Luminescence studies of the rare earth ions-doped CaF2 and MgF2 films for wavelength conversion

The rare earth (RE) Eu, Yb ions-doped CaF2 and MgF2 films were prepared by the vacuum deposition and sol-gel methods. In the sol-gel method, the trifluoroacetic acid (TFA, CF3000H) was used as a source of fluorine. The RE doped CaF2 and MgF2 films were characterized by photoluminescence (PL), photol...

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Published inJournal of alloys and compounds Vol. 408-412; pp. 838 - 841
Main Authors Hong, Byung-Chul, Kawano, Katsuyasu
Format Journal Article
LanguageEnglish
Published 09.02.2006
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Abstract The rare earth (RE) Eu, Yb ions-doped CaF2 and MgF2 films were prepared by the vacuum deposition and sol-gel methods. In the sol-gel method, the trifluoroacetic acid (TFA, CF3000H) was used as a source of fluorine. The RE doped CaF2 and MgF2 films were characterized by photoluminescence (PL), photoluminescence excitation (PLE), the X-ray diffraction (XRD) and the atomic force microscopy (AFM) measurements. By the vacuum deposition, the strong luminescence due to the electric dipole allowed 4fn-4fn-15d1 transitions of Eu2+ and Yb2+ ions were observed similar with those of the crystalline bulks. The AFM surface images of sol-gel films revealed the formation of the nano-particles for alkaline earth fluorides.
AbstractList The rare earth (RE) Eu, Yb ions-doped CaF2 and MgF2 films were prepared by the vacuum deposition and sol-gel methods. In the sol-gel method, the trifluoroacetic acid (TFA, CF3000H) was used as a source of fluorine. The RE doped CaF2 and MgF2 films were characterized by photoluminescence (PL), photoluminescence excitation (PLE), the X-ray diffraction (XRD) and the atomic force microscopy (AFM) measurements. By the vacuum deposition, the strong luminescence due to the electric dipole allowed 4fn-4fn-15d1 transitions of Eu2+ and Yb2+ ions were observed similar with those of the crystalline bulks. The AFM surface images of sol-gel films revealed the formation of the nano-particles for alkaline earth fluorides.
Author Kawano, Katsuyasu
Hong, Byung-Chul
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Snippet The rare earth (RE) Eu, Yb ions-doped CaF2 and MgF2 films were prepared by the vacuum deposition and sol-gel methods. In the sol-gel method, the...
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Title Luminescence studies of the rare earth ions-doped CaF2 and MgF2 films for wavelength conversion
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