Leaching kinetics of scheelite with sodium phytate
Considering the environmental requirements and cost of energy consumption, organic phytic acid salt, a non-toxic and non-polluted green reagent, was used to decompose scheelite. The present study investigated the leaching kinetics of scheelite ore with sodium phytate. The effects of reaction tempera...
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| Published in | Hydrometallurgy Vol. 186; pp. 83 - 90 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.06.2019
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| Abstract | Considering the environmental requirements and cost of energy consumption, organic phytic acid salt, a non-toxic and non-polluted green reagent, was used to decompose scheelite. The present study investigated the leaching kinetics of scheelite ore with sodium phytate. The effects of reaction temperature, initial sodium phytate concentration, scheelite ore particle size, and stirring speed on the scheelite leaching rate were analyzed. While independent of stirring speed, it was found that the leaching rate was significantly influenced by the temperatures and particle sizes at the investigated range. The leaching data revealed that the effects of the relevant operating variables on leaching rates are consistent with the shrinking-core model, with internal diffusion being the rate-controlling step. The apparent activation energy based on the Arrhenius expression was calculated as 84.54 kJ/mol, and the kinetic equation associated with the leaching rate of scheelite was established using quadratic regression.
•A green reagent sodium phytate is proposed for decomposition of scheelite.•The leaching kinetics is investigated based on unreacted shrinking core model.•The decomposition reaction of scheelite is controlled by internal diffusion.•The SEM results clearly demonstrate the internal diffusion mechanism. |
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| AbstractList | Considering the environmental requirements and cost of energy consumption, organic phytic acid salt, a non-toxic and non-polluted green reagent, was used to decompose scheelite. The present study investigated the leaching kinetics of scheelite ore with sodium phytate. The effects of reaction temperature, initial sodium phytate concentration, scheelite ore particle size, and stirring speed on the scheelite leaching rate were analyzed. While independent of stirring speed, it was found that the leaching rate was significantly influenced by the temperatures and particle sizes at the investigated range. The leaching data revealed that the effects of the relevant operating variables on leaching rates are consistent with the shrinking-core model, with internal diffusion being the rate-controlling step. The apparent activation energy based on the Arrhenius expression was calculated as 84.54 kJ/mol, and the kinetic equation associated with the leaching rate of scheelite was established using quadratic regression.
•A green reagent sodium phytate is proposed for decomposition of scheelite.•The leaching kinetics is investigated based on unreacted shrinking core model.•The decomposition reaction of scheelite is controlled by internal diffusion.•The SEM results clearly demonstrate the internal diffusion mechanism. |
| Author | Zhu, Xinrui Zhao, Zhongwei Liu, Xuheng |
| Author_xml | – sequence: 1 givenname: Xinrui surname: Zhu fullname: Zhu, Xinrui organization: School of Metallurgy and Environment, Central South University, Changsha 410083, China – sequence: 2 givenname: Xuheng surname: Liu fullname: Liu, Xuheng email: liuxuheng@csu.edu.cn organization: School of Metallurgy and Environment, Central South University, Changsha 410083, China – sequence: 3 givenname: Zhongwei surname: Zhao fullname: Zhao, Zhongwei organization: School of Metallurgy and Environment, Central South University, Changsha 410083, China |
