
– year: 2012
  ident: CR32
  publication-title: Method of separation and purification of thorium
  contributor:
    fullname: Liao
– year: 2017
  ident: CR24
  publication-title: Synthesis of novel P-containing extractants and the application in the extraction and separation of zirconium and hafnium
  contributor:
    fullname: Chen
– volume: 24
  start-page: 232
  year: 2016
  end-page: 236
  ident: CR2
  article-title: Selective extraction of In (III), Ga (III) and Zn (II) using novel extractant with phosphinic acid
  publication-title: Chin J Chem Eng
  doi: 10.1016/j.cjche.2015.06.001
  contributor:
    fullname: Oshima
– year: 2011
  ident: CR31
  publication-title: Method of purification of thorium
  contributor:
    fullname: Liao
– year: 2013
  ident: CR34
  publication-title: Preparation method of extraction resin and high-purity thorium
  contributor:
    fullname: Wang
– start-page: 36
  year: 1964
  ident: CR4
  article-title: Solvent extraction and separation of europium (III) and terbium (III) from uranium (VI) by monooctyl anilinobenzylphosphonate
  publication-title: Croat Chem Acta
  contributor:
    fullname: Jagodic
– volume: 188
  start-page: 4
  year: 2013
  end-page: 6
  ident: CR10
  article-title: The active transport of ions of rare-earth elements, alkali metals, Al(III), and Mg(II) with new lipophilic N,N-Bis[(Dihexylphosphoryl)Methyl]Octylamine
  publication-title: Phosphorus Sulfur Silicon Related Elem
  doi: 10.1080/10426507.2012.740691
  contributor:
    fullname: Cherkasov
– volume: 36
  start-page: 304
  year: 2018
  end-page: 310
  ident: CR18
  article-title: Extraction and separation of heavy rare earths from chloride medium by a-aminophosphonic acid HEHAPP
  publication-title: J Rare Earths
  doi: 10.1016/j.jre.2017.09.007
  contributor:
    fullname: Li
– volume: 32
  start-page: 1323
  year: 1970
  end-page: 1332
  ident: CR7
  article-title: Synthesis and physical properties of a novel aminophosphonic acid as an extracting agent for metals
  publication-title: J InOrg Nucl Chem
  doi: 10.1016/0022-1902(70)80131-2
  contributor:
    fullname: Herak
– volume: 167
  start-page: 107
  year: 2017
  end-page: 114
  ident: CR15
  article-title: Selective extraction and separation of Ce(IV) from thorium and trivalent rare earths in sulfate medium by an a-aminophosphonate extractant
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2016.11.009
  contributor:
    fullname: Li
– volume: 15
  start-page: 371
  year: 1968
  end-page: 375
  ident: CR3
  article-title: Separation of lanthanum from barium by solvent extraction with the monooctyl ester of anilinobenzylphosphonic acid
  publication-title: J Less Common Met
  doi: 10.1016/0022-5088(68)90102-1
  contributor:
    fullname: Radoševic
– volume: 35
  start-page: 117
  year: 2017
  end-page: 129
  ident: CR14
  article-title: Selective extraction and separation of Ce (IV) and Th (IV) from RE(III) in sulfate medium using Di(2-ethylhexyl)-N-heptylaminomethylphosphonate
  publication-title: Solvent Extraction Ion Exchange
  doi: 10.1080/07366299.2017.1292025
  contributor:
    fullname: Zhang
– volume: 492
  start-page: 31
  year: 2012
  end-page: 33
  ident: CR28
