Electron Impact Ionization-induced Fragmentation of Uracil-fused Tetrathiafulvalenes
The 70 eV electron ionization mass spectra of uracil‐fused tetrathiafulvalenes have been studied by accurate mass measurement, metastable ion analysis and collision‐induced dissociation. Changes in the structure of substituents, both in the tetrathiafulvalene moiety and on the N1 atom of uracil, cau...
Saved in:
| Published in | Rapid communications in mass spectrometry Vol. 10; no. 1; pp. 16 - 20 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Heyden & Son Limited
1996
|
| Online Access | Get full text |
Cover
Loading…
| Abstract | The 70 eV electron ionization mass spectra of uracil‐fused tetrathiafulvalenes have been studied by accurate mass measurement, metastable ion analysis and collision‐induced dissociation. Changes in the structure of substituents, both in the tetrathiafulvalene moiety and on the N1 atom of uracil, cause important differences in the fragmentation scheme. The position of alkyl substituents in the uracil ring is unambiguously confirmed. |
|---|---|
| AbstractList | The 70 eV electron ionization mass spectra of uracil‐fused tetrathiafulvalenes have been studied by accurate mass measurement, metastable ion analysis and collision‐induced dissociation. Changes in the structure of substituents, both in the tetrathiafulvalene moiety and on the N1 atom of uracil, cause important differences in the fragmentation scheme. The position of alkyl substituents in the uracil ring is unambiguously confirmed. |
| Author | Tilika, Vija Orduna, Jesús Neilands, Ojärs Garín, Javier |
| Author_xml | – sequence: 1 givenname: Javier surname: Garín fullname: Garín, Javier organization: Departamento de Química Orgánica, ICMA-Facultad de Ciencias, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain – sequence: 2 givenname: Jesús surname: Orduna fullname: Orduna, Jesús organization: Departamento de Química Orgánica, ICMA-Facultad de Ciencias, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain – sequence: 3 givenname: Ojärs surname: Neilands fullname: Neilands, Ojärs organization: Department of Organic Chemistry, Riga Technical University, ezenes 14, LV-1048, Riga, Latvia – sequence: 4 givenname: Vija surname: Tilika fullname: Tilika, Vija organization: Department of Organic Chemistry, Riga Technical University, ezenes 14, LV-1048, Riga, Latvia |
| BookMark | eNqF0MlOwzAUhWELgUQZ3iFLWLj42s1UEAhCWyKGqlCEWF05jg2BNEFOyvT0JBTYgMTK0rH9Lf41slyUhSbkAFgXGOM7W1dxFG8DC33KuIAtCEOPAbjN1Ic98Pr9w_iYXkbnPe7viy7rRuNdTidLpPPzZ5l0WOgC7UEYrJK1qnpgrcBZh0wHuVa1LQsnnj1JVTtxWWTvss7KgmZFOlc6dYZW3s10UX-uTmmcaytVllMzr5rbqa6trO8zaeb5s8x1oasNsmJkXunNr3OdXA8H0-iEno1HcXR4RpVwhU9BmkB5JjWe7CXc5zwIDDPgJtKActMg0YEGPwRIRMp1khjekzoB7no-14YpsU5uFq6yZVVZbfDJZjNp3xAYtvEQ23jYhsA2BH7H-3yA4CE28XARDwUyjMbIcdLItwv5Jcv12y_2P_VP9GtpbLqws6rWrz-2tI_o-cJ38eZihEdHEZwGE44j8QEPUZWP |
