Synthesis, characterisation and magnetic study of a cyano-substituted dysprosium double decker single-molecule magnet

Bis(octacyanophthalocyanine)dysprosium(III) (1) has been synthesised, characterised and magnetically studied. By the incorporation of cyano substituents on the phthalocyanine (Pc) rings, a starting point has been created for the chemical modification of double deckers for the purpose of surface self...

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 41; no. 4; pp. 1128 - 1130
Main Authors Waters, Michael, Moro, Fabrizio, Krivokapic, Itana, McMaster, Jonathan, van Slageren, Joris
Format Journal Article
LanguageEnglish
Published England 01.01.2012
Subjects
Double decker
Dysprosium
Leaves
Magnetic properties
Prints
Self assembly
Synthesis
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Summary:Bis(octacyanophthalocyanine)dysprosium(III) (1) has been synthesised, characterised and magnetically studied. By the incorporation of cyano substituents on the phthalocyanine (Pc) rings, a starting point has been created for the chemical modification of double deckers for the purpose of surface self-assembly. The modification of the rings leaves the magnetic properties of the double decker largely unaffected.
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ISSN:1477-9226
1477-9234
DOI:10.1039/c1dt11880c