Synthesis of dual stimuli-responsive polymers through atom transfer radical mechanism in aqueous media
New dual stimuli-responsive (thermo- & pH-) polymers were successfully synthesized through an atom transfer radical mechanism in aqueous media. N-Isopropylacrylamide (NiPAM) ([N]) as a precursor of temperatureresponsive moiety and sulfonamide-modified styrenic monomer and methacrylamide ([S]) we...
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Published in | Macromolecular research Vol. 25; no. 1; pp. 70 - 78 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Seoul
The Polymer Society of Korea
2017
Springer Nature B.V 한국고분자학회 |
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Abstract | New dual stimuli-responsive (thermo- & pH-) polymers were successfully synthesized through an atom transfer radical mechanism in aqueous media. N-Isopropylacrylamide (NiPAM) ([N]) as a precursor of temperatureresponsive moiety and sulfonamide-modified styrenic monomer and methacrylamide ([S]) were employed for the synthesis of the smart copolymers. The molar ratio of NiPAM to sulfonamide composed of the polymer backbone played an important role in the control of the phase transitional behavior of the formed block polymers. When the composition ratio of [S]/[N] decreases from 1/1 to 1/2, the dual stimuli-responsive phase behavior was clearly observed. Another important factor for the control of the phase morphology was to obtain the reactivity ratios,
r
1
and
r
2
, of the two monomers. In this study, Cu(I)-catalyzed copolymerization of sulfadimethoxinyl methacrylamide (MASX; M
1
) and NiPAM (M
2
) as the precursors of smart materials yielded
r
1
= 8.046 and
r
2
=1.572, leading to the production of a gradient type of copolymer in aqueous media. |
---|---|
AbstractList | New dual stimuli-responsive (thermo- & pH-) polymers were successfully synthesized through an atom transfer radical mechanism in aqueous media. N-Isopropylacrylamide (NiPAM) ([N]) as a precursor of temperatureresponsive moiety and sulfonamide-modified styrenic monomer and methacrylamide ([S]) were employed for the synthesis of the smart copolymers. The molar ratio of NiPAM to sulfonamide composed of the polymer backbone played an important role in the control of the phase transitional behavior of the formed block polymers. When the composition ratio of [S]/[N] decreases from 1/1 to 1/2, the dual stimuli-responsive phase behavior was clearly observed. Another important factor for the control of the phase morphology was to obtain the reactivity ratios,
r
1
and
r
2
, of the two monomers. In this study, Cu(I)-catalyzed copolymerization of sulfadimethoxinyl methacrylamide (MASX; M
1
) and NiPAM (M
2
) as the precursors of smart materials yielded
r
1
= 8.046 and
r
2
=1.572, leading to the production of a gradient type of copolymer in aqueous media. New dual stimuli-responsive (thermo- & pH-) polymers were successfully synthesized through an atom transfer radical mechanism in aqueous media. N-Isopropylacrylamide (NiPAM) ([N]) as a precursor of temperatureresponsive moiety and sulfonamide-modified styrenic monomer and methacrylamide ([S]) were employed for the synthesis of the smart copolymers. The molar ratio of NiPAM to sulfonamide composed of the polymer backbone played an important role in the control of the phase transitional behavior of the formed block polymers. When the composition ratio of [S]/[N] decreases from 1/1 to 1/2, the dual stimuli-responsive phase behavior was clearly observed. Another important factor for the control of the phase morphology was to obtain the reactivity ratios, r1 and r2, of the two monomers. In this study, Cu(I)-catalyzed copolymerization of sulfadimethoxinyl methacrylamide (MASX; M1) and NiPAM (M2) as the precursors of smart materials yielded r1 = 8.046 and r2=1.572, leading to the production of a gradient type of copolymer in aqueous media. New dual stimuli-responsive (thermo- & pH-) polymers were successfully synthesized through an atom transfer radical mechanism in aqueous media. N-Isopropylacrylamide (NiPAM) ([N]) as a precursor of