Semi-bridging σ-silyls as Z-type ligands

The reactions of SiHPh(NCH PPh ) C H -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M {μ-κ -Si,P,P'-SiPh(CH PPh ) C H } ] (M = Ni, Pd, Pt) in which the M-M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M Si core increa...

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Published inChemical communications (Cambridge, England) Vol. 56; no. 24; pp. 3532 - 3535
Main Authors Frogley, Benjamin J, Hill, Anthony F, Sharma, Manab, Sinha, Arup, Ward, Jas S
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 25.03.2020
Subjects
Bimetals
Crystallography
Ligands
Palladium
Platinum
Reagents
Silicon
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Abstract The reactions of SiHPh(NCH PPh ) C H -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M {μ-κ -Si,P,P'-SiPh(CH PPh ) C H } ] (M = Ni, Pd, Pt) in which the M-M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M Si core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal 'Z-type' silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.
AbstractList The reactions of SiHPh(NCH PPh ) C H -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M {μ-κ -Si,P,P'-SiPh(CH PPh ) C H } ] (M = Ni, Pd, Pt) in which the M-M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M Si core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal 'Z-type' silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.
The reactions of SiHPh(NCH 2 PPh 2 ) 2 C 6 H 4 -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M 2 {μ-κ 3 -Si ,P , P ′-SiPh(CH 2 PPh 2 ) 2 C 6 H 4 } 2 ] (M = Ni, Pd, Pt) in which the M–M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M 2 Si 2 core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal ‘Z-type’ silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.
The reactions of SiHPh(NCH2PPh2)2C6H4-1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M2{μ-κ3-Si,P,P′-SiPh(CH2PPh2)2C6H4}2] (M = Ni, Pd, Pt) in which the M–M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M2Si2 core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal ‘Z-type’ silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.
Author Sharma, Manab
Sinha, Arup
Frogley, Benjamin J
Hill, Anthony F
Ward, Jas S
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Cites_doi 10.1002/chem.201200746
10.1002/chem.201001281
10.1002/ejic.200800518
10.1002/anie.200503649
10.1016/j.poly.2004.05.012
10.1021/om200694r
10.1002/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-P
10.1021/om800670e
10.1002/anie.200702726
10.1021/ja973230v
10.1021/ic801293e
10.1021/ic300531b
10.1002/anie.200905241
10.1021/acs.organomet.5b00937
10.1002/chem.201405610
10.1002/(SICI)1521-3749(200005)626:5<1217::AID-ZAAC1217>3.0.CO;2-F
10.1002/anie.200900737
10.1039/C39930001729
10.1039/C0DT01181A
10.1021/ic50194a040
10.1021/ed400504f
10.1039/C7DT04155A
10.1007/430_2013_118
10.1039/C8DT04813D
10.1002/anie.201307618
10.1021/om5006319
10.1021/om501154d
10.1039/b408632e
10.1039/C0CC04109B
10.1021/om701162h
10.1039/b822678d
10.1002/anie.200900521
10.1039/b915395k
10.1021/om050630f
10.1021/acs.organomet.7b00137
10.1002/anie.200905391
10.1021/ja00356a022
10.1039/DT9870000061
10.1039/c1cc15561j
10.1016/B978-0-12-374784-6.00001-2
10.1002/tcr.201600061
10.1021/ja400128h
10.1021/om00086a026
10.1002/chem.200701027
10.1002/anie.201005431
10.1021/ja208675p
10.1515/MGMC.2005.28.4.201
10.1021/ic051975t
10.1021/ja504667f
10.1016/S0022-328X(01)00656-8
10.1002/zaac.200300037
10.1039/DT9790001294
10.1016/S0022-328X(00)00492-7
10.1021/ic061353n
10.1002/anie.201007967
10.1021/om400792j
10.1039/C39840000112
