Optimizing the removal of fluoride from water using new carbons obtained by modification of nut shell with a calcium solution from egg shell

• Published in: Biochemical engineering journal Vol. 62; pp. 1 - 7
• Main Authors: Hernández-Montoya, V., Ramírez-Montoya, L.A., Bonilla-Petriciolet, A., Montes-Morán, M.A.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.03.2012; Elsevier
• Subjects: Activated carbon; active sites; Adsorption; Biological and medical sciences; Biotechnology; Calcium; carbon; chemical speciation; Egg shell; elemental composition; Fluoride; Fundamental and applied biological sciences. Psychology; groundwater; Pecan nut shell; pecans; Taguchi method; Egg shell; Fluoride; Adsorption; Calcium; Pecan nut shell; Activated carbon; Water; Carbon; Optimization
• ISSN: 1369-703X; 1873-295X
• DOI: 10.1016/j.bej.2011.12.011

Carbons with specific calcium compounds were obtained from pecan nut shells modified with a calcium solution extracted from egg shells and they were efficient for the fluoride removal. [Display omitted] ► The pecan shells (PS) are an abundant waste derived of nut processing. ► The PS was used as precursor of activated carbon. ► The carbon was activated with a calcium solution extracted from egg shells. ► The activated carbon with calcium moieties were used in the fluoride removal from water. ► The calcium moieties are playing an important role in the fluoride adsorption mechanism. Carbons loaded with specific chemical moieties were prepared from pecan nut shells employing a natural modifier agent obtained from egg shell, which is rich in calcium, for the selective adsorption of fluoride from water. A L4 orthogonal array of the Taguchi method was used to optimize the synthesis conditions for obtaining these selective carbons. The samples obtained were characterized and the elemental composition, textural parameters and morphology were determined. Fluoride adsorption experiments were performed in synthetic and real groundwater samples. Results showed that carbons obtained from pecan nut shells modified with a calcium solution extracted from egg shells (CMPNS) were more effective for fluoride removal than those using the nut shell precursor as such. The calcium chemical species on the carbon surfaces were more important in the fluoride adsorption process than the carbon textural parameters. In addition, hydrogencarbonate was found to be the main competitor for the active sites of CMPNS during the fluoride removal process.