| ContentType | Journal Article |
| Copyright | Copyright © 1996 John Wiley & Sons, Ltd. |
| Copyright_xml | – notice: Copyright © 1996 John Wiley & Sons, Ltd. |
| DBID | BSCLL AAYXX CITATION |
| DOI | 10.1002/(SICI)1097-0231(19960115)10:1<16::AID-RCM427>3.0.CO;2-Q |
| DatabaseName | Istex CrossRef |
| DatabaseTitle | CrossRef |
| DatabaseTitleList | |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1097-0231 |
| EndPage | 20 |
| ExternalDocumentID | 10_1002__SICI_1097_0231_19960115_10_1_16__AID_RCM427_3_0_CO_2_Q RCM427 ark_67375_WNG_BBC1K8Q2_G |
| Genre | article |
| GrantInformation_xml | – fundername: DGICYT funderid: PB 94‐0577 |
| GroupedDBID | --- .3N .GA .Y3 05W 0R~ 10A 123 1L6 1OB 1OC 1ZS 31~ 33P 3SF 3WU 4.4 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5VS 66C 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AASGY AAXRX AAZKR ABCQN ABCUV ABEML ABIJN ABJNI ABPVW ACAHQ ACBWZ ACCFJ ACCZN ACGFS ACIWK ACPOU ACSCC ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN AEEZP AEIGN AEIMD AENEX AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFZJQ AHBTC AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB AQPKS ASPBG ATUGU AUFTA AVWKF AZBYB AZFZN AZVAB BAFTC BDRZF BFHJK BHBCM BMNLL BMXJE BNHUX BROTX BRXPI BSCLL BY8 CS3 D-E D-F DCZOG DPXWK DR1 DR2 DRFUL DRSTM DU5 EBD EBS EJD EMOBN F00 F01 F04 F5P FEDTE G-S G.N GNP GODZA H.T H.X HBH HF~ HGLYW HHY HHZ HVGLF HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LH5 LITHE LOXES LP6 LP7 LUTES LW6 LYRES MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2P P2W P2X P4D PALCI Q.N Q11 QB0 QRW R.K RIWAO RJQFR RNS ROL RWI RX1 RYL SAMSI SUPJJ TN5 UB1 V2E W8V W99 WBFHL WBKPD WH7 WIB WIH WIK WJL WOHZO WQJ WRC WRJ WXSBR WYISQ XG1 XPP XV2 ZCG ZZTAW ~02 ~IA ~WT AAYXX CITATION |
| ID | FETCH-LOGICAL-c3537-1af8c6fdf6a4b272288f0f15baf1c5d8be8e17911b3d2ebbf24aeb125672ef0c3 |
| IEDL.DBID | DR2 |
| ISSN | 0951-4198 |
| IngestDate | Fri Aug 23 01:25:05 EDT 2024 Sat Aug 24 00:54:59 EDT 2024 Wed Oct 30 09:53:28 EDT 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 1 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c3537-1af8c6fdf6a4b272288f0f15baf1c5d8be8e17911b3d2ebbf24aeb125672ef0c3 |
| Notes | ark:/67375/WNG-BBC1K8Q2-G DGICYT - No. PB 94-0577 istex:D3AA8BC1308CCA3FD0F43D63F89E30568F65981C ArticleID:RCM427 |
| PageCount | 5 |
| ParticipantIDs | crossref_primary_10_1002__SICI_1097_0231_19960115_10_1_16__AID_RCM427_3_0_CO_2_Q wiley_primary_10_1002_SICI_1097_0231_19960115_10_1_16_AID_RCM427_3_0_CO_2_Q_RCM427 istex_primary_ark_67375_WNG_BBC1K8Q2_G |
