The First Transition Metal Complexes of 15-Membered Triolefinic Macrocycles: (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene Complexes of Palladium(0), Platinum(0), and Silver(I)

(E,E,E)‐1,6,11‐Tris(arenesulfonyl)‐1,6,11‐triazacyclopentadeca‐3,8,13‐trienes (1) form very stable complexes with Pd0 and Pt0, and moderately stable complexes with AgI. The three olefins in the macrocycle are responsible for the complexation. The X‐ray structures of two complexes of Pd0 and Pt0 are...

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Published in	European journal of inorganic chemistry Vol. 2001; no. 8; pp. 1999 - 2006
Main Authors	Cerezo, Silvia, Cortès, Jordi, Lago, Elena, Molins, Elies, Moreno-Mañas, Marcial, Parella, Teodor, Pleixats, Roser, Torrejón, Javier, Vallribera, Adelina
Format	Journal Article
Language	English
Published	Weinheim WILEY-VCH Verlag GmbH 01.08.2001 WILEY‐VCH Verlag GmbH
Subjects	Heterocycles Macrocyclic ligands Palladium Platinum Silver
Online Access	Get full text
ISSN	1434-1948 1099-0682
DOI	10.1002/1099-0682(200108)2001:8<1999::AID-EJIC1999>3.0.CO;2-V

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Abstract	(E,E,E)‐1,6,11‐Tris(arenesulfonyl)‐1,6,11‐triazacyclopentadeca‐3,8,13‐trienes (1) form very stable complexes with Pd0 and Pt0, and moderately stable complexes with AgI. The three olefins in the macrocycle are responsible for the complexation. The X‐ray structures of two complexes of Pd0 and Pt0 are presented; both complexes are planar trigonal.
AbstractList	(E,E,E)‐1,6,11‐Tris(arenesulfonyl)‐1,6,11‐triazacyclopentadeca‐3,8,13‐trienes (1) form very stable complexes with Pd0 and Pt0, and moderately stable complexes with AgI. The three olefins in the macrocycle are responsible for the complexation. The X‐ray structures of two complexes of Pd0 and Pt0 are presented; both complexes are planar trigonal.
Author	Lago, Elena Cerezo, Silvia Pleixats, Roser Torrejón, Javier Cortès, Jordi Vallribera, Adelina Moreno-Mañas, Marcial Molins, Elies Parella, Teodor
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Snippet	(E,E,E)‐1,6,11‐Tris(arenesulfonyl)‐1,6,11‐triazacyclopentadeca‐3,8,13‐trienes (1) form very stable complexes with Pd0 and Pt0, and moderately stable complexes...
SourceID	crossref wiley istex
SourceType	Index Database Publisher
StartPage	1999
SubjectTerms	Heterocycles Macrocyclic ligands Palladium Platinum Silver
Title	The First Transition Metal Complexes of 15-Membered Triolefinic Macrocycles: (E,E,E)-1,6,11-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene Complexes of Palladium(0), Platinum(0), and Silver(I)
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