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| Cites_doi | 10.1080/12269328.2016.1186577 10.1016/j.hydromet.2016.05.018 10.3989/egeol.39849.060 10.1016/0304-386X(87)90010-7 10.1016/0891-5849(90)90146-A 10.1016/j.minpro.2007.04.007 10.1016/j.ijrmhm.2011.06.008 10.3184/095422904782775090 10.1016/S0304-386X(99)00028-6 10.1016/S1003-6326(17)60273-5 10.1246/bcsj.55.1934 10.1016/j.ijrmhm.2015.05.017 10.1016/j.hydromet.2011.03.004 10.1016/S0162-0134(99)00041-0 10.1016/j.hydromet.2016.03.009 10.1021/jf801465y 10.1016/S1003-6326(11)61120-5 |
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| References | Graf, Eaton (bb0035) 1990; 8 Li, Zhao (bb0060) 2016; 163 Liu, Sun, Zhao (bb0075) 2007; 7 Fang (bb0025) 2001; 16 Zhao, Liang, Liu, Chen, Li (bb0170) 2011; 29 Yang, Xie, Wang, Xu, Wang, Xu (bb0145) 2016; 164 Zhao, Zhai, Liu, Duan (bb0155) 2009; 19 Song, Chen, Zhao, Zhang, He (bb0110) 2016; 47 Ma, Zhang, Qin (bb0080) 2016; 2016 Wu, Zeng (bb0135) 2006 Crea, Crea, De Robertis (bb0015) 2004; 16 Demirkıran, Künkül (bb0020) 2007; 83 Li (bb0055) 1996; 12 Zhao, Cao, Chen (bb0160) 2011; 21 Tsuchida, Narita, Takeuchi, Adachi, Okabe (bb0120) 1982; 55 Wang, Zhao, Li (bb0130) 2005; 33 Iglesia (bb0045) 2009; 65 Levenspiels (bb0050) 1998 Paspaliaris, Tsolakis (bb0100) 1987; 19 Mo (bb0085) 1987 Zhao, Li, Chen, Liu (bb0175) 2013 Cosgrove, Irving (bb0010) 1982 Xu, Li, Meng (bb0140) 1996; 4 Heighton, Schmidt, Siefert (bb0040) 2008; 56 Li, Zhao, Ding (bb0070) 2014; 24 Zhao, Li, Wang, Li, Liu, Sun, Li (bb0165) 2011; 108 Olanipekun (bb0095) 1999; 53 Bebot-Brigaud, Dange, Fauconnier, Gerard (bb0005) 1999; 75 Song, He, Chen, Zhao (bb0115) 2017; 27 Nguyen, Man (bb0090) 2016; 19 Zhang, Li, Zhao (bb0150) 2015; 52 Li, Yang, Li (bb0065) 2010 Feng, Feng, Xu (bb0030) 2006; 31 Payehghadr, Babaei, Saghatforoush, Ashrafi (bb0105) 2009; 3 Mo (10.1016/j.hydromet.2019.04.004_bb0085) 1987 Nguyen (10.1016/j.hydromet.2019.04.004_bb0090) 2016; 19 Zhao (10.1016/j.hydromet.2019.04.004_bb0175) 2013 Ma (10.1016/j.hydromet.2019.04.004_bb0080) 2016; 2016 Feng (10.1016/j.hydromet.2019.04.004_bb0030) 2006; 31 Song (10.1016/j.hydromet.2019.04.004_bb0110) 2016; 47 Zhao (10.1016/j.hydromet.2019.04.004_bb0170) 2011; 29 Zhao (10.1016/j.hydromet.2019.04.004_bb0155) 2009; 19 Li (10.1016/j.hydromet.2019.04.004_bb0065) 2010 Song (10.1016/j.hydromet.2019.04.004_bb0115) 2017; 27 Graf (10.1016/j.hydromet.2019.04.004_bb0035) 1990; 8 Zhao (10.1016/j.hydromet.2019.04.004_bb0160) 2011; 21 Demirkıran (10.1016/j.hydromet.2019.04.004_bb0020) 2007; 83 Iglesia (10.1016/j.hydromet.2019.04.004_bb0045) 2009; 65 Paspaliaris (10.1016/j.hydromet.2019.04.004_bb0100) 1987; 19 Crea (10.1016/j.hydromet.2019.04.004_bb0015) 2004; 16 Liu (10.1016/j.hydromet.2019.04.004_bb0075) 2007; 7 Heighton (10.1016/j.hydromet.2019.04.004_bb0040) 2008; 56 Li (10.1016/j.hydromet.2019.04.004_bb0060) 2016; 163 Fang (10.1016/j.hydromet.2019.04.004_bb0025) 2001; 16 Zhang (10.1016/j.hydromet.2019.04.004_bb0150) 2015; 52 Li (10.1016/j.hydromet.2019.04.004_bb0070) 2014; 24 Xu (10.1016/j.hydromet.2019.04.004_bb0140) 1996; 4 Wang (10.1016/j.hydromet.2019.04.004_bb0130) 2005; 33 Yang (10.1016/j.hydromet.2019.04.004_bb0145) 2016; 164 Bebot-Brigaud (10.1016/j.hydromet.2019.04.004_bb0005) 1999; 75 Olanipekun (10.1016/j.hydromet.2019.04.004_bb0095) 1999; 53 Payehghadr (10.1016/j.hydromet.2019.04.004_bb0105) 2009; 3 Cosgrove (10.1016/j.hydromet.2019.04.004_bb0010) 1982 Wu (10.1016/j.hydromet.2019.04.004_bb0135) 2006 Levenspiels (10.1016/j.hydromet.2019.04.004_bb0050) 1998 Tsuchida (10.1016/j.hydromet.2019.04.004_bb0120) 1982; 55 Zhao (10.1016/j.hydromet.2019.04.004_bb0165) 2011; 108 Li (10.1016/j.hydromet.2019.04.004_bb0055) 1996; 12 |
