The coordination chemistry of perfluorovinyl substituted phosphine ligands, a crystallographic and spectroscopic study. Co-crystallisation of both cis- and trans-isomers of [PtCl2{P(i)pr2(CF=CF2)}2] within the same unit cell

• Published in: Dalton transactions : an international journal of inorganic chemistry no. 1; pp. 101 - 114
• Main Authors: Barnes, Nicholas A, Brisdon, Alan K, Brown, F R William, Cross, Wendy I, Herbert, Christopher J, Pritchard, Robin G, Sadiq, Ghazala
• Format: Journal Article
• Language: English
• Published: England 01.01.2008

The coordination chemistry of the perfluorovinyl phosphines PEt2(CF=CF2), P(i)Pr2(CF=CF2), PCy,(CF=CF2) and PPh(CF=CF2)2 to rhodium(I), palladium(II), and platinum(II) centres has been investigated. The electronic properties of the ligands are estimated based on v(CO) and 1J(Rh-P) values. X-Ray diff...