10.1002/anie.200905950
10.1002/chem.201001228
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References Dixon (C9CC07763D-(cit15)/*[position()=1]) 2014; 33
Gualco (C9CC07763D-(cit8d)/*[position()=1]) 2015; 34
Braunschweig (C9CC07763D-(cit5a)/*[position()=1]) 2007; 46
Brendler (C9CC07763D-(cit9d)/*[position()=1]) 2011; 50
Ma (C9CC07763D-(cit3b)/*[position()=1]) 2019; 49
Vogel (C9CC07763D-(cit6g)/*[position()=1]) 2003; 629
Autschbach (C9CC07763D-(cit9b)/*[position()=1]) 2012; 18
Steinke (C9CC07763D-(cit6b)/*[position()=1]) 2005
Klinkhammer (C9CC07763D-(cit11c)/*[position()=1]) 2000; 626
Landry (C9CC07763D-(cit3f)/*[position()=1]) 2006; 45
Qi (C9CC07763D-(cit16c)/*[position()=1]) 2018; 47
Sircoglou (C9CC07763D-(cit6f)/*[position()=1]) 2009; 48
(C9CC07763D-(cit13a)/*[position()=1]) 2013
Gualco (C9CC07763D-(cit8b)/*[position()=1]) 2010; 16
Kameo (C9CC07763D-(cit8e)/*[position()=2]) 2017; 17
Xiong (C9CC07763D-(cit16b)/*[position()=1]) 2016; 35
Cotton (C9CC07763D-(cit17b)/*[position()=1]) 1976; 21
Braunschweig (C9CC07763D-(cit4a)/*[position()=1]) 2011; 40
Heine (C9CC07763D-(cit11b)/*[position()=1]) 1993
Lin (C9CC07763D-(cit20)/*[position()=1]) 2014; 136
Bauer (C9CC07763D-(cit5b)/*[position()=1]) 2012; 51
Tilley (C9CC07763D-(cit14)/*[position()=1]) 2008; 27
Bauer (C9CC07763D-(cit5c)/*[position()=1]) 2011; 47
(C9CC07763D-(cit13b)/*[position()=1]) 2007
Kameo (C9CC07763D-(cit8c)/*[position()=1]) 2017; 36
Wilfling (C9CC07763D-(cit11d)/*[position()=1]) 2010; 49
Ciriano (C9CC07763D-(cit10)/*[position()=1]) 1979
Komuro (C9CC07763D-(cit11e)/*[position()=1]) 2010; 46
Linti (C9CC07763D-(cit6e)/*[position()=1]) 2001; 626
Westcott (C9CC07763D-(cit19)/*[position()=1]) 2004; 23
Nova (C9CC07763D-(cit12)/*[position()=1]) 2014; 53
Gualco (C9CC07763D-(cit8a)/*[position()=1]) 2009; 48
Figueroa (C9CC07763D-(cit3e)/*[position()=1]) 2006; 45
Bontemps (C9CC07763D-(cit3c)/*[position()=1]) 2006; 45
Golden (C9CC07763D-(cit5f)/*[position()=1]) 1998; 120
Aldridge (C9CC07763D-(cit6d)/*[position()=1]) 2005; 28
Osakada (C9CC07763D-(cit11a)/*[position()=1]) 2000; 611
Bunn (C9CC07763D-(cit6c)/*[position()=1]) 2005; 24
Mayer (C9CC07763D-(cit5e)/*[position()=1]) 1984; 3
Barr (C9CC07763D-(cit17a)/*[position()=1]) 1984
Bontemps (C9CC07763D-(cit3d)/*[position()=1]) 2008; 14
Wagler (C9CC07763D-(cit1)/*[position()=1]) 2014; 155
Whited (C9CC07763D-(cit16a)/*[position()=1]) 2014; 33
Hersh (C9CC07763D-(cit17c)/*[position()=1]) 1983; 105
Braunschweig (C9CC07763D-(cit7)/*[position()=1]) 2009; 48
Braunschweig (C9CC07763D-(cit6a)/*[position()=1]) 2008; 47
Tsoureas (C9CC07763D-(cit3g)/*[position()=1]) 2009
Bauer (C9CC07763D-(cit5d)/*[position()=1]) 2010; 16
Borren (C9CC07763D-(cit18b)/*[position()=1]) 2013; 135
Amgoune (C9CC07763D-(cit2b)/*[position()=1]) 2011; 47
Green (C9CC07763D-(cit18a)/*[position()=1]) 1987
Dyson (C9CC07763D-(cit3h)/*[position()=1]) 2011; 30
Devillard (C9CC07763D-(cit5h)/*[position()=1]) 2015; 21
Wagler (C9CC07763D-(cit9e)/*[position()=1]) 2008
Truflandier (C9CC07763D-(cit9a)/*[position()=1]) 2011; 50
Hill (C9CC07763D-(cit3a)/*[position()=1]) 1999; 38
Moret (C9CC07763D-(cit3i)/*[position()=1]) 2011; 133
Wagler (C9CC07763D-(cit9c)/*[position()=1]) 2010; 49
Burlitch (C9CC07763D-(cit5g)/*[position()=1]) 1979; 18
Green (C9CC07763D-(cit2a)/*[position()=1]) 2014; 91
Bouhadir (C9CC07763D-(cit4b)/*[position()=1]) 2010; 58
Emslie (C9CC07763D-(cit3j)/*[position()=1]) 2008; 27
Turculet (C9CC07763D-(cit13c)/*[position()=1]) 2014
References_xml – volume: 18
  start-page: 12803
  year: 2012
  ident: C9CC07763D-(cit9b)/*[position()=1]
  publication-title: Chem. – Eur. J.