  article-title: Thorium fuel has risks
  publication-title: Nature
  doi: 10.1038/492031a
  contributor:
    fullname: Nuttall
– volume: 169
  start-page: 607
  year: 2017
  end-page: 611
  ident: CR16
  article-title: Separation of zirconium from hafnium in sulfate medium using solvent extraction with a new reagent BEAP
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2017.04.001
  contributor:
    fullname: Kuang
– volume: 78
  start-page: 1167
  year: 2008
  end-page: 1171
  ident: CR11
  article-title: Synthesis, transport, and ionophoric properties of α,β-diphosphorylated aza podands
  publication-title: IV. Induced membrane transport of alkali and alkaline-earth metal ions. Russ J Gen Chem
  contributor:
    fullname: Garifzyanov
– year: 2014
  ident: CR20
  publication-title: A method of extraction and separation of cerium, fluorine and thorium
  contributor:
    fullname: Li
– year: 2016
  ident: CR26
  publication-title: Use and method of neutral amino groupcontaining phosphorus extractants used for extracting and separating uranium
  contributor:
    fullname: Li
– volume: 18
  start-page: 137
  year: 2011
  end-page: 147
  ident: CR12
  article-title: Synthesis of phosphonic acid extractants and selective extraction of In(III) and Ga(III) from acidic media containing Zn(II)
  publication-title: Sol Extr Res Devel Jpn
  contributor:
    fullname: Ohto
– year: 2017
  ident: CR23
  publication-title: Use and method of neutral amino group-containing phosphorus extractants used for extracting and recovering Cu(II)
  contributor:
    fullname: Wu
– year: 2014
  ident: CR39
  publication-title: Extraction and separation Th4+ by neutral phosphoramidite extractants
  contributor:
    fullname: Zhang
– volume: 75
  start-page: 1208
  year: 2005
  end-page: 1211
  ident: CR9
  article-title: Liquid extraction of noble metal ions with an a-amino phosphonate
  publication-title: Russ J Gen Chem
  doi: 10.1007/s11176-005-0397-5
  contributor:
    fullname: Kryukov
– volume: 174
  start-page: 78
  year: 2017
  end-page: 83
  ident: CR27
  article-title: Synergistic extraction and separation of rare earths from chloride medium by the mixture of HEHAPP and D2EHPA
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2017.09.011
  contributor:
    fullname: Li
– volume: 178
  start-page: 54
  year: 2018
  end-page: 59
  ident: CR22
  article-title: Selective extraction and recovery of scandium from sulfate medium by Cextrant 230
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2018.04.005
  contributor:
    fullname: Zhang
– volume: 30
  start-page: 1142
  year: 2012
  end-page: 1145
  ident: CR37
  article-title: Extraction and separation of thorium and rare earths with 5,11,17,23-tetra (diethoxyphosphoryl)-25,26,27,28-tetraacetoxycalix[ 4]arene
  publication-title: J Rare Earths
  doi: 10.1016/S1002-0721(12)60195-1
  contributor:
    fullname: Bai
– year: 1960
  ident: CR29
  publication-title: Liquid-liquid extraction process for the recovery of high purity thorium oxide
  contributor:
    fullname: Prater
– year: 1967
  ident: CR5
  article-title: Solvent extraction and separation of niobium and tantalum by monoctylester of anilinobenzylphosphonic acid. in, Inst
