The preparation of 2,2′-bithiophene-based conjugated microporous polymers by direct arylation polymerization and their application in fluorescence sensing 2,4-dinitrophenol
In this paper, we report the synthetic strategy of direct arylation polymerization (DAP) for four 2,2′-bithiophene-based conjugated microporous polymers (the 2,2′-BTh-based CMPs) by coupling 2,2′-bithiophene with the building blocks containing bromine. Compared to conventional coupling polymerizatio...
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Published in | Analytica chimica acta Vol. 1240; p. 340779 |
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Format | Journal Article |
Language | English |
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Elsevier B.V
01.02.2023
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ISSN | 0003-2670 1873-4324 1873-4324 |
DOI | 10.1016/j.aca.2022.340779 |
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Abstract | In this paper, we report the synthetic strategy of direct arylation polymerization (DAP) for four 2,2′-bithiophene-based conjugated microporous polymers (the 2,2′-BTh-based CMPs) by coupling 2,2′-bithiophene with the building blocks containing bromine. Compared to conventional coupling polymerization, this synthetic scheme is simple, facile and atomically efficient owing to neither preactivating the C–H bonds in 2,2′-bithiophene using organometallic reagents nor synthesis of complex thiophene-based building blocks. The resulting 2,2′-BTh-based CMPs exhibit excellent thermal stability, high specific surface areas, and good microporosity. Their specific surface areas are higher than that of other previously reported CMPs prepared with DAP. The four 2,2′-BTh-based CMPs can be utilized for multicolor fluorescence sensing of 2,4-dinitrophenol (DNP) with the high sensitivity and selectivity. The sensitivities appear to increase with the degree of structural distortion.
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•The 2,2′-bithiophene-based CMPs were synthesized by DAP.•The 2,2′-bithiophene-based CMPs can fluorescence sense DNP. |
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AbstractList | In this paper, we report the synthetic strategy of direct arylation polymerization (DAP) for four 2,2'-bithiophene-based conjugated microporous polymers (the 2,2'-BTh-based CMPs) by coupling 2,2'-bithiophene with the building blocks containing bromine. Compared to conventional coupling polymerization, this synthetic scheme is simple, facile and atomically efficient owing to neither preactivating the C-H bonds in 2,2'-bithiophene using organometallic reagents nor synthesis of complex thiophene-based building blocks. The resulting 2,2'-BTh-based CMPs exhibit excellent thermal stability, high specific surface areas, and good microporosity. Their specific surface areas are higher than that of other previously reported CMPs prepared with DAP. The four 2,2'-BTh-based CMPs can be utilized for multicolor fluorescence sensing of 2,4-dinitrophenol (DNP) with the high sensitivity and selectivity. The sensitivities appear to increase with the degree of structural distortion. In this paper, we report the synthetic strategy of direct arylation polymerization (DAP) for four 2,2′-bithiophene-based conjugated microporous polymers (the 2,2′-BTh-based CMPs) by coupling 2,2′-bithiophene with the building blocks containing bromine. Compared to conventional coupling polymerization, this synthetic scheme is simple, facile and atomically efficient owing to neither preactivating the C–H bonds in 2,2′-bithiophene using organometallic reagents nor synthesis of complex thiophene-based building blocks. The resulting 2,2′-BTh-based CMPs exhibit excellent thermal stability, high specific surface areas, and good microporosity. Their specific surface areas are higher than that of other previously reported CMPs prepared with DAP. The four 2,2′-BTh-based CMPs can be utilized for multicolor fluorescence sensing of 2,4-dinitrophenol (DNP) with the high sensitivity and selectivity. The sensitivities appear to increase with the degree of structural distortion. [Display omitted] •The 2,2′-bithiophene-based CMPs were synthesized by DAP.•The 2,2′-bithiophene-based CMPs can fluorescence sense DNP. In this paper, we report the synthetic strategy of direct arylation polymerization (DAP) for four 2,2'-bithiophene-based conjugated microporous polymers (the 2,2'-BTh-based CMPs) by coupling 2,2'-bithiophene with the building blocks containing bromine. Compared to conventional coupling polymerization, this synthetic scheme is simple, facile and atomically efficient owing to neither preactivating the C-H bonds in 2,2'-bithiophene using organometallic reagents nor synthesis of complex thiophene-based building blocks. The resulting 2,2'-BTh-based CMPs exhibit excellent thermal stability, high specific surface areas, and good microporosity. Their specific surface areas are higher than that of other previously reported CMPs prepared with DAP. The four 2,2'-BTh-based CMPs can be utilized for multicolor fluorescence sensing of 2,4-dinitrophenol (DNP) with the high sensitivity and selectivity. The sensitivities appear to increase with the degree of structural distortion.In this paper, we report the synthetic strategy of direct arylation polymerization (DAP) for four 2,2'-bithiophene-based conjugated microporous polymers (the 2,2'-BTh-based CMPs) by coupling 2,2'-bithiophene with the building blocks containing bromine. Compared to conventional coupling polymerization, this synthetic scheme is simple, facile and atomically efficient owing to neither preactivating the C-H bonds in 2,2'-bithiophene using organometallic reagents nor synthesis of complex thiophene-based building blocks. The resulting 2,2'-BTh-based CMPs exhibit excellent thermal stability, high specific surface areas, and good microporosity. Their specific surface areas are higher than that of other previously reported CMPs prepared with DAP. The four 2,2'-BTh-based CMPs can be utilized for multicolor fluorescence sensing of 2,4-dinitrophenol (DNP) with the high sensitivity and selectivity. The sensitivities appear to increase with the degree of structural distortion. |
ArticleNumber | 340779 |
Author | Zhang, Yu-Xia |
Author_xml | – sequence: 1 givenname: Yu-Xia surname: Zhang fullname: Zhang, Yu-Xia email: xyyuxiazhang@163.com organization: School of Chemistry and Chemical Engineering, Xinyang Normal University, Xinyang, 464000, China |
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Keywords | 2,2′-bithiophene Conjugated microporous polymers DAP Direct arylation polymerization 2,4-dinitrophenol Fluorescent sense |
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Snippet | In this paper, we report the synthetic strategy of direct arylation polymerization (DAP) for four 2,2′-bithiophene-based conjugated microporous polymers (the... In this paper, we report the synthetic strategy of direct arylation polymerization (DAP) for four 2,2'-bithiophene-based conjugated microporous polymers (the... |
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SourceType | Aggregation Database Index Database Enrichment Source Publisher |
StartPage | 340779 |
SubjectTerms | 2,2′-bithiophene 2,4-Dinitrophenol Conjugated microporous polymers Direct arylation polymerization Fluorescence Fluorescent sense Polymerization Polymers - chemistry |
Title | The preparation of 2,2′-bithiophene-based conjugated microporous polymers by direct arylation polymerization and their application in fluorescence sensing 2,4-dinitrophenol |
URI | https://dx.doi.org/10.1016/j.aca.2022.340779 https://www.ncbi.nlm.nih.gov/pubmed/36641146 https://www.proquest.com/docview/2765779017 |
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