SMM Behaviour of the Butterfly {CrIII2DyIII2} Pivalate Complex and Magneto‐structurally Correlated Relaxation Thermal Barrier
We are reporting the synthesis, single‐crystal X‐ray structure characterization, and magnetic property investigations of the pivalate butterfly {CrIII2LnIII2} complexes with Ln= Gd and Dy and the isostructural Y(III) sample. We found an anti‐ferromagnetic Cr(III)‐Ln(III) exchange interaction, which,...
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Published in | Chemistry : a European journal Vol. 28; no. 59; pp. e202201450 - n/a |
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Language | English |
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21.10.2022
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Abstract | We are reporting the synthesis, single‐crystal X‐ray structure characterization, and magnetic property investigations of the pivalate butterfly {CrIII2LnIII2} complexes with Ln= Gd and Dy and the isostructural Y(III) sample. We found an anti‐ferromagnetic Cr(III)‐Ln(III) exchange interaction, which, as previously observed in related Cr(III)/Ln(III) systems, plays a key role in suppressing quantum tunnelling of magnetization and enhances the SMM performance in the Dy(III) complex. In fact, a pure Orbach relaxation mechanism, with absence of QT regime, is observed with a thermal barrier of 50 cm−1, leading to magnetization hysteresis opening, measured with a commercial magnetometer, up to 3.6 K with a coercive field of 2.9 T. Analysis of SMM behaviour in literature‐known butterfly {CrIII2DyIII2} complexes, reveals the existence of a magneto‐structural correlation between Ueff, the thermal barrier size, and the mean Cr−Dy bond distances. Moreover, a clear correlation is found for the thermal barrier magnitude and the maximum temperature hysteresis opening and coercive field.
We report a new pivalate butterfly {CrIII2LnIII2} system with magnetization tunneling relaxation suppresion and hysteresis opening up to 3.6 K in the Ln=Dy complex, due to Cr−Dy exchange interaction. We have found a magneto‐structural correlation between the Orbach thermal barrier for magentization reversal and the mean Cr−Dy bond lenght across all literature reported butterfly {CrIII2DyIII2} complexes. |
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AbstractList | We are reporting the synthesis, single‐crystal X‐ray structure characterization, and magnetic property investigations of the pivalate butterfly {CrIII2LnIII2} complexes with Ln= Gd and Dy and the isostructural Y(III) sample. We found an anti‐ferromagnetic Cr(III)‐Ln(III) exchange interaction, which, as previously observed in related Cr(III)/Ln(III) systems, plays a key role in suppressing quantum tunnelling of magnetization and enhances the SMM performance in the Dy(III) complex. In fact, a pure Orbach relaxation mechanism, with absence of QT regime, is observed with a thermal barrier of 50 cm−1, leading to magnetization hysteresis opening, measured with a commercial magnetometer, up to 3.6 K with a coercive field of 2.9 T. Analysis of SMM behaviour in literature‐known butterfly {CrIII2DyIII2} complexes, reveals the existence of a magneto‐structural correlation between Ueff, the thermal barrier size, and the mean Cr−Dy bond distances. Moreover, a clear correlation is found for the thermal barrier magnitude and the maximum temperature hysteresis opening and coercive field.
We report a new pivalate butterfly {CrIII2LnIII2} system with magnetization tunneling relaxation suppresion and hysteresis opening up to 3.6 K in the Ln=Dy complex, due to Cr−Dy exchange interaction. We have found a magneto‐structural correlation between the Orbach thermal barrier for magentization reversal and the mean Cr−Dy bond lenght across all literature reported butterfly {CrIII2DyIII2} complexes. We are reporting the synthesis, single‐crystal X‐ray structure characterization, and magnetic property investigations of the pivalate butterfly {CrIII2LnIII2} complexes with Ln= Gd and Dy and the isostructural Y(III) sample. We found an anti‐ferromagnetic Cr(III)‐Ln(III) exchange interaction, which, as previously observed in related Cr(III)/Ln(III) systems, plays a key role in suppressing quantum tunnelling of magnetization and enhances the SMM performance in the Dy(III) complex. In fact, a pure Orbach relaxation mechanism, with absence of QT regime, is observed with a thermal barrier of 50 cm−1, leading to magnetization hysteresis opening, measured with a commercial magnetometer, up to 3.6 K with a coercive field of 2.9 T. Analysis of SMM behaviour in literature‐known butterfly {CrIII2DyIII2} complexes, reveals the existence of a magneto‐structural correlation between Ueff, the thermal barrier size, and the mean Cr−Dy bond distances. Moreover, a clear correlation is found for the thermal barrier magnitude and the maximum temperature hysteresis opening and coercive field. Abstract We are reporting the synthesis, single‐crystal X‐ray structure characterization, and magnetic property investigations of the pivalate butterfly {Cr III 2 Ln III 2 } complexes with Ln= Gd and Dy and the isostructural Y(III) sample. We found an anti‐ferromagnetic Cr(III)‐Ln(III) exchange interaction, which, as previously observed in related Cr(III)/Ln(III) systems, plays a key role in suppressing quantum tunnelling of magnetization and enhances the SMM performance in the Dy(III) complex. In fact, a pure Orbach relaxation mechanism, with absence of QT regime, is observed with a thermal barrier of 50 cm −1 , leading to magnetization hysteresis opening, measured with a commercial magnetometer, up to 3.6 K with a coercive field of 2.9 T. Analysis of SMM behaviour in literature‐known butterfly {Cr III 2 Dy III 2 } complexes, reveals the existence of a magneto‐structural correlation between U eff , the thermal barrier size, and the mean Cr−Dy bond distances. Moreover, a clear correlation is found for the thermal barrier magnitude and the maximum temperature hysteresis opening and coercive field. |
Author | Carrella, Luca M. Mecchia Ortiz, Juan H. Alborés, Pablo Cabrosi, Daiana Rentschler, Eva |
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Snippet | We are reporting the synthesis, single‐crystal X‐ray structure characterization, and magnetic property investigations of the pivalate butterfly {CrIII2LnIII2}... Abstract We are reporting the synthesis, single‐crystal X‐ray structure characterization, and magnetic property investigations of the pivalate butterfly {Cr... |
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SubjectTerms | Chemistry Chromium Coercivity Correlation Dysprosium Ferromagnetism Gadolinium heteronuclear 3d/4 f Hysteresis Magnetic properties Magnetization magneto structural correlation Magnetometers Quantum tunnelling SMM Structural analysis Thermal barriers Trivalent chromium tunneling suppression |
Title | SMM Behaviour of the Butterfly {CrIII2DyIII2} Pivalate Complex and Magneto‐structurally Correlated Relaxation Thermal Barrier |
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