Preparation methods of cellulose nanocrystal and its application in treatment of environmental pollution: A mini-review
Cellulose nanocrystals (CNCs) are rod-shaped nanomaterials with the same chemical composition as plant cellulose and can be extracted by physical, chemical, or biological pretreatment from raw materials. To modify the properties of CNCs, esterification, oxidation, and etherification can be further a...
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| Published in | Colloid and interface science communications Vol. 53; p. 100707 |
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| Main Authors | , , , , , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.03.2023
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| Abstract | Cellulose nanocrystals (CNCs) are rod-shaped nanomaterials with the same chemical composition as plant cellulose and can be extracted by physical, chemical, or biological pretreatment from raw materials. To modify the properties of CNCs, esterification, oxidation, and etherification can be further applied to modify the surface of CNCs. In addition to surface modification, graft modification is an approach to significantly alter the properties of CNCs via covalently conjugating cellulose with other polymers with distinct features. After modification, the adsorption performance of CNCs for heavy metal ions (e.g. Pb2+, Cd2+, Cu2+), organic dyes (e.g. methylene blue, crystal violet), and volatile organic compounds (VOCs) can be greatly improved. This review focuses on the preparation and modification methods of CNCs, as well as the adsorption performance of CNCs and CNC composites.
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•The preparation methods of CNCs were reviewed, and the advantages and disadvantages of physical and chemical methods were compared.•The advantages of selecting graft modification were highlighted by comprehensive comparison of various modification methods.•The treatment performance of CNCs and its composite materials after graft modification to heavy metal ions, organic dyes and volatile organic pollutants was greatly improved. |
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| AbstractList | Cellulose nanocrystals (CNCs) are rod-shaped nanomaterials with the same chemical composition as plant cellulose and can be extracted by physical, chemical, or biological pretreatment from raw materials. To modify the properties of CNCs, esterification, oxidation, and etherification can be further applied to modify the surface of CNCs. In addition to surface modification, graft modification is an approach to significantly alter the properties of CNCs via covalently conjugating cellulose with other polymers with distinct features. After modification, the adsorption performance of CNCs for heavy metal ions (e.g. Pb2+, Cd2+, Cu2+), organic dyes (e.g. methylene blue, crystal violet), and volatile organic compounds (VOCs) can be greatly improved. This review focuses on the preparation and modification methods of CNCs, as well as the adsorption performance of CNCs and CNC composites.
[Display omitted]
•The preparation methods of CNCs were reviewed, and the advantages and disadvantages of physical and chemical methods were compared.•The advantages of selecting graft modification were highlighted by comprehensive comparison of various modification methods.•The treatment performance of CNCs and its composite materials after graft modification to heavy metal ions, organic dyes and volatile organic pollutants was greatly improved. |
| ArticleNumber | 100707 |
| Author | Zhang, Yuzhe Gu, Peiyang Li, Zhongyu Shao, Yizi Wu, Hao Han, Xiaogang Zhang, Yan Xu, Wei Zhou, Man |
| Author_xml | – sequence: 1 givenname: Yuzhe surname: Zhang fullname: Zhang, Yuzhe organization: School of Environmental science and Engineering, Changzhou University, Changzhou 213164, China – sequence: 2 givenname: Yan surname: Zhang fullname: Zhang, Yan organization: School of Environmental science and Engineering, Changzhou University, Changzhou 213164, China – sequence: 3 givenname: Wei surname: Xu fullname: Xu, Wei organization: Department of Environmental and Chemical Engineering, Shanghai University, Shanghai, China – sequence: 4 givenname: Hao surname: Wu fullname: Wu, Hao organization: School of Environmental science and Engineering, Changzhou University, Changzhou 213164, China – sequence: 5 givenname: Yizi surname: Shao fullname: Shao, Yizi organization: Changzhou University School of Environmental & Safety Engineering, School of Urban Construction, School of Emergency Management Science and Engineering, China – sequence: 6 givenname: Xiaogang surname: Han fullname: Han, Xiaogang organization: Changzhou Qingliu environmental protection technology co. LTD, China – sequence: 7 givenname: Man surname: Zhou fullname: Zhou, Man organization: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China – sequence: 8 givenname: Peiyang surname: Gu fullname: Gu, Peiyang email: gupeiyang0714@cczu.edu.cn organization: Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China – sequence: 9 givenname: Zhongyu surname: Li fullname: Li, Zhongyu email: zhongyuli@mail.tsinghua.edu.cn organization: School of Environmental science and Engineering, Changzhou University, Changzhou 213164, China |
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