  publication-title: Ruder Boskovic
  contributor:
    fullname: Herak
– volume: 82
  start-page: 33
  year: 2012
  end-page: 42
  ident: CR8
  article-title: Liquid extraction of some rare earth elements with aminomethylphosphine oxides
  publication-title: Russ J Gen Chem
  doi: 10.1134/S1070363212010069
  contributor:
    fullname: Bazanova
– volume: 36
  start-page: 136
  year: 2018
  end-page: 149
  ident: CR17
  article-title: Solvent extraction and separation of rare earths from chloride media using a-aminophosphonic acid extractant HEHAMP
  publication-title: Solvent Extraction Ion Exchange
  doi: 10.1080/07366299.2018.1431079
  contributor:
    fullname: Li
– volume: 35
  start-page: 34
  year: 2017
  end-page: 40
  ident: CR13
  article-title: Extraction and recovery of cerium (IV) and thorium (IV) from sulphate medium by an a-aminophosphonate extractant
  publication-title: J Rare Earths
  doi: 10.1016/S1002-0721(16)60170-9
  contributor:
    fullname: Li
– volume: 33
  start-page: 2651
  year: 1971
  end-page: 2659
  ident: CR6
  article-title: Solvent extraction study of lanthanum and europium by acidic esters of aminophosphonic acids
  publication-title: J InOrg Nucl Chem
  doi: 10.1016/0022-1902(71)80242-7
  contributor:
    fullname: Šipalo
– year: 2016
  ident: CR25
  publication-title: Use and method of neutral amino group-containing phosphorus extractants used for extracting and separating zirconium (IV) and/or hafnium (IV)
  contributor:
    fullname: Zhang
– year: 2016
  ident: CR33
  publication-title: Process of separating and purifying thorium
  contributor:
    fullname: Liao
– volume: 79
  start-page: 2599
  year: 2009
  end-page: 2605
  ident: CR1
  article-title: Extraction of scandium ions by new aminophosphinyl extractants
  publication-title: Russ J Gen Chem
  doi: 10.1134/S107036320912007X
  contributor:
    fullname: Leont’ev
– year: 2014
  ident: CR19
  publication-title: Extraction and separation Ce4+ by neutral amino group-containing phosphorus extractants
  contributor:
    fullname: Zhang
– year: 2012
  ident: CR35
  publication-title: Method of separation and purification of thorium with calixarene
  contributor:
    fullname: Sun
– volume: 163
  start-page: 192
  year: 2016
  end-page: 197
  ident: CR38
  article-title: Selective extraction and separation of thorium from rare earths by a phosphorodiamidate extractant
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2016.04.008
  contributor:
    fullname: Zhang
– volume: 298
  start-page: 1651
  year: 2013
  end-page: 1657
  ident: CR30
  article-title: Preparation of high-purity thorium by solvent extraction with di-(2-ethylhexyl) 2-ethylhexyl phosphonate
  publication-title: J Radioanal Nucl Chem
  doi: 10.1007/s10967-013-2643-3
  contributor:
    fullname: Liao
– volume: 32
  start-page: 1323
  year: 1970
  ident: 9295_CR7
  publication-title: J InOrg Nucl Chem
  doi: 10.1016/0022-1902(70)80131-2
  contributor:
    fullname: V Jagodic
– volume-title: Process of separating and purifying thorium
  year: 2016
  ident: 9295_CR33
  contributor:
    fullname: D Li
– volume-title: Method of separation and purification of thorium with calixarene
