The confined space electron transfer in phosphotungstate intercalated ZnAl-LDHs enhances its photocatalytic performance for oxidation/extraction desulfurization of model oil in air

• Published in: Green chemistry : an international journal and green chemistry resource : GC Vol. 2; no. 24; pp. 559 - 5519
• Main Authors: Cai, Yingjie, Song, Hongyan, An, Zhe, Xiang, Xu, Shu, Xin, He, Jing
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 10.12.2018
• Subjects: Acetonitrile; air; Ambient temperature; Catalysis; Catalysts; Catalytic activity; Confined spaces; Desulfurization; Desulfurizing; Dibenzothiophene; Electrochemistry; Electron transfer; Environmental protection; Free radicals; fuels; Green chemistry; Irradiation; Oil; oils; oxidants; Oxidation; Oxidizing agents; Photocatalysis; photocatalysts; Photooxidation; Radiation dosage; Synergistic effect; trapping; Ultraviolet radiation

Deep desulfurization of fuels is a hot issue in the environmental protection field in recent years. Phosphotungstate intercalated hydrotalcites (ZnAl-(PW 12 O 40 ) x -LDHs) with varying amounts of PW 12 O 40 3− were prepared by an exfoliation-reassembly method, and their structures and properties we...