Chemoselective Quinoline and Isoquinoline Reduction by Energy Transfer Catalysis Enabled Hydrogen Atom Transfer

• Published in: Angewandte Chemie International Edition Vol. 62; no. 48; pp. e202312203 - n/a
• Main Authors: Liu, De‐Hai, Nagashima, Kyogo, Liang, Hui, Yue, Xue‐Lin, Chu, Yun‐Peng, Chen, Shuming, Ma, Jiajia
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 27.11.2023; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Alkanes; Alkenes; Catalysis; Chemical reduction; Chemistry; Chemistry, Multidisciplinary; Chemoselectivity; Dearomatization; Energy Transfer; Functional groups; Hydrogen; Hydrogen atoms; Physical Sciences; Quinoline; Reduction; Science & Technology; Visible Light; ELECTROREDUCTION; Chemoselectivity; ARENES; PHOTO-BIRCH REDUCTION; AROMATIC-COMPOUNDS; SODIUM-BOROHYDRIDE; Reduction; Visible Light; PHOTOREDUCTION; Dearomatization; Energy Transfer; LITHIUM; ELECTRON-TRANSFER REACTIONS; ACCESS

(Hetero)arene reduction is one of the key avenues for synthesizing related cyclic alkenes and alkanes. While catalytic hydrogenation and Birch reduction are the two broadly utilized approaches for (hetero)arene reduction across academia and industry over the last century, both methods have encounter...