Selective oxidation of (hetero)sulfides with molecular oxygen under clean conditions

The development of eco-friendly and switchable catalytic systems for the conversion of a sole raw-material into distinct high-value products is a particularly attractive concept and a daunting synthetic challenge. In the present work, the first example of efficient and selective oxidation of sulfide...

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Published inGreen chemistry : an international journal and green chemistry resource : GC Vol. 22; no. 2; pp. 433 - 438
Main Authors Liu, Kai-Jian, Deng, Ji-Hui, Yang, Jie, Gong, Shao-Feng, Lin, Ying-Wu, He, Jun-Yi, Cao, Zhong, He, Wei-Min
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 27.01.2020
Royal Society of Chemistry
Subjects
catalytic activity
Catalytic converters
Chemistry
Chemistry, Multidisciplinary
Green & Sustainable Science & Technology
Green chemistry
high-value products
Oxidation
Oxygen
Physical Sciences
raw materials
Science & Technology
Science & Technology - Other Topics
Sulfides
Sulfones
ALCOHOLS
SULFOXIDES
INSERTION
ELECTRON
SULFIDES
AMBIENT
SULFONES
AEROBIC OXIDATIONS
METAL-FREE
CYCLIZATION
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Abstract The development of eco-friendly and switchable catalytic systems for the conversion of a sole raw-material into distinct high-value products is a particularly attractive concept and a daunting synthetic challenge. In the present work, the first example of efficient and selective oxidation of sulfides to sulfones and sulfoxides using molecular oxygen under clean conditions was established. The first example of selective oxidation of sulfides to sulfones and sulfoxides using molecular oxygen under clean conditions was established. The desired products could be easily collected through recrystallization in large-scale preparation.
AbstractList The development of eco-friendly and switchable catalytic systems for the conversion of a sole raw-material into distinct high-value products is a particularly attractive concept and a daunting synthetic challenge. In the present work, the first example of efficient and selective oxidation of sulfides to sulfones and sulfoxides using molecular oxygen under clean conditions was established.
The development of eco-friendly and switchable catalytic systems for the conversion of a sole raw-material into distinct high-value products is a particularly attractive concept and a daunting synthetic challenge. In the present work, the first example of efficient and selective oxidation of sulfides to sulfones and sulfoxides using molecular oxygen under clean conditions was established. The first example of selective oxidation of sulfides to sulfones and sulfoxides using molecular oxygen under clean conditions was established. The desired products could be easily collected through recrystallization in large-scale preparation.
Author Liu, Kai-Jian
He, Wei-Min
He, Jun-Yi
Yang, Jie
Gong, Shao-Feng
Lin, Ying-Wu
Deng, Ji-Hui
Cao, Zhong
AuthorAffiliation Department of Chemistry
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation
University of South China
Changsha University of Science and Technology
Hunan University of Science and Engineering
School of Chemistry and Chemical Engineering
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  givenname: Kai-Jian
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  fullname: Cao, Zhong
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  givenname: Wei-Min
  surname: He
  fullname: He, Wei-Min
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Issue 2
Keywords ALCOHOLS
SULFOXIDES
INSERTION
ELECTRON
SULFIDES
AMBIENT
SULFONES
AEROBIC OXIDATIONS
METAL-FREE
CYCLIZATION
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SSID ssj0011764
Score 2.6075873
Snippet The development of eco-friendly and switchable catalytic systems for the conversion of a sole raw-material into distinct high-value products is a particularly...
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SubjectTerms catalytic activity
Catalytic converters
Chemistry
Chemistry, Multidisciplinary
Green & Sustainable Science & Technology
Green chemistry
high-value products
Oxidation
Oxygen
Physical Sciences
raw materials
Science & Technology
Science & Technology - Other Topics
Sulfides
Sulfones
Title Selective oxidation of (hetero)sulfides with molecular oxygen under clean conditions
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Volume 22
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