A review of nickel-molybdenum based hydrogen evolution electrocatalysts from theory to experiment

Hydrogen evolution reaction (HER) from alkaline electrolytes is one of most promising methods for producing hydrogen. The remaining obstacles include the development of high performance and earth-abundant electrocatalysts which can be cost-effectively fabricated in large-scale. Ni-Mo based materials...

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Published inApplied catalysis. A, General Vol. 651; p. 119013
Main Authors Park, Sun Hwa, To, Dung T., Myung, Nosang V.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 05.02.2023
Subjects
Alkaline electrolyte
Electrocatalysts
Hydrogen evolution reaction
Ni-Mo alloy
Nickel
Alkaline electrolyte
Hydrogen evolution reaction
Nickel
Electrocatalysts
Ni-Mo alloy
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Abstract Hydrogen evolution reaction (HER) from alkaline electrolytes is one of most promising methods for producing hydrogen. The remaining obstacles include the development of high performance and earth-abundant electrocatalysts which can be cost-effectively fabricated in large-scale. Ni-Mo based materials are one of potential candidates which might meet the most needs. In this review, we summarize the latest progress in Ni-Mo based HER catalysts in alkaline electrolytes from theoretical calculation to experimental results. This work also summarizes several different strategies to enhance the HER rate. Finally, the future perspective of the next generation electrocatalysts is discussed. [Display omitted] •Latest development of Ni-Mo based electrocatalysts for hydrogen production.•Theoretical calculations and experimental evaluations of various Ni-Mo alloys.•Effective strategies to improve the hydrogen evolution reaction performance.
AbstractList Hydrogen evolution reaction (HER) from alkaline electrolytes is one of most promising methods for producing hydrogen. The remaining obstacles include the development of high performance and earth-abundant electrocatalysts which can be cost-effectively fabricated in large-scale. Ni-Mo based materials are one of potential candidates which might meet the most needs. In this review, we summarize the latest progress in Ni-Mo based HER catalysts in alkaline electrolytes from theoretical calculation to experimental results. This work also summarizes several different strategies to enhance the HER rate. Finally, the future perspective of the next generation electrocatalysts is discussed. [Display omitted] •Latest development of Ni-Mo based electrocatalysts for hydrogen production.•Theoretical calculations and experimental evaluations of various Ni-Mo alloys.•Effective strategies to improve the hydrogen evolution reaction performance.
ArticleNumber 119013
Author To, Dung T.
Park, Sun Hwa
Myung, Nosang V.
Author_xml – sequence: 1
  givenname: Sun Hwa
  surname: Park
  fullname: Park, Sun Hwa
  email: psh@kriss.kr
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– sequence: 2
  givenname: Dung T.
  surname: To
  fullname: To, Dung T.
  email: dto@nd.edu
  organization: Department of Chemical and Biomolecular Engineering, University of Notre Dame, USA
– sequence: 3
  givenname: Nosang V.
  surname: Myung
  fullname: Myung, Nosang V.
  email: nmyung@nd.edu
  organization: Department of Chemical and Biomolecular Engineering, University of Notre Dame, USA
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Keywords Alkaline electrolyte
Hydrogen evolution reaction
Nickel
Electrocatalysts
Ni-Mo alloy
Language English
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Snippet Hydrogen evolution reaction (HER) from alkaline electrolytes is one of most promising methods for producing hydrogen. The remaining obstacles include the...
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SubjectTerms Alkaline electrolyte
Electrocatalysts
Hydrogen evolution reaction
Ni-Mo alloy
Nickel
Title A review of nickel-molybdenum based hydrogen evolution electrocatalysts from theory to experiment
URI https://dx.doi.org/10.1016/j.apcata.2022.119013
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