| PublicationCentury | 1900 |
| PublicationDate | 1996 |
| PublicationDateYYYYMMDD | 1996-01-01 |
| PublicationDate_xml | – year: 1996 text: 1996 |
| PublicationDecade | 1990 |
| PublicationPlace | London |
| PublicationPlace_xml | – name: London |
| PublicationTitle | Rapid communications in mass spectrometry |
| PublicationTitleAlternate | Rapid Commun. Mass Spectrom |
| PublicationYear | 1996 |
| Publisher | Heyden & Son Limited |
| Publisher_xml | – name: Heyden & Son Limited |
| References | J. Garín Adv. Heterocyclic Chem. 62, 249 (1995). K. L. Busch, G. L. Glish and S. A. McLuckey Mass Spectrometry/Mass Spectrometry. Techniques and Applications of Tandem Mass Spectrometry, VCH New York, 1988. (b) P. Blanchard, G. Duguay, J. Garín, J. Orduna, A. Gorgues and M. Sallé Rapid Commun. Mass Spectrom. 8, 701 (1994). (b) P. J. Skabara, M. R. Bryce, A. S. Batsanov and J. A. K. Howard J. Org. Chem. 60, 4644 (1995). reprinted in J. Mass Spectrom. 30, 797 (1995). (b) R. K. Boyd Spectros. Int. J. 1, 169 (1982). J. R. Andersen, H. Egsgaard, E. Larsen, K. Bechgaard and E. M. Engler Org. Mass Spectrom. 13, 121 (1978). (a) G. C. Papavassiliou, S. Y. Yiannopoulos and J. S. Zambounis Mol. Cryst. Liq. Cryst. 120, 333 (1985) (b) M. Himottu, K. Pihlaja, G. Stáger and P. Vainiotalo Rapid Commun. Mass Spectrom. 7, 374 (1993) G. Schukat and E. Fanghänel Sulfur Rep. 14, 245 (1993). (a) B. Ž. Jovanović, A. Períc and V. V. Vajs Rapid Commun. Mass Spectrom. 9, 845 (1995) (e) H. Budzikiewicz, C. Djerassi and D. H. Williams Mass Spectrometry of Organic Compounds, Holden-Day San Francisco, 1967, pp. 585-590. J. Garín, J. Orduna and S. Uriel Rapid Commun. Mass Spectrom. 7, 587 (1993). (b) G. C. Papavassiliou, S. Y. Yiannopoulos and J. S. Zambounis Chemica Scripta, 27, 265 (1987) (a) C. Rovira, J. Tarrés, M. Dias, J. Garín and J. Orduna Rapid Commun. Mass Spectrom. 9, 276 (1995) (a) A. P. Bruins, K. R. Jennings and S. Evans Int. J. Mass Spectrom. Ion Phys. 26, 395 (1978). (a) K. Levsen and H. Schwarz Angew. Chem. Int. Ed. Engl. 15, 509 (1976) (b) F. W. McLafferty, P. F. Bente, R. Kornfield, S-C. Tsai and I. Howe J. Am. Chem. Soc. 95, 2120 (1973) R. Andreu, J. Garín, J. Orduna, M. Savirón and S. Uriel Rapid Commun. Mass Spectrom. 7, 815 (1993). (d) Q. N. Porter and J. Baldas Mass Spectrometry of Heterocyclic Compounds, John Wiley New York, 1971, pp. 468-486 C. B. Jacoby, M. L. Gross and R. L. Zey J. Am. Soc. Mass Spectrom. 5, 837 (1994). (c) K. Lahlil, A. Moradpour, C. Merienne and C. Bowlas J. Org. Chem. 59, 8030 (1994). 1993; 7 1993; 14 1995; 62 1992 1994 1992 1992 1985 1987 1994; 120 27 59 1976 1973 1995; 15 95 30 1995 1994; 9 8 1995 1993 1969 1971 1967; 9 7 1995 1978 1982; 26 1 1978; 13 1994; 5 1983 1995; 60 1988 |