| References_xml | – volume: 2016 start-page: 35 year: 2016 ident: bb0080 article-title: The leaching kinetics of K-feldspar in sulfuric acid with the aid of ultrasound publication-title: Ultrason. Sonochem. – year: 1982 ident: bb0010 article-title: Inositol Phosphates: Their Chemistry, Biochemistry, and Physiology – volume: 19 start-page: 247 year: 2016 end-page: 259 ident: bb0090 article-title: A review on the separation of molybdenum, tungsten, and vanadium from leach liquors of diverse resources by solvent extraction publication-title: Geosyst. Eng. – volume: 29 start-page: 739 year: 2011 end-page: 742 ident: bb0170 article-title: Sodium hydroxide digestion of scheelite by reactive extrusion publication-title: Int. J. Refract. Metals Hard Mater. – volume: 31 start-page: 63 year: 2006 end-page: 66 ident: bb0030 article-title: Complexation of phytic acid with metal ions publication-title: China Oils Fats. – volume: 108 start-page: 152 year: 2011 end-page: 156 ident: bb0165 article-title: Extracting tungsten from scheelite concentrate with caustic soda by autoclaving process publication-title: Hydrometallurgy – volume: 7 start-page: 108 year: 2007 ident: bb0075 article-title: The latest development of separation of molybdenum from tungsten publication-title: Rare Metals Cement. Carbides – year: 2006 ident: bb0135 article-title: Study on Preparation of Phosphate Magnesium Fertilizer From Flotation Tailings of Low and Medium-Grade Phosphate Rock – volume: 164 start-page: 97 year: 2016 end-page: 102 ident: bb0145 article-title: Extraction and separation of tungsten from acidic high-phosphorus solution publication-title: Hydrometallurgy – volume: 75 start-page: 71 year: 1999 end-page: 78 ident: bb0005 article-title: 31 P NMR, potentiometric and spectrophotometric studies of phytic acid ionization and complexation properties toward Co publication-title: J. Inorg. Biochem. – start-page: 11 year: 2013 end-page: 14 ident: bb0175 article-title: Technology status and development of scheelite metallurgy in China publication-title: Nonferr. Metals Sci. Eng. – volume: 55 start-page: 1934 year: 1982 end-page: 1938 ident: bb0120 article-title: Manufacture of high pure titanium (IV) oxide by the chloride process: I. Kinetic study on leaching of ilmenite ore in concentrated hydrochloric acid solution publication-title: Bull. Chem. Soc. Jpn. – volume: 53 start-page: 1 year: 1999 end-page: 10 ident: bb0095 article-title: A kinetic study of the leaching of a nigerian ilmenite ore by hydrochloric acid publication-title: Hydrometallurgy – volume: 27 start-page: 2492 year: 2017 end-page: 2502 ident: bb0115 article-title: Removal of tungsten from molybdate solution by Fe–Mn binary oxide adsorbent publication-title: Trans. Nonferrous Metals Soc. China – volume: 56 start-page: 9543 year: 2008 end-page: 9547 ident: bb0040 article-title: Kinetic and equilibrium constants of phytic acid and ferric and ferrous phytate derived from nuclear magnetic resonance spectroscopy publication-title: J. Agric. Food Chem. – volume: 47 start-page: 1 year: 2016 end-page: 11 ident: bb0110 article-title: Theoretical basis for the separation of W and Mo with manganese dioxide: a speciation-based approach publication-title: Metal. Mater. Transac. B – volume: 16 start-page: 53 year: 2004 end-page: 59 ident: bb0015 article-title: Speciation of phytate ion in aqueous solution. Characterisation