  doi: 10.1002/chem.201200746
  contributor:
    fullname: Autschbach
– volume: 16
  start-page: 10808
  year: 2010
  ident: C9CC07763D-(cit8b)/*[position()=1]
  publication-title: Chem. – Eur. J.
  doi: 10.1002/chem.201001281
  contributor:
    fullname: Gualco
– start-page: 4225
  year: 2008
  ident: C9CC07763D-(cit9e)/*[position()=1]
  publication-title: Eur. J. Inorg. Chem.
  doi: 10.1002/ejic.200800518
  contributor:
    fullname: Wagler
– volume-title: Pincer and Pincer-Type Complexes
  year: 2014
  ident: C9CC07763D-(cit13c)/*[position()=1]
  contributor:
    fullname: Turculet
– volume: 45
  start-page: 1611
  year: 2006
  ident: C9CC07763D-(cit3c)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200503649
  contributor:
    fullname: Bontemps
– volume: 23
  start-page: 2665
  year: 2004
  ident: C9CC07763D-(cit19)/*[position()=1]
  publication-title: Polyhedron
  doi: 10.1016/j.poly.2004.05.012
  contributor:
    fullname: Westcott
– volume: 30
  start-page: 5844
  year: 2011
  ident: C9CC07763D-(cit3h)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/om200694r
  contributor:
    fullname: Dyson
– volume: 38
  start-page: 2759
  year: 1999
  ident: C9CC07763D-(cit3a)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/(SICI)1521-3773(19990917)38:18<2759::AID-ANIE2759>3.0.CO;2-P
  contributor:
    fullname: Hill
– volume: 27
  start-page: 5317
  year: 2008
  ident: C9CC07763D-(cit3j)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/om800670e
  contributor:
    fullname: Emslie
– volume: 21
  start-page: 1
  year: 1976
  ident: C9CC07763D-(cit17b)/*[position()=1]
  publication-title: Prog. Inorg. Chem.
  contributor:
    fullname: Cotton
– volume: 46
  start-page: 7782
  year: 2007
  ident: C9CC07763D-(cit5a)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200702726
  contributor:
    fullname: Braunschweig
– volume: 120
  start-page: 223
  year: 1998
  ident: C9CC07763D-(cit5f)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja973230v
  contributor:
    fullname: Golden
– volume: 47
  start-page: 8595
  year: 2008
  ident: C9CC07763D-(cit6a)/*[position()=1]
  publication-title: Inorg. Chem.
  doi: 10.1021/ic801293e
  contributor:
    fullname: Braunschweig
– volume: 51
  start-page: 5617
  year: 2012
  ident: C9CC07763D-(cit5b)/*[position()=1]
  publication-title: Inorg. Chem.
  doi: 10.1021/ic300531b
  contributor:
    fullname: Bauer
– volume: 49
  start-page: 624
  year: 2010
  ident: C9CC07763D-(cit9c)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200905241
  contributor:
    fullname: Wagler
– volume: 35
  start-page: 357
  year: 2016
  ident: C9CC07763D-(cit16b)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/acs.organomet.5b00937
  contributor:
    fullname: Xiong
– volume: 21
  start-page: 74
  year: 2015
  ident: C9CC07763D-(cit5h)/*[position()=1]
  publication-title: Chem. – Eur. J.
  doi: 10.1002/chem.201405610
  contributor:
    fullname: Devillard
– volume: 626
  start-page: 1217
  year: 2000
  ident: C9CC07763D-(cit11c)/*[position()=1]
  publication-title: Z. Anorg. Allg. Chem.
  doi: 10.1002/(SICI)1521-3749(200005)626:5<1217::AID-ZAAC1217>3.0.CO;2-F
  contributor:
    fullname: Klinkhammer
– volume: 48
  start-page: 3454
  year: 2009
  ident: C9CC07763D-(cit6f)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200900737
  contributor:
    fullname: Sircoglou
– start-page: 1729
  year: 1993
  ident: C9CC07763D-(cit11b)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/C39930001729
  contributor:
    fullname: Heine
– volume: 40
  start-page: 549
  year: 2011
  ident: C9CC07763D-(cit4a)/*[position()=1]
  publication-title: Dalton Trans.
