Grafting acrylic acid onto polypropylene by reactive extrusion with pre-irradiated PP as initiator

In this paper, the modification of polypropylene (PP) with acrylic acid (AA) by reactive extrusion using pre-irradiated PP (rPP) as initiator was investigated. It was found the relatively high graft degree (Gd) and slight degradation of modified PP was obtained when 20 wt% rPP was used. This result...

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Published inRadiation physics and chemistry (Oxford, England : 1993) Vol. 77; no. 3; pp. 370 - 372
Main Authors Cai, Chuanlun, Shi, Qiang, Li, Lili, Zhu, Lianchao, Yin, Jinghua
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.03.2008
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Abstract In this paper, the modification of polypropylene (PP) with acrylic acid (AA) by reactive extrusion using pre-irradiated PP (rPP) as initiator was investigated. It was found the relatively high graft degree (Gd) and slight degradation of modified PP was obtained when 20 wt% rPP was used. This result can be explained in terms of effective concentration of free radicals. Compared with the neat PP, the modified PP showed the high-notched impact strength and improved adhesion of PP to polar substrate. This technique is of potential industrial interest for PP modification.
AbstractList In this paper, the modification of polypropylene (PP) with acrylic acid (AA) by reactive extrusion using pre-irradiated PP (rPP) as initiator was investigated. It was found the relatively high graft degree (Gd) and slight degradation of modified PP was obtained when 20wt% rPP was used. This result can be explained in terms of effective concentration of free radicals. Compared with the neat PP, the modified PP showed the high-notched impact strength and improved adhesion of PP to polar substrate. This technique is of potential industrial interest for PP modification.
In this paper, the modification of polypropylene (PP) with acrylic acid (AA) by reactive extrusion using pre-irradiated PP (rPP) as initiator was investigated. It was found the relatively high graft degree (Gd) and slight degradation of modified PP was obtained when 20 wt% rPP was used. This result can be explained in terms of effective concentration of free radicals. Compared with the neat PP, the modified PP showed the high-notched impact strength and improved adhesion of PP to polar substrate. This technique is of potential industrial interest for PP modification.
Author Zhu, Lianchao
Li, Lili
Cai, Chuanlun
Yin, Jinghua
Shi, Qiang
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Cites_doi 10.1016/S0969-806X(98)00293-X
10.1002/app.23877
10.1016/j.polymer.2006.01.012
10.1016/S0969-806X(03)00453-5
10.1016/S0142-9418(03)00018-7
10.1016/S0969-806X(98)00277-1
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Keywords Polypropylene
Grafting
Acrylic acid
Pre-irradiated
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Snippet In this paper, the modification of polypropylene (PP) with acrylic acid (AA) by reactive extrusion using pre-irradiated PP (rPP) as initiator was investigated....
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SubjectTerms Acrylic acid
Grafting
Polypropylene
Pre-irradiated
Title Grafting acrylic acid onto polypropylene by reactive extrusion with pre-irradiated PP as initiator
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