of Ca-phytate sparingly soluble species publication-title: Chem. Spec. Bioavail. – volume: 21 start-page: 2758 year: 2011 end-page: 2763 ident: bb0160 article-title: Separation of macro amounts of tungsten and molybdenum by precipitation with ferrous salt publication-title: Trans. Nonferrous Metals Soc. China – year: 1987 ident: bb0085 article-title: Metallurgical Kinetics – volume: 3 start-page: 92 year: 2009 end-page: 97 ident: bb0105 article-title: Spectrophotometric and conductometric studies of the thermodynamics complexation of Zn publication-title: Afr. J. Pure Appl. Chem. – volume: 19 start-page: 949 year: 2009 end-page: 954 ident: bb0155 article-title: Pre-desilication of laterite in NaOH sub-molten salt system publication-title: Chin. J. Nonferr. Metals – volume: 163 start-page: 55 year: 2016 end-page: 60 ident: bb0060 article-title: Kinetics of scheelite concentrate digestion with sulfuric acid in the presence of phosphoric acid publication-title: Hydrometallurgy – volume: 4 start-page: 41 year: 1996 end-page: 42 ident: bb0140 article-title: Simple method for determination of mineral powder density publication-title: Nonferr. Metals – volume: 12 start-page: 46 year: 1996 end-page: 49 ident: bb0055 article-title: The progress of tungsten concentrates decomposition technique in China and future direction publication-title: China Tungsten Ind. – year: 1998 ident: bb0050 article-title: Chemical Reaction Engineering – volume: 65 start-page: 109 year: 2009 end-page: 119 ident: bb0045 article-title: Estimating the thermodynamic properties of phosphate minerals at high and low temperature from the sum of constituent units publication-title: Estud. Geol. – volume: 16 start-page: 80 year: 2001 end-page: 81 ident: bb0025 article-title: Decomposition of scheelite with NaOH in autoclaving publication-title: China Tungsten Ind. – volume: 19 start-page: 259 year: 1987 end-page: 266 ident: bb0100 article-title: Reaction kinetics for the leaching of iron oxides in diasporic bauxite from the Parnassus–Giona Zone (Greece) by hydrochloric acid publication-title: Hydrometallurgy – volume: 33 start-page: 1 year: 2005 end-page: 4 ident: bb0130 article-title: Thermodynamics analysis on phosphate decomposition of scheelite publication-title: Rare Metals Cement. Carbides – volume: 8 start-page: 61 year: 1990 end-page: 69 ident: bb0035 article-title: Antioxidant functions of phytic acid publication-title: Free Radic. Biol. Med. – volume: 24 start-page: 1607 year: 2014 end-page: 1615 ident: bb0070 article-title: Kinetics of scheelite concentrate leached by sodium phosphate under ultrasound publication-title: Chin. J. Nonferr. Metals – year: 2010 ident: bb0065 article-title: Tungsten Metallurgy – volume: 52 start-page: 78 year: 2015 end-page: 84 ident: bb0150 article-title: Leaching kinetics of scheelite with nitric acid and phosphoric acid publication-title: Int. J. Refract. Metals Hard Mater. – volume: 83 start-page: 76 year: 2007 end-page: 80 ident: bb0020 article-title: Dissolution kinetics of ulexite in perchloric acid solutions publication-title: Int. J. Miner. Process. – volume: 19 start-page: 247 issue: 5 year: 2016 ident: 10.1016/j.hydromet.2019.04.004_bb0090 article-title: A review on the separation of molybdenum, tungsten, and vanadium from leach liquors of diverse resources by solvent extraction publication-title: Geosyst. Eng. doi: 10.1080/12269328.2016.1186577 – volume: 164 start-page: 97 year: 2016 ident: 10.1016/j.hydromet.2019.04.004_bb0145 article-title: Extraction and separation of tungsten from acidic high-phosphorus solution publication-title: Hydrometallurgy doi: 10.1016/j.hydromet.2016.05.018 – volume: 