  year: 2012
  ident: 9295_CR35
  contributor:
    fullname: W Liao
– volume: 36
  start-page: 136
  year: 2018
  ident: 9295_CR17
  publication-title: Solvent Extraction Ion Exchange
  doi: 10.1080/07366299.2018.1431079
  contributor:
    fullname: Q Zhao
– volume-title: Preparation method of extraction resin and high-purity thorium
  year: 2013
  ident: 9295_CR34
  contributor:
    fullname: W Liao
– volume-title: Method of separation and purification of thorium
  year: 2012
  ident: 9295_CR32
  contributor:
    fullname: D Li
– volume: 78
  start-page: 1167
  year: 2008
  ident: 9295_CR11
  publication-title: IV. Induced membrane transport of alkali and alkaline-earth metal ions. Russ J Gen Chem
  contributor:
    fullname: R A Cherkasov
– volume-title: Use and method of neutral amino group-containing phosphorus extractants used for extracting and separating zirconium (IV) and/or hafnium (IV)
  year: 2016
  ident: 9295_CR25
  contributor:
    fullname: W Liao
– volume: 35
  start-page: 34
  year: 2017
  ident: 9295_CR13
  publication-title: J Rare Earths
  doi: 10.1016/S1002-0721(16)60170-9
  contributor:
    fullname: Y Lu
– volume: 24
  start-page: 232
  year: 2016
  ident: 9295_CR2
  publication-title: Chin J Chem Eng
  doi: 10.1016/j.cjche.2015.06.001
  contributor:
    fullname: Y Sasaki
– volume: 33
  start-page: 2651
  year: 1971
  ident: 9295_CR6
  publication-title: J InOrg Nucl Chem
  doi: 10.1016/0022-1902(71)80242-7
  contributor:
    fullname: V Jagodic
– volume: 178
  start-page: 54
  year: 2018
  ident: 9295_CR22
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2018.04.005
  contributor:
    fullname: W Le
– volume: 30
  start-page: 1142
  year: 2012
  ident: 9295_CR37
  publication-title: J Rare Earths
  doi: 10.1016/S1002-0721(12)60195-1
  contributor:
    fullname: Y Li
– volume: 492
  start-page: 31
  year: 2012
  ident: 9295_CR28
  publication-title: Nature
  doi: 10.1038/492031a
  contributor:
    fullname: S F Ashley
– volume: 163
  start-page: 192
  year: 2016
  ident: 9295_CR38
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2016.04.008
  contributor:
    fullname: Y Lu
– volume: 79
  start-page: 2599
  year: 2009
  ident: 9295_CR1
  publication-title: Russ J Gen Chem
  doi: 10.1134/S107036320912007X
  contributor:
    fullname: R A Cherkasov
– volume: 82
  start-page: 33
  year: 2012
  ident: 9295_CR8
  publication-title: Russ J Gen Chem
  doi: 10.1134/S1070363212010069
  contributor:
    fullname: R A Cherkasov
– volume: 18
  start-page: 137
  year: 2011
  ident: 9295_CR12
  publication-title: Sol Extr Res Devel Jpn
  contributor:
    fullname: A Koshimoto
– start-page: 36
  volume-title: Croat Chem Acta
  year: 1964
  ident: 9295_CR4
  contributor:
    fullname: M Herak
– volume: 36
  start-page: 304
  year: 2018
  ident: 9295_CR18
  publication-title: J Rare Earths
  doi: 10.1016/j.jre.2017.09.007
  contributor:
    fullname: S Kuang
– volume-title: Use and method of neutral phosphine extractant used for extracting and separating cerium (IV) or thorium (IV)
  year: 2016
  ident: 9295_CR21
  contributor:
    fullname: W Liao
– volume-title: Use and method of neutral amino groupcontaining phosphorus extractants used for extracting and separating uranium
