Reclaiming Inactive Lithium with a Triiodide/Iodide Redox Couple for Practical Lithium Metal Batteries
High‐energy‐density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by the consumption of electrolyte and active Li reservoir, seriously deteriorating the cyclability of batteries. Herein, a triiodide/iodide (I3−/...
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| Published in | Angewandte Chemie International Edition Vol. 60; no. 42; pp. 22990 - 22995 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley Subscription Services, Inc
11.10.2021
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| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1433-7851 1521-3773 1521-3773 |
| DOI | 10.1002/anie.202110589 |
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| Abstract | High‐energy‐density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by the consumption of electrolyte and active Li reservoir, seriously deteriorating the cyclability of batteries. Herein, a triiodide/iodide (I3−/I−) redox couple initiated by stannic iodide (SnI4) is demonstrated to reclaim inactive Li. The reduction of I3− converts inactive Li into soluble LiI, which then diffuses to the cathode side. The oxidation of LiI by the delithiated cathode transforms cathode into the lithiation state and regenerates I3−, reclaiming Li ion from inactive Li. The regenerated I3− engages the further redox reactions. Furthermore, the formation of Sn mitigates the corrosion of I3− on active Li reservoir sacrificially. In working Li | LiNi0.5Co0.2Mn0.3O2 batteries, the accumulated inactive Li is significantly reclaimed by the reversible I3−/I− redox couple, improving the lifespan of batteries by twice. This work initiates a creative solution to reclaim inactive Li for prolonging the lifespan of practical Li metal batteries.
A triiodide/iodide (I3−/I−) redox couple is introduced with a SnI4 initiator to reclaim inactive Li. The reduction of I3− converts inactive Li into soluble LiI, and the oxidation of LiI by a delithiated cathode realizes the restoration of Li ion in cathode from inactive Li. The regenerated I3− by oxidation engages the further redox reactions. |
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| AbstractList | High‐energy‐density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by the consumption of electrolyte and active Li reservoir, seriously deteriorating the cyclability of batteries. Herein, a triiodide/iodide (I3−/I−) redox couple initiated by stannic iodide (SnI4) is demonstrated to reclaim inactive Li. The reduction of I3− converts inactive Li into soluble LiI, which then diffuses to the cathode side. The oxidation of LiI by the delithiated cathode transforms cathode into the lithiation state and regenerates I3−, reclaiming Li ion from inactive Li. The regenerated I3− engages the further redox reactions. Furthermore, the formation of Sn mitigates the corrosion of I3− on active Li reservoir sacrificially. In working Li | LiNi0.5Co0.2Mn0.3O2 batteries, the accumulated inactive Li is significantly reclaimed by the reversible I3−/I− redox couple, improving the lifespan of batteries by twice. This work initiates a creative solution to reclaim inactive Li for prolonging the lifespan of practical Li metal batteries. High‐energy‐density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by the consumption of electrolyte and active Li reservoir, seriously deteriorating the cyclability of batteries. Herein, a triiodide/iodide (I 3 − /I − ) redox couple initiated by stannic iodide (SnI 4 ) is demonstrated to reclaim inactive Li. The reduction of I 3 − converts inactive Li into soluble LiI, which then diffuses to the cathode side. The oxidation of LiI by the delithiated cathode transforms cathode into the lithiation state and regenerates I 3 − , reclaiming Li ion from inactive Li. The regenerated I 3 − engages the further redox reactions. Furthermore, the formation of Sn mitigates the corrosion of I 3 − on active Li reservoir sacrificially. In working Li | LiNi 0.5 Co 0.2 Mn 0.3 O 2 batteries, the accumulated inactive Li is significantly reclaimed by the reversible I 3 − /I − redox couple, improving the lifespan of batteries by twice. This work initiates a creative solution to reclaim inactive Li for prolonging the lifespan of practical Li metal batteries. High‐energy‐density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by the consumption of electrolyte and active Li reservoir, seriously deteriorating the cyclability of batteries. Herein, a triiodide/iodide (I3−/I−) redox couple initiated by stannic iodide (SnI4) is demonstrated to reclaim inactive Li. The reduction of I3− converts inactive Li into soluble LiI, which then diffuses to the cathode side. The oxidation of LiI by the delithiated cathode transforms cathode into the lithiation state and regenerates I3−, reclaiming Li ion from inactive Li. The regenerated I3− engages the further redox reactions. Furthermore, the formation of Sn