16 start-page: 80 year: 2001 ident: 10.1016/j.hydromet.2019.04.004_bb0025 article-title: Decomposition of scheelite with NaOH in autoclaving publication-title: China Tungsten Ind. – volume: 4 start-page: 41 year: 1996 ident: 10.1016/j.hydromet.2019.04.004_bb0140 article-title: Simple method for determination of mineral powder density publication-title: Nonferr. Metals – start-page: 11 issue: 5 year: 2013 ident: 10.1016/j.hydromet.2019.04.004_bb0175 article-title: Technology status and development of scheelite metallurgy in China publication-title: Nonferr. Metals Sci. Eng. – year: 2010 ident: 10.1016/j.hydromet.2019.04.004_bb0065 – volume: 65 start-page: 109 issue: 2 year: 2009 ident: 10.1016/j.hydromet.2019.04.004_bb0045 article-title: Estimating the thermodynamic properties of phosphate minerals at high and low temperature from the sum of constituent units publication-title: Estud. Geol. doi: 10.3989/egeol.39849.060 – volume: 19 start-page: 259 year: 1987 ident: 10.1016/j.hydromet.2019.04.004_bb0100 article-title: Reaction kinetics for the leaching of iron oxides in diasporic bauxite from the Parnassus–Giona Zone (Greece) by hydrochloric acid publication-title: Hydrometallurgy doi: 10.1016/0304-386X(87)90010-7 – volume: 7 start-page: 108 issue: 1 year: 2007 ident: 10.1016/j.hydromet.2019.04.004_bb0075 article-title: The latest development of separation of molybdenum from tungsten publication-title: Rare Metals Cement. Carbides – volume: 2016 start-page: 35 year: 2016 ident: 10.1016/j.hydromet.2019.04.004_bb0080 article-title: The leaching kinetics of K-feldspar in sulfuric acid with the aid of ultrasound publication-title: Ultrason. Sonochem. – year: 2006 ident: 10.1016/j.hydromet.2019.04.004_bb0135 – volume: 12 start-page: 46 year: 1996 ident: 10.1016/j.hydromet.2019.04.004_bb0055 article-title: The progress of tungsten concentrates decomposition technique in China and future direction publication-title: China Tungsten Ind. – volume: 19 start-page: 949 issue: 5 year: 2009 ident: 10.1016/j.hydromet.2019.04.004_bb0155 article-title: Pre-desilication of laterite in NaOH sub-molten salt system publication-title: Chin. J. Nonferr. Metals – volume: 8 start-page: 61 issue: 1 year: 1990 ident: 10.1016/j.hydromet.2019.04.004_bb0035 article-title: Antioxidant functions of phytic acid publication-title: Free Radic. Biol. Med. doi: 10.1016/0891-5849(90)90146-A – volume: 83 start-page: 76 issue: 1 year: 2007 ident: 10.1016/j.hydromet.2019.04.004_bb0020 article-title: Dissolution kinetics of ulexite in perchloric acid solutions publication-title: Int. J. Miner. Process. doi: 10.1016/j.minpro.2007.04.007 – year: 1987 ident: 10.1016/j.hydromet.2019.04.004_bb0085 – volume: 29 start-page: 739 issue: 6 year: 2011 ident: 10.1016/j.hydromet.2019.04.004_bb0170 article-title: Sodium hydroxide digestion of scheelite by reactive extrusion publication-title: Int. J. Refract. Metals Hard Mater. doi: 10.1016/j.ijrmhm.2011.06.008 – volume: 16 start-page: 53 issue: 1–2 year: 2004 ident: 10.1016/j.hydromet.2019.04.004_bb0015 article-title: Speciation of phytate ion in aqueous solution. Characterisation of Ca-phytate sparingly soluble species publication-title: Chem. Spec. Bioavail. doi: 10.3184/095422904782775090 – volume: 53 start-page: 1 issue: 1 year: 1999 ident: 10.1016/j.hydromet.2019.04.004_bb0095 article-title: A kinetic study of the leaching of a nigerian ilmenite ore by hydrochloric acid publication-title: Hydrometallurgy doi: 10.1016/S0304-386X(99)00028-6 – volume: 31 start-page: 63 issue: 8 year: 2006 ident: 10.1016/j.hydromet.2019.04.004_bb0030 article-title: Complexation of phytic acid with metal ions publication-title: