Adsorption characteristics of carbon tetrachloride from aqueous solution onto polyacrylonitrile-based activated carbon fiber

The isotherm, mechanism and kinetics of carbon tetrachloride (CT) adsorption by polyacrylonitrile-based activated carbon fiber (PAN-ACF) were investigated in batch reactors and a continuous flow reactor, and the regeneration of PAN-ACF was also studied. Freundlich and Dubinin-Radushkevich (D-R) adso...

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Published inJournal of Central South University of Technology. Science & technology of mining and metallurgy Vol. 17; no. 5; pp. 972 - 978
Main Authors Liu, Wen-xia, Guan, Bao-hong, Yu, Jie
Format Journal Article
LanguageEnglish
Published Heidelberg Central South University 01.10.2010
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ISSN1005-9784
1993-0666
DOI10.1007/s11771-010-0586-1

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Abstract The isotherm, mechanism and kinetics of carbon tetrachloride (CT) adsorption by polyacrylonitrile-based activated carbon fiber (PAN-ACF) were investigated in batch reactors and a continuous flow reactor, and the regeneration of PAN-ACF was also studied. Freundlich and Dubinin-Radushkevich (D-R) adsorption equations can well describe the adsorption isotherm. CT is mainly adsorbed on the exterior surface of PAN-ACF with low boundary layer effect and rate-controlling step of intra-particle diffusion. The adsorption dynamics in the batch reactor well fits with the pseudo-first-order model, and the breakthrough curves in the continuous flow reactor can be well described by the Yoon-Nelson model. The ACF can be recycled through thermal regeneration, whereas the adsorption capacity decreases from 7.87 to 4.98 mg/g after the fourth regeneration. 78%–94% of CT can be removed from the wastewater of a fluorine chemical plant on a pilot scale, which confirms the efficacy of ACF under industrial conditions. The results indicate that PAN-ACF is applicable to CT removal from wastewater.
AbstractList The isotherm, mechanism and kinetics of carbon tetrachloride (CT) adsorption by polyacrylonitrile-based activated carbon fiber (PAN-ACF) were investigated in batch reactors and a continuous flow reactor, and the regeneration of PAN-ACF was also studied. Freundlich and Dubinin-Radushkevich (D-R) adsorption equations can well describe the adsorption isotherm. CT is mainly adsorbed on the exterior surface of PAN-ACF with low boundary layer effect and rate-controlling step of intra-particle diffusion. The adsorption dynamics in the batch reactor well fits with the pseudo-first-order model, and the breakthrough curves in the continuous flow reactor can be well described by the Yoon-Nelson model. The ACF can be recycled through thermal regeneration, whereas the adsorption capacity decreases from 7.87 to 4.98 mg/g after the fourth regeneration. 78%–94% of CT can be removed from the wastewater of a fluorine chemical plant on a pilot scale, which confirms the efficacy of ACF under industrial conditions. The results indicate that PAN-ACF is applicable to CT removal from wastewater.
Author Liu, Wen-xia
Guan, Bao-hong
Yu, Jie
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10.1021/ja01203a066
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– reference: YoonY. H.NelsonJ. H.Application of gas adsorption kinetics I: A theoretical model for respirator cartridge service life [J]American Industrial Hygiene Association Journal1984458509516
– reference: ReichenbergD.Properties of ion exchange resins in relation to their structure. III: Kinetics of exchange [J]Journal of the American Chemical Society195375358959710.1021/ja01099a022
– reference: OhsakaT.ShinozakiK.TsurutaK.HiranoK.Photo-electrochemical degradation of some chlorinated organic compounds on n-TiO2 electrode [J]Chemosphere20087381279128310.1016/j.chemosphere.2008.07.016
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– reference: MunC. H.NgW. J.HeJ. Z.Evaluation of biodegradation potential of carbon tetrachloride and chlorophenols under acidogenic condition [J]Journal of Environmental Engineering2008134317718310.1061/(ASCE)0733-9372(2008)134:3(177)
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– reference: KimB. K.RyuS. K.KimB. J.ParkS. J.Adsorption behavior of propylamine on activated carbon fiber surfaces as induced by oxygen functional complexes [J]Journal of Colloid and Interface Science2006302269569710.1016/j.jcis.2006.07.028
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– reference: HernandezM. A.GonzalezA. I.RojasF.AsomozaM.SolisS.PortilloR.Adsorption of chlorinated compounds (chlorobenzene, chloroform, and carbon tetrachloride) on microporous SiO2, Ag-doped SiO2 and natural and dealuminated clinoptilolites [J]Industrial and Engineering Chemistry Research200746103373338110.1021/ie061041s
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– reference: ShenW.-z.WangH.GuanR.-g.LiZ.-jie.Surface modification of activated carbon fiber and its adsorption for vitamin B1 and folic acid [J]Colloids and Surfaces A: Physicochemical and Engineering Aspects2008331326326710.1016/j.colsurfa.2008.08.017
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Snippet The isotherm, mechanism and kinetics of carbon tetrachloride (CT) adsorption by polyacrylonitrile-based activated carbon fiber (PAN-ACF) were investigated in...
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Metallic Materials
Title Adsorption characteristics of carbon tetrachloride from aqueous solution onto polyacrylonitrile-based activated carbon fiber
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