  year: 2016
  ident: 9295_CR26
  contributor:
    fullname: W Liao
– volume-title: A method of extraction and separation of cerium, fluorine and thorium
  year: 2014
  ident: 9295_CR20
  contributor:
    fullname: W Liao
– volume: 188
  start-page: 4
  year: 2013
  ident: 9295_CR10
  publication-title: Phosphorus Sulfur Silicon Related Elem
  doi: 10.1080/10426507.2012.740691
  contributor:
    fullname: N Davletshina
– volume-title: Extraction and separation Ce4+ by neutral amino group-containing phosphorus extractants
  year: 2014
  ident: 9295_CR19
  contributor:
    fullname: W Liao
– volume: 174
  start-page: 78
  year: 2017
  ident: 9295_CR27
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2017.09.011
  contributor:
    fullname: S Kuang
– volume-title: Use and method of neutral amino group-containing phosphorus extractants used for extracting and recovering Cu(II)
  year: 2017
  ident: 9295_CR23
  contributor:
    fullname: W Liao
– volume: 15
  start-page: 371
  year: 1968
  ident: 9295_CR3
  publication-title: J Less Common Met
  doi: 10.1016/0022-5088(68)90102-1
  contributor:
    fullname: V Jagodic
– volume: 167
  start-page: 107
  year: 2017
  ident: 9295_CR15
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2016.11.009
  contributor:
    fullname: S Kuang
– volume: 298
  start-page: 1651
  year: 2013
  ident: 9295_CR30
  publication-title: J Radioanal Nucl Chem
  doi: 10.1007/s10967-013-2643-3
  contributor:
    fullname: Y Wang
– volume: 75
  start-page: 1208
  year: 2005
  ident: 9295_CR9
  publication-title: Russ J Gen Chem
  doi: 10.1007/s11176-005-0397-5
  contributor:
    fullname: A R Garifzyanov
– volume-title: Ruder Boskovic
  year: 1967
  ident: 9295_CR5
  contributor:
    fullname: H Herak
– volume: 35
  start-page: 117
  year: 2017
  ident: 9295_CR14
  publication-title: Solvent Extraction Ion Exchange
  doi: 10.1080/07366299.2017.1292025
  contributor:
    fullname: H Wei
– volume: 169
  start-page: 607
  year: 2017
  ident: 9295_CR16
  publication-title: Hydrometallurgy
  doi: 10.1016/j.hydromet.2017.04.001
  contributor:
    fullname: S Chen
– volume-title: Extraction and separation Th4+ by neutral phosphoramidite extractants
  year: 2014
  ident: 9295_CR39
  contributor:
    fullname: W Liao
– volume: 88
  start-page: 1836
  year: 2013
  ident: 9295_CR36
  publication-title: J Chem Technol Biotechnol
  doi: 10.1002/jctb.4035
  contributor:
    fullname: Y Lu
– volume-title: Synthesis of novel P-containing extractants and the application in the extraction and separation of zirconium and hafnium
  year: 2017
  ident: 9295_CR24
  contributor:
    fullname: S Chen
– volume-title: Liquid-liquid extraction process for the recovery of high purity thorium oxide
  year: 1960
  ident: 9295_CR29
  contributor:
    fullname: C C Christensen
– volume-title: Method of purification of thorium
  year: 2011
  ident: 9295_CR31
  contributor:
    fullname: D Li
SSID ssj0000389014
Score 2.3874497
SecondaryResourceType review_article
Snippet Rare earths (REs) play a key role in high-tech fields and the associated thorium is a vital element for nuclear energy. However, to be used in high-tech...