| References_xml | – volume: 9 8 start-page: 276 701 year: 1995 1994 publication-title: Rapid Commun. Mass Spectrom. Rapid Commun. Mass Spectrom. – start-page: 325 year: 1995 – year: 1988 – start-page: 350 1432 year: 1992 1992 – volume: 15 95 30 start-page: 509 2120 797 year: 1976 1973 1995 publication-title: Angew. Chem. Int. Ed. Engl. J. Am. Chem. Soc. J. Mass Spectrom. – volume: 62 start-page: 249 year: 1995 publication-title: Adv. Heterocyclic Chem. – volume: 5 start-page: 837 year: 1994 publication-title: J. Am. Soc. Mass Spectrom. – volume: 7 start-page: 587 year: 1993 publication-title: Rapid Commun. Mass Spectrom. – volume: 13 start-page: 121 year: 1978 publication-title: Org. Mass Spectrom. – volume: 7 start-page: 815 year: 1993 publication-title: Rapid Commun. Mass Spectrom. – volume: 9 7 start-page: 845 374 513 468 585 year: 1995 1993 1969 1971 1967 end-page: 486 590 publication-title: Rapid Commun. Mass Spectrom. Rapid Commun. Mass Spectrom. – volume: 14 start-page: 245 year: 1993 publication-title: Sulfur Rep. – start-page: 945 1116 year: 1992 1994 – volume: 26 1 start-page: 395 169 year: 1978 1982 publication-title: Int. J. Mass Spectrom. Ion Phys. Spectros. Int. J. – volume: 60 start-page: 405 4644 year: 1983 1995 publication-title: J. Org. Chem. – volume: 120 27 59 start-page: 333 265 8030 year: 1985 1987 1994 publication-title: Mol. Cryst. Liq. Cryst. Chemica Scripta J. Org. Chem. |
| SSID | ssj0011520 |
| Score | 1.5287148 |
| Snippet | The 70 eV electron ionization mass spectra of uracil‐fused tetrathiafulvalenes have been studied by accurate mass measurement, metastable ion analysis and... |
| SourceID | crossref wiley istex |
| SourceType | Aggregation Database Publisher |
| StartPage | 16 |
| Title | Electron Impact Ionization-induced Fragmentation of Uracil-fused Tetrathiafulvalenes |
| URI | https://api.istex.fr/ark:/67375/WNG-BBC1K8Q2-G/fulltext.pdf https://onlinelibrary.wiley.com/doi/abs/10.1002%2F%28SICI%291097-0231%2819960115%2910%3A1%3C16%3A%3AAID-RCM427%3E3.0.CO%3B2-Q |
| Volume | 10 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwxV3NbhMxELaqIgEX_hHhT3sgqBw2Xdu7601AoGabtgtqS0IjcrNsrw1RywaliYSQkHgEnoCH40mY2Z9UBSROiKt35U8az9gz9sw3hDxyOSyq4cpXuY39UEDAqsHL8FmuQmUTI7oB1g7vH8R74_DlJJqskS9NLUzFD7G6cEPLKPdrNHClTzfPSEPBAXuTpRkEzPiI6iOPGVIbIdsIRcIEGEY6gjZPITzleFu9lW37o3Q_ZKLNB7wTdNLDNu8zfwg7OOUCE8K2RyvyKZikInXERvQhxOYXyYsafXMDkZ-scDcaVBjq0Wc07vXOsJ5XSE8B59zZdwGX8dN5n7g81Hauku-NOKpcluPOcqE75vMvTJH_TV7XyJXaXfa2Kv2-TtZscYNcSpsudTfJZFD38fGyst7Ty2ZNaemPr9-mRQ6qm3vgnr_7UFdZFd7MeeO5MtMT-MMtT-H7kUWS3vdT5ZYnYHq4_98i453BUbrn190ifMMjLnyqXGJil7tYhZoJxpLEBY5GWjlqojzRNrHIxUo1z5nV2jFQRg3-XSyYdYHht8l6MSvsHeIJawXtRsyIiIXCUE214izo6kDZromSFnndrKP8WJGCyIr-mUmJQq7f9UHEshFw-YOksZQgVlmJVXIZyPRQMjlskcelPqzmU_NjzLkTkXx7sCv7_ZS-SoZM7rbIqFzl34D_hvtH2Hrk7r-Y9B65XKW4433VfbK-mC_tA_DgFvphaWg_AUOQJg0 |