China Oils Fats. – volume: 27 start-page: 2492 issue: 11 year: 2017 ident: 10.1016/j.hydromet.2019.04.004_bb0115 article-title: Removal of tungsten from molybdate solution by Fe–Mn binary oxide adsorbent publication-title: Trans. Nonferrous Metals Soc. China doi: 10.1016/S1003-6326(17)60273-5 – volume: 55 start-page: 1934 issue: 6 year: 1982 ident: 10.1016/j.hydromet.2019.04.004_bb0120 article-title: Manufacture of high pure titanium (IV) oxide by the chloride process: I. Kinetic study on leaching of ilmenite ore in concentrated hydrochloric acid solution publication-title: Bull. Chem. Soc. Jpn. doi: 10.1246/bcsj.55.1934 – volume: 52 start-page: 78 year: 2015 ident: 10.1016/j.hydromet.2019.04.004_bb0150 article-title: Leaching kinetics of scheelite with nitric acid and phosphoric acid publication-title: Int. J. Refract. Metals Hard Mater. doi: 10.1016/j.ijrmhm.2015.05.017 – volume: 33 start-page: 1 issue: 1 year: 2005 ident: 10.1016/j.hydromet.2019.04.004_bb0130 article-title: Thermodynamics analysis on phosphate decomposition of scheelite publication-title: Rare Metals Cement. Carbides – volume: 108 start-page: 152 issue: 1 year: 2011 ident: 10.1016/j.hydromet.2019.04.004_bb0165 article-title: Extracting tungsten from scheelite concentrate with caustic soda by autoclaving process publication-title: Hydrometallurgy doi: 10.1016/j.hydromet.2011.03.004 – volume: 75 start-page: 71 issue: 1 year: 1999 ident: 10.1016/j.hydromet.2019.04.004_bb0005 article-title: 31 P NMR, potentiometric and spectrophotometric studies of phytic acid ionization and complexation properties toward Co2+, Ni2+, Cu2+, Zn2+ and Cd2+ publication-title: J. Inorg. Biochem. doi: 10.1016/S0162-0134(99)00041-0 – volume: 3 start-page: 92 issue: 5 year: 2009 ident: 10.1016/j.hydromet.2019.04.004_bb0105 article-title: Spectrophotometric and conductometric studies of the thermodynamics complexation of Zn2+, Cu2+, Co2+, Ni2+ and Cd2+ ions with a new schiff base ligand in acetonitrile solution publication-title: Afr. J. Pure Appl. Chem. – year: 1998 ident: 10.1016/j.hydromet.2019.04.004_bb0050 – volume: 163 start-page: 55 year: 2016 ident: 10.1016/j.hydromet.2019.04.004_bb0060 article-title: Kinetics of scheelite concentrate digestion with sulfuric acid in the presence of phosphoric acid publication-title: Hydrometallurgy doi: 10.1016/j.hydromet.2016.03.009 – year: 1982 ident: 10.1016/j.hydromet.2019.04.004_bb0010 – volume: 47 start-page: 1 issue: 1 year: 2016 ident: 10.1016/j.hydromet.2019.04.004_bb0110 article-title: Theoretical basis for the separation of W and Mo with manganese dioxide: a speciation-based approach publication-title: Metal. Mater. Transac. B – volume: 24 start-page: 1607 issue: 6 year: 2014 ident: 10.1016/j.hydromet.2019.04.004_bb0070 article-title: Kinetics of scheelite concentrate leached by sodium phosphate under ultrasound publication-title: Chin. J. Nonferr. Metals – volume: 56 start-page: 9543 issue: 20 year: 2008 ident: 10.1016/j.hydromet.2019.04.004_bb0040 article-title: Kinetic and equilibrium constants of phytic acid and ferric and ferrous phytate derived from nuclear magnetic resonance spectroscopy publication-title: J. Agric. Food Chem. doi: 10.1021/jf801465y – volume: 21 start-page: 2758 issue: 12 year: 2011 ident: 10.1016/j.hydromet.2019.04.004_bb0160 article-title: Separation of macro amounts of tungsten and molybdenum by precipitation with ferrous salt publication-title: Trans. Nonferrous Metals Soc. China doi: 10.1016/S1003-6326(11)61120-5 |
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| Title | Leaching kinetics of scheelite with sodium phytate |
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