Enhanced photocatalytic activity of Mg-doped ZnO thin films prepared by sol-gel method
Undoped ZnO and Mg-doped ZnO (MZO) thin films were synthesized by sol-gel dip-coating technique. The effect of Mg dopant on the structural, surface-morphological, and optical properties together with the photocatalytic activities of the films was studied. Morphological study shows that incorporation...
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Published in | Surface engineering Vol. 37; no. 6; pp. 775 - 783 |
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Main Authors | , |
Format | Journal Article |
Language | English |
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London, England
Taylor & Francis
03.06.2021
SAGE Publications |
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Online Access | Get full text |
ISSN | 0267-0844 1743-2944 |
DOI | 10.1080/02670844.2020.1801143 |
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Abstract | Undoped ZnO and Mg-doped ZnO (MZO) thin films were synthesized by sol-gel dip-coating technique. The effect of Mg dopant on the structural, surface-morphological, and optical properties together with the photocatalytic activities of the films was studied. Morphological study shows that incorporation of Mg increases the porosity of the films. Structural investigation reveals that Mg doping declines the crystallinity of the films. The optical analysis demonstrates that the Urbach energy of the films increases due to Mg doping, suggesting the formation of localized energy states. Photocatalytic activities of the films were evaluated by studying the degradation of methylene blue under the ultraviolet light irradiation. MZO demonstrates better photocatalytic efficiency compared to ZnO films. The enhanced photocatalytic efficiency of MZO can be attributed to the charge trapping by localized states, and porosity-induced surface area enhancement due to Mg doping. |
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AbstractList | ABSTRACT
Undoped ZnO and Mg-doped ZnO (MZO) thin films were synthesized by sol–gel dip-coating technique. The effect of Mg dopant on the structural, surface-morphological, and optical properties together with the photocatalytic activities of the films was studied. Morphological study shows that incorporation of Mg increases the porosity of the films. Structural investigation reveals that Mg doping declines the crystallinity of the films. The optical analysis demonstrates that the Urbach energy of the films increases due to Mg doping, suggesting the formation of localized energy states. Photocatalytic activities of the films were evaluated by studying the degradation of methylene blue under the ultraviolet light irradiation. MZO demonstrates better photocatalytic efficiency compared to ZnO films. The enhanced photocatalytic efficiency of MZO can be attributed to the charge trapping by localized states, and porosity-induced surface area enhancement due to Mg doping. Undoped ZnO and Mg-doped ZnO (MZO) thin films were synthesized by sol-gel dip-coating technique. The effect of Mg dopant on the structural, surface-morphological, and optical properties together with the photocatalytic activities of the films was studied. Morphological study shows that incorporation of Mg increases the porosity of the films. Structural investigation reveals that Mg doping declines the crystallinity of the films. The optical analysis demonstrates that the Urbach energy of the films increases due to Mg doping, suggesting the formation of localized energy states. Photocatalytic activities of the films were evaluated by studying the degradation of methylene blue under the ultraviolet light irradiation. MZO demonstrates better photocatalytic efficiency compared to ZnO films. The enhanced photocatalytic efficiency of MZO can be attributed to the charge trapping by localized states, and porosity-induced surface area enhancement due to Mg doping. |
Author | Azam, Muhammad G. Islam, Muhammad R. |
Author_xml | – sequence: 1 givenname: Muhammad R. surname: Islam fullname: Islam, Muhammad R. email: rakibul@phy.buet.ac.bd organization: Department of Physics, Bangladesh University of Engineering and Technology (BUET) – sequence: 2 givenname: Muhammad G. surname: Azam fullname: Azam, Muhammad G. organization: Department of Physics, Bangladesh University of Engineering and Technology (BUET) |
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Cites_doi | 10.1080/15422119.2017.1383918 10.1016/j.saa.2013.08.090 10.1080/01932691.2018.1485580 10.1002/crat.200800326 10.1016/j.mssp.2014.07.034 10.1080/10643389.2018.1487227 10.1021/acs.jpcc.7b02530 10.1063/1.5129065 10.1021/am300359h 10.1103/PhysRevB.37.10244 10.1039/C8SC02348D 10.1080/14328917.2018.1445157 10.7567/JJAP.55.092301 10.1063/1.4815941 10.1088/1361-6641/ab5159 10.1016/j.surfin.2019.05.007 10.1007/s11051-005-5131-z 10.1063/1.4801900 10.1016/j.apsusc.2015.05.078 10.1016/j.mssp.2018.09.010 10.1021/acscatal.8b03521 10.1021/jp2038653 10.1007/s40201-019-00366-x 10.1080/17458080.2015.1025302 10.1179/1743294415Y.0000000096 10.1080/02670844.2019.1573344 10.1016/j.matlet.2015.03.001 10.1080/02670844.2018.1477559 10.1016/j.rser.2017.08.020 10.1080/02670844.2018.1555913 10.1038/srep36194 10.1088/0022-3727/21/12/023 10.1038/s41565-018-0216-x 10.1016/j.materresbull.2011.06.015 10.1080/24701556.2019.1662806 10.1063/1.1690091 10.1179/1743294414Y.0000000414 10.1088/2053-1591/aac918 10.1039/c3ce40798e 10.1080/02670844.2018.1528690 10.1080/02670844.2016.1270797 10.1088/1361-6641/ab2790 |
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Snippet | Undoped ZnO and Mg-doped ZnO (MZO) thin films were synthesized by sol-gel dip-coating technique. The effect of Mg dopant on the structural,... ABSTRACT Undoped ZnO and Mg-doped ZnO (MZO) thin films were synthesized by sol–gel dip-coating technique. The effect of Mg dopant on the structural,... |
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Title | Enhanced photocatalytic activity of Mg-doped ZnO thin films prepared by sol-gel method |
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