  doi: 10.1039/C0DT01181A
  contributor:
    fullname: Braunschweig
– volume: 18
  start-page: 1097
  year: 1979
  ident: C9CC07763D-(cit5g)/*[position()=1]
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50194a040
  contributor:
    fullname: Burlitch
– volume: 91
  start-page: 807
  year: 2014
  ident: C9CC07763D-(cit2a)/*[position()=1]
  publication-title: J. Chem. Educ.
  doi: 10.1021/ed400504f
  contributor:
    fullname: Green
– volume: 47
  start-page: 2581
  year: 2018
  ident: C9CC07763D-(cit16c)/*[position()=1]
  publication-title: Dalton Trans.
  doi: 10.1039/C7DT04155A
  contributor:
    fullname: Qi
– volume: 155
  start-page: 29
  year: 2014
  ident: C9CC07763D-(cit1)/*[position()=1]
  publication-title: Struct. Bond
  doi: 10.1007/430_2013_118
  contributor:
    fullname: Wagler
– volume: 49
  start-page: 1976
  year: 2019
  ident: C9CC07763D-(cit3b)/*[position()=1]
  publication-title: Dalton Trans.
  doi: 10.1039/C8DT04813D
  contributor:
    fullname: Ma
– volume: 53
  start-page: 1103
  year: 2014
  ident: C9CC07763D-(cit12)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201307618
  contributor:
    fullname: Nova
– volume: 33
  start-page: 5070
  year: 2014
  ident: C9CC07763D-(cit16a)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/om5006319
  contributor:
    fullname: Whited
– volume: 34
  start-page: 1449
  year: 2015
  ident: C9CC07763D-(cit8d)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/om501154d
  contributor:
    fullname: Gualco
– start-page: 55
  year: 2005
  ident: C9CC07763D-(cit6b)/*[position()=1]
  publication-title: Dalton Trans.
  doi: 10.1039/b408632e
  contributor:
    fullname: Steinke
– volume: 47
  start-page: 859
  year: 2011
  ident: C9CC07763D-(cit2b)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/C0CC04109B
  contributor:
    fullname: Amgoune
– volume: 27
  start-page: 2223
  year: 2008
  ident: C9CC07763D-(cit14)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/om701162h
  contributor:
    fullname: Tilley
– start-page: 2538
  year: 2009
  ident: C9CC07763D-(cit3g)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/b822678d
  contributor:
    fullname: Tsoureas
– volume: 48
  start-page: 4239
  year: 2009
  ident: C9CC07763D-(cit7)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200900521
  contributor:
    fullname: Braunschweig
– volume: 46
  start-page: 1136
  year: 2010
  ident: C9CC07763D-(cit11e)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/b915395k
  contributor:
    fullname: Komuro
– volume: 24
  start-page: 5879
  year: 2005
  ident: C9CC07763D-(cit6c)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/om050630f
  contributor:
    fullname: Bunn
– volume: 36
  start-page: 2096
  year: 2017
  ident: C9CC07763D-(cit8c)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/acs.organomet.7b00137
  contributor:
    fullname: Kameo
– volume: 48
  start-page: 9892
  year: 2009
  ident: C9CC07763D-(cit8a)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200905391
  contributor:
    fullname: Gualco
– volume-title: Top. Organomet. Chem.
  year: 2013
  ident: C9CC07763D-(cit13a)/*[position()=1]
– volume: 105
  start-page: 5834
  year: 1983
  ident: C9CC07763D-(cit17c)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja00356a022
  contributor:
    fullname: Hersh
– start-page: 61
  year: 1987
  ident: C9CC07763D-(cit18a)/*[position()=1]
  publication-title: J. Chem. Soc., Dalton Trans.
  doi: 10.1039/DT9870000061
  contributor:
    fullname: Green
– volume: 47
  start-page: 12783
  year: 2011
  ident: C9CC07763D-(cit5c)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/c1cc15561j
  contributor:
    fullname: Bauer
– volume: 58
  start-page: 1
  year: 2010
  ident: C9CC07763D-(cit4b)/*[position()=1]
  publication-title: Adv. Organomet. Chem.
  doi: 10.1016/B978-0-12-374784-6.00001-2
  contributor:
    fullname: Bouhadir
– volume: 17
  start-page: 268
  year: 2017
  ident: C9CC07763D-(cit8e)/*[position()=2]
  publication-title: Chem. Rec.
