Semi-bridging σ-silyls as Z-type ligands

The reactions of SiHPh(NCH PPh ) C H -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M {μ-κ -Si,P,P'-SiPh(CH PPh ) C H } ] (M = Ni, Pd, Pt) in which the M-M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M Si core increa...

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Published inChemical communications (Cambridge, England) Vol. 56; no. 24; pp. 3532 - 3535
Main Authors Frogley, Benjamin J, Hill, Anthony F, Sharma, Manab, Sinha, Arup, Ward, Jas S
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 25.03.2020
Subjects
Bimetals
Crystallography
Ligands
Palladium
Platinum
Reagents
Silicon
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Abstract The reactions of SiHPh(NCH PPh ) C H -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M {μ-κ -Si,P,P'-SiPh(CH PPh ) C H } ] (M = Ni, Pd, Pt) in which the M-M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M Si core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal 'Z-type' silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.
AbstractList The reactions of SiHPh(NCH PPh ) C H -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M {μ-κ -Si,P,P'-SiPh(CH PPh ) C H } ] (M = Ni, Pd, Pt) in which the M-M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M Si core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal 'Z-type' silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.
The reactions of SiHPh(NCH2PPh2)2C6H4-1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M2{μ-κ3-Si,P,P′-SiPh(CH2PPh2)2C6H4}2] (M = Ni, Pd, Pt) in which the M–M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M2Si2 core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal ‘Z-type’ silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.
The reactions of SiHPh(NCH 2 PPh 2 ) 2 C 6 H 4 -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M 2 {μ-κ 3 -Si ,P , P ′-SiPh(CH 2 PPh 2 ) 2 C 6 H 4 } 2 ] (M = Ni, Pd, Pt) in which the M–M bond is unsymmetrically bridged by two σ-silyl groups. The asymmetry of the M 2 Si 2 core increases from Ni through Pd to Pt and is consistent with a bonding description in which one metal acts as an electron pair donor to a trigonal bipyramidal ‘Z-type’ silicon centre, reminsicent of semi-bridging coordination by CO, carbynes and boryl ligands.
Author Sharma, Manab
Sinha, Arup
Frogley, Benjamin J
Hill, Anthony F
Ward, Jas S
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Snippet The reactions of SiHPh(NCH PPh ) C H -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M {μ-κ -Si,P,P'-SiPh(CH PPh...
The reactions of SiHPh(NCH 2 PPh 2 ) 2 C 6 H 4 -1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes [M 2 {μ-κ 3 -Si ,P...
The reactions of SiHPh(NCH2PPh2)2C6H4-1,2 with a range of zerovalent group 10 reagents afford the homoleptic bimetallic complexes...
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SubjectTerms Bimetals
Crystallography
Ligands
Palladium
Platinum
Reagents
Silicon
Title Semi-bridging σ-silyls as Z-type ligands
URI https://www.ncbi.nlm.nih.gov/pubmed/32103222
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