Switching the on‐surface orientation of oxygen‐functionalized helicene
Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with helicenes is a key step toward new organic materials devices. The deposition of a heterohelicene containing two furano groups and two hydroxyl groups...
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| Published in | Chirality (New York, N.Y.) Vol. 36; no. 2; pp. e23642 - n/a |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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01.02.2024
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| Abstract | Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with helicenes is a key step toward new organic materials devices. The deposition of a heterohelicene containing two furano groups and two hydroxyl groups onto copper(111) surface in ultrahigh vacuum leads to different adsorbate modifications. At low coverage and low temperature, the molecules tend to lie on the surface in order to maximize van der Waals contact with the substrate. Thermal treatment leads to deprotonation of the hydroxyl groups and in part into a reorientation from lying into a standing adsorbate mode.
With increasing coverage and temperature, oxygen‐functionalized helicenes switch their adsorbate mode on a copper surface. |
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| AbstractList | Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with helicenes is a key step toward new organic materials devices. The deposition of a heterohelicene containing two furano groups and two hydroxyl groups onto copper(111) surface in ultrahigh vacuum leads to different adsorbate modifications. At low coverage and low temperature, the molecules tend to lie on the surface in order to maximize van der Waals contact with the substrate. Thermal treatment leads to deprotonation of the hydroxyl groups and in part into a reorientation from lying into a standing adsorbate mode.
With increasing coverage and temperature, oxygen‐functionalized helicenes switch their adsorbate mode on a copper surface. Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with helicenes is a key step toward new organic materials devices. The deposition of a heterohelicene containing two furano groups and two hydroxyl groups onto copper(111) surface in ultrahigh vacuum leads to different adsorbate modifications. At low coverage and low temperature, the molecules tend to lie on the surface in order to maximize van der Waals contact with the substrate. Thermal treatment leads to deprotonation of the hydroxyl groups and in part into a reorientation from lying into a standing adsorbate mode. Abstract Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with helicenes is a key step toward new organic materials devices. The deposition of a heterohelicene containing two furano groups and two hydroxyl groups onto copper(111) surface in ultrahigh vacuum leads to different adsorbate modifications. At low coverage and low temperature, the molecules tend to lie on the surface in order to maximize van der Waals contact with the substrate. Thermal treatment leads to deprotonation of the hydroxyl groups and in part into a reorientation from lying into a standing adsorbate mode. |
| Author | Hasan, Mohammed Wäckerlin, Christian Karnik, Anil V. Ernst, Karl‐Heinz Voigt, Jan |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38384155$$D View this record in MEDLINE/PubMed |
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10.1038/s41557‐022‐01044‐6 – ident: e_1_2_7_4_1 doi: 10.1021/cr200087r |
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| Snippet | Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with helicenes... Abstract Helicenes represent an important class of chiral organic material with promising optoelectronic properties. Hence, functionalization of surfaces with... |
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| StartPage | e23642 |
| SubjectTerms | Adsorbates chiral crystallization Heat treatment helicenes Hydroxyl groups Low temperature Optoelectronics Organic materials scanning tunneling microscopy Substrates surface science Ultrahigh vacuum |
| Title | Switching the on‐surface orientation of oxygen‐functionalized helicene |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fchir.23642 https://www.ncbi.nlm.nih.gov/pubmed/38384155 https://www.proquest.com/docview/2929308919 https://search.proquest.com/docview/2930476954 |
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