  doi: 10.1002/tcr.201600061
  contributor:
    fullname: Kameo
– volume: 135
  start-page: 4942
  year: 2013
  ident: C9CC07763D-(cit18b)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja400128h
  contributor:
    fullname: Borren
– volume: 3
  start-page: 1292
  year: 1984
  ident: C9CC07763D-(cit5e)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/om00086a026
  contributor:
    fullname: Mayer
– volume-title: The Chemistry of Pincer Compounds
  year: 2007
  ident: C9CC07763D-(cit13b)/*[position()=1]
– volume: 14
  start-page: 731
  year: 2008
  ident: C9CC07763D-(cit3d)/*[position()=1]
  publication-title: Chem. – Eur. J.
  doi: 10.1002/chem.200701027
  contributor:
    fullname: Bontemps
– volume: 50
  start-page: 255
  year: 2011
  ident: C9CC07763D-(cit9a)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201005431
  contributor:
    fullname: Truflandier
– volume: 133
  start-page: 18118
  year: 2011
  ident: C9CC07763D-(cit3i)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja208675p
  contributor:
    fullname: Moret
– volume: 28
  start-page: 201
  year: 2005
  ident: C9CC07763D-(cit6d)/*[position()=1]
  publication-title: Main Group Met. Chem.
  doi: 10.1515/MGMC.2005.28.4.201
  contributor:
    fullname: Aldridge
– volume: 45
  start-page: 2588
  year: 2006
  ident: C9CC07763D-(cit3f)/*[position()=1]
  publication-title: Inorg. Chem.
  doi: 10.1021/ic051975t
  contributor:
    fullname: Landry
– volume: 136
  start-page: 13672
  year: 2014
  ident: C9CC07763D-(cit20)/*[position()=1]
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja504667f
  contributor:
    fullname: Lin
– volume: 626
  start-page: 82
  year: 2001
  ident: C9CC07763D-(cit6e)/*[position()=1]
  publication-title: J. Organomet. Chem.
  doi: 10.1016/S0022-328X(01)00656-8
  contributor:
    fullname: Linti
– volume: 629
  start-page: 1491
  year: 2003
  ident: C9CC07763D-(cit6g)/*[position()=1]
  publication-title: Z. Anorg. Allg. Chem.
  doi: 10.1002/zaac.200300037
  contributor:
    fullname: Vogel
– start-page: 1294
  year: 1979
  ident: C9CC07763D-(cit10)/*[position()=1]
  publication-title: J. Chem. Soc., Dalton Trans.
  doi: 10.1039/DT9790001294
  contributor:
    fullname: Ciriano
– volume: 611
  start-page: 323
  year: 2000
  ident: C9CC07763D-(cit11a)/*[position()=1]
  publication-title: J. Organomet. Chem.
  doi: 10.1016/S0022-328X(00)00492-7
  contributor:
    fullname: Osakada
– volume: 45
  start-page: 7056
  year: 2006
  ident: C9CC07763D-(cit3e)/*[position()=1]
  publication-title: Inorg. Chem.
  doi: 10.1021/ic061353n
  contributor:
    fullname: Figueroa
– volume: 50
  start-page: 4696
  year: 2011
  ident: C9CC07763D-(cit9d)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201007967
  contributor:
    fullname: Brendler
– volume: 33
  start-page: 653
  year: 2014
  ident: C9CC07763D-(cit15)/*[position()=1]
  publication-title: Organometallics
  doi: 10.1021/om400792j
  contributor:
    fullname: Dixon
– start-page: 112
  year: 1984
  ident: C9CC07763D-(cit17a)/*[position()=1]
  publication-title: J. Chem. Soc., Chem. Commun.
  doi: 10.1039/C39840000112
  contributor:
    fullname: Barr
– volume: 49
  start-page: 3219
  year: 2010
  ident: C9CC07763D-(cit11d)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.200905950
  contributor:
    fullname: Wilfling
– volume: 16
  start-page: 11985
  year: 2010
  ident: C9CC07763D-(cit5d)/*[position()=1]
  publication-title: Chem. – Eur. J.
  doi: 10.1002/chem.201001228
  contributor:
    fullname: Bauer
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Snippet The reactions of SiHPh(NCH PPh ) C H -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M {μ-κ -Si,P,P'-SiPh(CH PPh...
The reactions of SiHPh(NCH 2 PPh 2 ) 2 C 6 H 4 -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M 2 {μ-κ 3 -Si ,P...
The reactions of SiHPh(NCH2PPh2)2C6H4-1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes...
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SubjectTerms Bimetals
Crystallography
Ligands
Palladium
Platinum
Reagents
Silicon
Title Semi-bridging σ-silyls as Z-type ligands
URI https://www.ncbi.nlm.nih.gov/pubmed/32103222
https://www.proquest.com/docview/2382050181/abstract/
https://search.proquest.com/docview/2366643434
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