mitigates the corrosion of I3− on active Li reservoir sacrificially. In working Li | LiNi0.5Co0.2Mn0.3O2 batteries, the accumulated inactive Li is significantly reclaimed by the reversible I3−/I− redox couple, improving the lifespan of batteries by twice. This work initiates a creative solution to reclaim inactive Li for prolonging the lifespan of practical Li metal batteries. A triiodide/iodide (I3−/I−) redox couple is introduced with a SnI4 initiator to reclaim inactive Li. The reduction of I3− converts inactive Li into soluble LiI, and the oxidation of LiI by a delithiated cathode realizes the restoration of Li ion in cathode from inactive Li. The regenerated I3− by oxidation engages the further redox reactions. High-energy-density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by the consumption of electrolyte and active Li reservoir, seriously deteriorating the cyclability of batteries. Herein, a triiodide/iodide (I3 - /I- ) redox couple initiated by stannic iodide (SnI4 ) is demonstrated to reclaim inactive Li. The reduction of I3 - converts inactive Li into soluble LiI, which then diffuses to the cathode side. The oxidation of LiI by the delithiated cathode transforms cathode into the lithiation state and regenerates I3 - , reclaiming Li ion from inactive Li. The regenerated I3 - engages the further redox reactions. Furthermore, the formation of Sn mitigates the corrosion of I3 - on active Li reservoir sacrificially. In working Li | LiNi0.5 Co0.2 Mn0.3 O2 batteries, the accumulated inactive Li is significantly reclaimed by the reversible I3 - /I- redox couple, improving the lifespan of batteries by twice. This work initiates a creative solution to reclaim inactive Li for prolonging the lifespan of practical Li metal batteries.High-energy-density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by the consumption of electrolyte and active Li reservoir, seriously deteriorating the cyclability of batteries. Herein, a triiodide/iodide (I3 - /I- ) redox couple initiated by stannic iodide (SnI4 ) is demonstrated to reclaim inactive Li. The reduction of I3 - converts inactive Li into soluble LiI, which then diffuses to the cathode side. The oxidation of LiI by the delithiated cathode transforms cathode into the lithiation state and regenerates I3 - , reclaiming Li ion from inactive Li. The regenerated I3 - engages the further redox reactions. Furthermore, the formation of Sn mitigates the corrosion of I3 - on active Li reservoir sacrificially. In working Li | LiNi0.5 Co0.2 Mn0.3 O2 batteries, the accumulated inactive Li is significantly reclaimed by the reversible I3 - /I- redox couple, improving the lifespan of batteries by twice. This work initiates a creative solution to reclaim inactive Li for prolonging the lifespan of practical Li metal batteries. |
| Author | Shi, Peng Huang, Jia‐Qi Tao, Xin‐Yong Jin, Cheng‐Bin Zhang, Qiang Hou, Li‐Peng Sheng, Ou‐Wei Li, Bo‐Quan Zhang, Xue‐Qiang Sun, Shu‐Yu |
| Author_xml | – sequence: 1 givenname: Cheng‐Bin orcidid: 0000-0002-0304-8814 surname: Jin fullname: Jin, Cheng‐Bin organization: Tsinghua University – sequence: 2 givenname: Xue‐Qiang orcidid: 0000-0003-2856-1881 surname: Zhang fullname: Zhang, Xue‐Qiang organization: Tsinghua University – sequence: 3 givenname: Ou‐Wei surname: Sheng fullname: Sheng, Ou‐Wei organization: Zhejiang University of Technology – sequence: 4 givenname: Shu‐Yu surname: Sun fullname: Sun, Shu‐Yu organization: Tsinghua University – sequence: 5 givenname: Li‐Peng surname: Hou fullname: Hou, Li‐Peng organization: Tsinghua University – sequence: 6 givenname: Peng surname: Shi fullname: Shi, Peng organization: Tsinghua University – sequence: 7 givenname: Bo‐Quan surname: Li fullname: Li, Bo‐Quan organization: Beijing Institute of Technology – sequence: 8 givenname: Jia‐Qi orcidid: 0000-0001-7394-9186 surname: Huang fullname: Huang, Jia‐Qi organization: Beijing Institute of Technology – sequence: 9 givenname: Xin‐Yong orcidid: 0000-0003-4084-7743 surname: Tao fullname: Tao, Xin‐Yong organization: Zhejiang University of Technology – sequence: 10 givenname: Qiang orcidid: 0000-0002-3929-1541 surname: Zhang fullname: Zhang, Qiang email: zhang-qiang@mails.tsinghua.edu.cn organization: Tsinghua University |
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| Snippet | High‐energy‐density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by... High-energy-density lithium (Li) metal batteries suffer from a short lifespan owing to apparently ceaseless inactive Li accumulation, which is accompanied by... |
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| SubjectTerms | Cathodes I3−/I− redox couple Iodides Life span Lithium Lithium batteries lithium metal anode Oxidation practical lithium batteries reclaiming inactive lithium Redox reactions Reservoirs |
| Title | Reclaiming Inactive Lithium with a Triiodide/Iodide Redox Couple for Practical Lithium Metal Batteries |
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