An unexpected Schiff base-type Ni(II) complex: Synthesis, crystal structures, fluorescence, electrochemical property and SOD-like activities

• Published in: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 137; pp. 661 - 669
• Main Authors: Chai, Lan-Qin, Zhang, Hong-Song, Huang, Jiao-Jiao, Zhang, Yu-Li
• Format: Journal Article
• Language: English
• Published: England Elsevier B.V 25.02.2015
• Subjects: Crystal structures; Crystallization; Crystallography, X-Ray; Cyclic voltammetry; Electrochemistry; Hydrogen Bonding; Ligands; Magnetic Resonance Spectroscopy; Metals - chemistry; Molecular Conformation; Nickel - chemistry; Oxidation-Reduction; Quinazoline-type ligand; Schiff base-type complex; Schiff Bases - chemistry; Spectrometry, Fluorescence; Spectrophotometry, Ultraviolet; Spectroscopic properties; Spectroscopy, Fourier Transform Infrared; Superoxide Dismutase - chemistry; Superoxide dismutase activities; Cyclic voltammetry; Spectroscopic properties; Crystal structures; Schiff base-type complex; Quinazoline-type ligand; Superoxide dismutase activities

An unexpected Schiff base-type Ni(II) complex instead of an anticipated quinazoline-type complex has been synthesized and structural characterized by spectroscopic methods. Crystal structures of the ligand and complex have been determined by single-crystal X-ray diffraction. Moreover, the electroche...