temperatureresponsive moiety and sulfonamide-modified styrenic monomer and methacrylamide ([S]) were employed for the synthesis of the smart copolymers. The molar ratio of NiPAM to sulfonamide composed of the polymer backbone played an important role in the control of the phase transitional behavior of the formed block polymers. When the composition ratio of [S]/[N] decreases from 1/1 to 1/2, the dual stimuli-responsive phase behavior was clearly observed. Another important factor for the control of the phase morphology was to obtain the reactivity ratios, r1 and r2, of the two monomers. In this study, Cu(I)-catalyzed copolymerization of sulfadimethoxinyl methacrylamide (MASX; M1) and NiPAM (M2) as the precursors of smart materials yielded r1 = 8.046 and r2=1.572, leading to the production of a gradient type of copolymer in aqueous media. KCI Citation Count: 7 |
Author | Siddique, Abu B. Kang, Ho-Jung An, Jin Wook Lee, Young Jin Lee, Jae Yeol Kim, Hyun Jun Kim, Jungahn Park, Hyeongjong Kim, Sehoon Lee, Geon Chang |
Author_xml | – sequence: 1 givenname: Abu B. surname: Siddique fullname: Siddique, Abu B. organization: Department of Chemistry, Kyung Hee University – sequence: 2 givenname: Jin Wook surname: An fullname: An, Jin Wook organization: Department of Chemistry, Kyung Hee University – sequence: 3 givenname: Hyun Jun surname: Kim fullname: Kim, Hyun Jun organization: Department of Chemistry, Kyung Hee University – sequence: 4 givenname: Hyeongjong surname: Park fullname: Park, Hyeongjong organization: Department of Chemistry, Kyung Hee University – sequence: 5 givenname: Young Jin surname: Lee fullname: Lee, Young Jin organization: Department of Chemistry, Kyung Hee University – sequence: 6 givenname: Geon Chang surname: Lee fullname: Lee, Geon Chang organization: Department of Chemistry, Kyung Hee University – sequence: 7 givenname: Ho-Jung surname: Kang fullname: Kang, Ho-Jung organization: Department of Chemistry, Kyung Hee University – sequence: 8 givenname: Jae Yeol surname: Lee fullname: Lee, Jae Yeol organization: Department of Chemistry, Kyung Hee University – sequence: 9 givenname: Sehoon surname: Kim fullname: Kim, Sehoon organization: Center for Theranostics, Korea Institute of Science and Technology – sequence: 10 givenname: Jungahn surname: Kim fullname: Kim, Jungahn email: jakim05@khu.ac.kr organization: Department of Chemistry, Kyung Hee University |
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Cites_doi | 10.1002/polc.5070510111 10.1021/ma071203b 10.1002/(SICI)1521-3927(19990501)20:5<269::AID-MARC269>3.0.CO;2-3 10.1002/pol.1950.120050210 10.1021/bc980054m 10.1063/1.453267 10.1016/0014-2964(73)90042-X 10.1021/cr9901182 10.1021/acs.langmuir.6b00392 10.1007/s00396-008-1922-y 10.1016/j.colsurfb.2011.09.028 10.1002/1099-1395(200012)13:12<775::AID-POC314>3.0.CO;2-D 10.1021/cr940534g 10.1063/1.447548 10.1021/ar000011x 10.1002/med.10047 10.1002/1521-3773(20020415)41:8<1413::AID-ANIE1413>3.0.CO;2-K 10.1021/ja982295a 10.1126/science.1078192 10.1038/354291a0 10.1038/373049a0 10.1007/BF03218847 10.1021/ma0349985 10.1038/35007047 10.1021/jp100714j 10.1021/ma00062a016 10.1007/3-540-45362-8_3 10.1002/masy.19870100117 |
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Keywords | block copolymer reactivity ratio atom transfer radical polymerization dual stimuli-responsive gradient polymer |
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SubjectTerms | Aqueous solutions Characterization and Evaluation of Materials Chemical synthesis Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Copolymerization Copolymers Isopropylacrylamide Methacrylamide Monomers Morphology Nanochemistry Nanotechnology Phase transitions Physical Chemistry Polymer Sciences Polymers Precursors Smart materials Soft and Granular Matter Stimuli Sulfonamides 고분자공학 |
Title | Synthesis of dual stimuli-responsive polymers through atom transfer radical mechanism in aqueous media |
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ispartofPNX | Macromolecular Research, 2017, 25(1), , pp.70-78 |
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