SourceID proquest
crossref
springer
SourceType Aggregation Database
Publisher
StartPage 1319
SubjectTerms Cerium
Engineering
High tech industries
Nuclear energy
Nuclear engineering
Nuclear reactors
Rare earth elements
Review
Separation
Solvent extraction
Thorium
Title Progress in the extraction and separation of rare earths and related metals with novel extractants: A review
URI https://link.springer.com/article/10.1007/s11431-018-9295-0
https://www.proquest.com/docview/2121645345
Volume 61
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV07T8MwED71scDAG1EolQcmUKrUifNgixClAoEYqFSmyHYcgVpS1KQM_HrOeRCeQ8fIlqX4znef7fs-A5yYnvRjhMqGyyJh2DHzDeFazKAywnyPIZMJzUa-vXNGY_t6wiYNoJ9HF8m0X91I5oG65rphZtc7X1yfVLOKm9BmWu-rBe3g6vGmPlnRknFmLuqtK-wN16KD6jrzr3G-J6QaZf64GM3zzXCz4ACmuUyhLjOZ9peZ6Mv33yKOK_zKFmyU8JMEhb9sQ0MlO7D-RZRwF2b3umQLAyB5TgjCQ4Lhe1HQHwhPIpKqQi4cP-cxwb029kD_e0rz1pwboyLyohDVp0Qf85Jk_qZm1TC67uacBKTgzOzBeHj5cDEyyjcZDGkxKzNij_oKMaPPuGM7XAjXQR-IuScc6TP9BipVA0dZXAlPyCjmImKmpFJFinER29Y-tJJ5og6AmK7rxYhOTZ9GtpID32auLynnnulwxBkdOK0ME74W0hthLbKspzDEKQz1FIZmB7qV6cJyFaYhpmXcDTLLZh04q0xRN_872OFKvY9gjWpb5oVnXWhli6U6RqSSiV7pmj1ojmnwAWWi4OU
link.rule.ids 315,786,790,27955,27956,41114,41556,42183,42625,52144,52267
linkProvider Springer Nature
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV07T8MwED5BOwADb0ShgAcmUKrUifNgqxCl0IcYWqlMke04AlFS1LQM_HrOeShQwdAxsmUlvvPdZ_u-LwCXpif9CKGy4bJQGHbEfEO4FjOoDDHfY8hkQrOR-wOnM7Ifx2yc87iTotq9uJJMI3VJdsPUrre-uECpphWvQ9XWCb4C1db9c7c8WtGacWaq6q1L7A3Xos3iPvOvcX5npBJmLt2MpgmnvQPD4lWzOpO3xmIuGvJrScVxxW_Zhe0cgJJW5jF7sKbifdj6IUt4AJMnXbSFIZC8xgQBIsEAPssIEITHIUlUJhiOj9OI4G4be6AHviRpa8qOUSF5V4jrE6IPekk8_VSTYhhdeXNDWiRjzRzCqH03vO0Y-V8ZDGkxa25EHvUVokafccd2uBCug14QcU840mf6L6hUNR1lcSU8IcOIi5CZkkoVKsZFZFtHUImnsToGYrquFyE-NX0a2ko2fZu5vqSce6bDEWnU4KqwTPCRiW8EpcyynsIApzDQUxiYNagXtgvydZgEmJhxP8gsm9XgujBF2fzvYCcr9b6Ajc6w3wt6D4PuKWxSbde0DK0Olflsoc4Qt8zFee6n31zm49A
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV07T8MwELagSAgGxFMUCnhgAlmkTpzEbBVQlVfVgUrdIj8FUkmrJvD7OedBAMHAaNm64Xz2fbbv-4zQqRcrbgEqk4hpSQLLOJGRzwhVGvI9bJlMOjby4zAcjIO7CZtU_5xmdbV7_SRZchqcSlOaX8y1vWiIb5Dm3TEYFit1FONltOIyowvxMe19XrI49Tiv0Pd2xfYk8mm3ftn8zcr33NQAzh9vpEXq6W-ijQoz4l45yVtoyaTbaP2LkuAOmo5cnRXsWvglxYDpMOy5i5KzgEWqcWZKjW9oziyGAzKMgKB5zoregtBiNH41AMUz7O5mcTp7N9PajCuWucQ9XBJddtG4f_N0NSDVRwpE-czPiY0pNwD0OBNhEAopoxAmzopYhooz93EpNd3Q-MLIWCpthdTMU1QZbZiQNvD3UCudpWYfYS-KYguQ0uNUB0Z1ecAirqgQsRcKAAdtdFa7MJmXehlJo4zs_J2AvxPn78Rro07t5KRaOlkCuRSOcMwPWBud145vuv80dvCv0SdodXTdTx5uh_eHaI26GCgKxzqolS_ezBEgjVweF9H0AW-jy1I
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Progress+in+the+extraction+and+separation+of+rare+earths+and+related+metals+with+novel+extractants%3A+A+review&rft.jtitle=Science+China.+Technological+sciences&rft.au=Kuang%2C+ShengTing&rft.au=Liao%2C+WuPing&rft.date=2018-09-01&rft.pub=Springer+Nature+B.V&rft.issn=1674-7321&rft.eissn=1869-1900&rft.volume=61&rft.issue=9&rft.spage=1319&rft.epage=1328&rft_id=info:doi/10.1007%2Fs11431-018-9295-0&rft.externalDBID=NO_FULL_TEXT
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1674-7321&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1674-7321&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1674-7321&client=summon