| link.rule.ids | 315,783,787,1378,4033,27937,27938,27939,46308,46732 |
| linkProvider | Wiley-Blackwell |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwxV1LbxMxELZKK9FeeCPCcw8ElcOma3t3vQkI1GzTZmmTNiERuVm21y5RYYNCIiEOiJ_AP-C_8UsY7yNVAYkT4uq1_Gln_JgZe75B6LFJQamKClekOnR9Bg6rBCvDJanwhY4Ua3o2d7jXD7tj_9UkmKyhL1UuTMEPsQq42ZWR79d2gduA9M45ayhYYK-TOAGP2d6iupbIzHIbWboRbBkToNnyEdRpDP4pteHq3WTPHcY9n7A67dCG14iP67RN3MEltAEbBrUVEPaGK_opGKWgdbSl6H3wzi-jlyX8zraFfroC3q5goamFn-Ow1ToHe1FAPQOgC6ffhlXkp4tWcX6s7V9F3yuBFK9ZzhrLhWyoz79wRf4_iV1DV0qL2dktpvh1tKazG2gzrgrV3USTTlnKx0nylE8nmVXZpT--fptmKcze1AEL_fR9mWiVOTPjjOdCTd9BD7P8CN9H2vL0vp0K-BtYffYIuIXG-51R3HXLghGuogFlLhYmUqFJTSh8SRghUWQ8gwMpDFZBGkkdaUvHiiVNiZbSEJiPEky8kBFtPEVvo_Vsluk7yGFaM9wMiGIB8ZnCEktBideUntBNFUQ1dFIpkn8oeEF4wQBNOLdCLq_2QcS8EnDegeOQcxArL8TKKfd4fMwJH9TQk3xCrMYT8zP77I4F_E3_gLfbMT6MBoQf1NAwV_NvwH_D_SNs2XL3Xwz6CG12R70jfpT0D--hreLFuw1f3Ufri_lSPwCDbiEf5qvuJ8rxKic |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwxV3NbhMxELZKKxUu_CNS_vZAUDlsurZ315uAQM0maZfStEkbkZtle-0StWyqkEgICYlH4Al4OJ6E8f6kKiBxQly9lj9pPLOesWe-QeipSWFTFRWuSHXo-gwCVglehktS4QsdKdb0bO3wfj_cHflvxsF4BX2pamEKfojlhZu1jPx_bQ38PDVbF6Sh4IAdJXECAbN9RHUtj5mlNrJsI9gSJsCwpSOo0xjCU2pvq7eTjjuM933C6rRLG14jPqjTNnEHV9CaH1LPZoR1hkv2KVilYHW0neh9CM7X0esSfmvTQj9fAm9WsDDUwi9x2GpdgL0qoF4A0KXDb83u46fLTnF-qvVuoO-VPIpkltPGYi4b6vMvVJH_TWA30fXSX3a2CwW_hVZ0dhtdjas2dXfQuFs28nGSvODTSaZVbemPr98mWQq6mzrgn598KMusMmdqnNFMqMkZzDCLj_D9WFuW3vcTYRZnYHv2ALiLRr3ucbzrlu0iXEUDylwsTKRCk5pQ-JIwQqLIeAYHUhisgjSSOtKWjBVLmhItpSGgjRIcvJARbTxF76HVbJrp-8hhWjPcDIhiAfGZwhJLQYnXlJ7QTRVENXRY7SM_L1hBeMH_TDi3Qi4f9kHEvBJwPoHjkHMQKy_Eyin3eHzACR_U0LNcH5bridmpTbpjAX_X3-Htdoz3ogHhOzU0zHf5N-C_4f4RthzZ-BeLPkHrh50ef5v09x6ga0W6u727eohW57OFfgTe3Fw-zm3uJ_ncKNY |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Electron+Impact+Ionization-induced+Fragmentation+of+Uracil-fused+Tetrathiafulvalenes&rft.jtitle=Rapid+communications+in+mass+spectrometry&rft.au=Gar%C3%ADn%2C+Javier&rft.au=Orduna%2C+Jes%C3%BAs&rft.au=Neilands%2C+Oj%C3%A4rs&rft.au=Tilika%2C+Vija&rft.date=1996&rft.issn=0951-4198&rft.eissn=1097-0231&rft.volume=10&rft.issue=1&rft.spage=16&rft.epage=20&rft_id=info:doi/10.1002%2F%28SICI%291097-0231%2819960115%2910%3A1%3C16%3A%3AAID-RCM427%3E3.0.CO%3B2-Q&rft.externalDBID=n%2Fa&rft.externalDocID=10_1002__SICI_1097_0231_19960115_10_1_16__AID_RCM427_3_0_CO_2_Q |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0951-4198&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0951-4198&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0951-4198&client=summon |