Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties
The reactions of [M III (CN) 6 ] 3− (M = Cr or Co) with Cu II complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac] 2 (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [Cu 4 (aemp) 4 (H 2 O) 2 ][Cr(CN) 6 ]Cl ( 1 ) and [Cu 3...
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| Published in | Transition metal chemistry (Weinheim) Vol. 39; no. 4; pp. 387 - 392 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cham
Springer International Publishing
01.05.2014
Springer Nature B.V |
| Subjects | |
| Online Access | Get full text |
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| Abstract | The reactions of [M
III
(CN)
6
]
3−
(M = Cr or Co) with Cu
II
complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]
2
(Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [Cu
4
(aemp)
4
(H
2
O)
2
][Cr(CN)
6
]Cl (
1
) and [Cu
3
(aemp)
3
(H
2
O)][Co(CN)
6
]·2H
2
O·MeOH (
2
). In complex
1
, the six cyanide ligands of the [Cr(CN)
6
]
3−
moiety are involved in bridging, while in complex
2
only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex
1
exhibits intermetallic ferromagnetic coupling, with
J
= 8.2 cm
−1
. |
|---|---|
| AbstractList | The reactions of [M
III
(CN)
6
]
3−
(M = Cr or Co) with Cu
II
complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]
2
(Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [Cu
4
(aemp)
4
(H
2
O)
2
][Cr(CN)
6
]Cl (
1
) and [Cu
3
(aemp)
3
(H
2
O)][Co(CN)
6
]·2H
2
O·MeOH (
2
). In complex
1
, the six cyanide ligands of the [Cr(CN)
6
]
3−
moiety are involved in bridging, while in complex
2
only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex
1
exhibits intermetallic ferromagnetic coupling, with
J
= 8.2 cm
−1
. The reactions of [M super(III)(CN) sub(6)] super(3-) (M = Cr or Co) with Cu super(II) complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac] sub(2) (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [Cu sub(4)(aemp) sub(4)(H sub(2)O) sub(2)][Cr(CN) sub(6)]Cl (1) and [Cu sub(3)(aemp) sub(3)(H sub(2)O)][Co(CN) sub(6)].2H sub(2)O.MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN) sub(6)] super(3-) moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 cm super(-1). The reactions of [M^sup III^(CN)^sub 6^]^sup 3-^ (M = Cr or Co) with Cu^sup II^ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]^sub 2^ (Haemp = 2-[(2-amino-ethylimino)-methyl]-phenol) give rise to 1D cyanide-bridged bimetallic coordination polymers [Cu^sub 4^(aemp)^sub 4^(H2O)^sub 2^][Cr(CN)^sub 6^]Cl (1) and [Cu^sub 3^(aemp)^sub 3^(H2O)][Co(CN)^sub 6^]·2H2O·MeOH (2). In complex 1, the six cyanide ligands of the [Cr(CN)^sub 6^]^sup 3-^ moiety are involved in bridging, while in complex 2 only five cyanide ligands act as bridges to give a neutral chain. Magnetic studies reveal that complex 1 exhibits intermetallic ferromagnetic coupling, with J = 8.2 cm^sup -1^.[PUBLICATION ABSTRACT] |
| Author | Kou, Hui-Zhong Zhao, Chong-Chao Cui, Ai-Li Li, Shu-Tao |
| Author_xml | – sequence: 1 givenname: Shu-Tao surname: Li fullname: Li, Shu-Tao organization: Department of Chemistry, Tsinghua University – sequence: 2 givenname: Chong-Chao surname: Zhao fullname: Zhao, Chong-Chao organization: Department of Chemistry, Tsinghua University – sequence: 3 givenname: Ai-Li surname: Cui fullname: Cui, Ai-Li organization: Department of Chemistry, Tsinghua University – sequence: 4 givenname: Hui-Zhong surname: Kou fullname: Kou, Hui-Zhong email: kouhz@mail.tsinghua.edu.cn organization: Department of Chemistry, Tsinghua University |
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| Cites_doi | 10.1021/ja00104a046 10.1021/ic034028y 10.1002/ejic.200300500 10.1021/ic702234y 10.1021/cg050186j 10.1016/S0277-5387(99)00218-1 10.1039/b211276k 10.1021/ic049857d 10.1039/c2dt31675g 10.1039/dt9840002839 10.1002/chem.200500365 10.1021/ic960481g 10.1021/ic102179n 10.1021/ja01975a003 10.1002/anie.200390099 10.1021/ja016656p 10.1002/chem.200390192 10.1039/b201312f 10.1007/430_032 10.1021/ar040158e 10.1002/ejic.201200480 10.1039/B401557F 10.1039/b605521d 10.1039/b008314n 10.1021/ic2011875 |
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| Keywords | Ferromagnetic Coupling Cyanide Ligand Tridentate Ligand Magnetic Coupling Magnetic Susceptibility Measurement |
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| Snippet | The reactions of [M
III
(CN)
6
]
3−
(M = Cr or Co) with Cu
II
complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]
2... The reactions of [M^sup III^(CN)^sub 6^]^sup 3-^ (M = Cr or Co) with Cu^sup II^ complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac]^sub 2^... The reactions of [M super(III)(CN) sub(6)] super(3-) (M = Cr or Co) with Cu super(II) complexes of a tridentate schiff base [Cu(aemp)Cl] or [Cu(aemp)Ac] sub(2)... |
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| SubjectTerms | Bimetals Bridges (structures) Catalysis Chemistry Chemistry and Materials Science Coordination polymers Crystal structure Cyanides Ferromagnetism Inorganic Chemistry Ligands Magnetic properties Organometallic Chemistry Physical Chemistry |
| Title | Cyanide-bridged one-dimensional bimetallic complexes based on a tridentate copper(II) building block: synthesis, crystal structures and magnetic properties |
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