Controlled in situ reaction for the assembly of Cu( ii ) mixed-ligand coordination polymers: synthesis, structure, mechanistic insights, magnetism and catalysis

• Published in: Dalton transactions : an international journal of inorganic chemistry Vol. 44; no. 24; pp. 11013 - 11020
• Main Authors: Wang, Xing-Po, Zhao, Ya-Qin, Jagličić, Zvonko, Wang, Su-Na, Lin, Shu-Jie, Li, Xiao-Yi, Sun, Di
• Format: Journal Article
• Language: English
• Published: England 28.06.2015

It has been a challenge to decipher the in situ ligand reaction mechanism in assembly processes, involving metals and ligands. The present study shows two crystalline mixed-ligand Cu( ii ) coordination polymers isolated by controlled in situ ligand reactions under the same hydrothermal conditions. T...