Keeping Superprotonic Conductivity over a Wide Temperature Region via Sulfate Hopping Sites‐Decorated Zirconium‐Oxo Clusters

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 18; no. 48; pp. e2205444 - n/a
• Main Authors: Xie, Wei‐Lian, Li, Xiao‐Min, Lin, Jiao‐Min, Dong, Long‐zhang, Chen, Yu, Li, Ning, Shi, Jing‐Wen, Liu, Jing‐Jing, Liu, Jiang, Li, Shun‐Li, Lan, Ya‐Qian
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 01.12.2022
• Subjects: Clusters; Conduction; Conductivity; Conductors; hydrogen bonds; Lewis acidity; Nanotechnology; proton transport; Protons; Relative humidity; sulfate group; Zirconium; zirconium‐oxo clusters
• ISSN: 1613-6810; 1613-6829; 1613-6829
• DOI: 10.1002/smll.202205444

Metal‐oxo clusters have emerged as advanced proton conductors with well‐defined and tunable structures. Nevertheless, the exploitation of metal‐oxo clusters with high and stable proton conductivity over a relatively wide temperature range still remains a great challenge. Herein, three sulfate groups...