Palladacycles as Precatalysts in Heck and Cross-Coupling Reactions

A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate under mild conditions with n‐butyl acrylate and vinyltributylstannane, respectively. This palladacycle acts as an active (pre)catalyst for cr...

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Published inAdvanced synthesis & catalysis Vol. 343; no. 4; pp. 338 - 342
Main Authors Paz Muñoz, M., Martín-Matute, Belén, Fernández-Rivas, Carolina, Cárdenas, Diego J., Echavarren, Antonio M.
Format Journal Article
LanguageEnglish
Published Weinheim Wiley-VCH Verlag GmbH 30.04.2001
Wiley‐VCH Verlag GmbH
Wiley
Subjects
Chemistry
Chemistry, Applied
Chemistry, Organic
cross-coupling
Heck reaction
homogeneous catalysis
metallacycles
P ligands
palladium
Physical Sciences
Science & Technology
HIGHLY-ACTIVE CATALYST
Heck reaction
N-HETEROCYCLIC CARBENES
OXIDATIVE ADDITION
ARYLBORONIC ACIDS
EFFICIENT CATALYSTS
GENERAL-METHOD
SULFUR-CONTAINING PALLADACYCLES
homogeneous catalysis
PALLADIUM-CATALYZED REACTIONS
cross-coupling
ALIPHATIC PALLADATION
palladium
P ligands
ARYL CHLORIDES
metallacycles
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Abstract A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate under mild conditions with n‐butyl acrylate and vinyltributylstannane, respectively. This palladacycle acts as an active (pre)catalyst for cross‐coupling and Heck reactions.
AbstractList A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate under mild conditions with n‐butyl acrylate and vinyltributylstannane, respectively. This palladacycle acts as an active (pre)catalyst for cross‐coupling and Heck reactions.
Author Cárdenas, Diego J.
Echavarren, Antonio M.
Fernández-Rivas, Carolina
Martín-Matute, Belén
Paz Muñoz, M.
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Cites_doi 10.1021/cr9903048
10.1021/ja001708g
10.1021/ol0058644
10.1021/ol0063048
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Issue 4
Keywords HIGHLY-ACTIVE CATALYST
Heck reaction
N-HETEROCYCLIC CARBENES
OXIDATIVE ADDITION
ARYLBORONIC ACIDS
EFFICIENT CATALYSTS
GENERAL-METHOD
SULFUR-CONTAINING PALLADACYCLES
homogeneous catalysis
PALLADIUM-CATALYZED REACTIONS
cross-coupling
ALIPHATIC PALLADATION
palladium
P ligands
ARYL CHLORIDES
metallacycles
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SSID ssj0017877
Score 1.9023604
Snippet A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies. The new oxapalladacycle 1 was shown to insert and transmetalate...
A variety of palladacycles are shown to catalyze Heck alkenylations with similar efficiencies, The new oxapalladacycle 1 was shown to insert and transmetalate...
Source Web of Science
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webofscience
wiley
istex
SourceType Aggregation Database
Enrichment Source
Index Database
Publisher
StartPage 338
SubjectTerms Chemistry
Chemistry, Applied
Chemistry, Organic
cross-coupling
Heck reaction
homogeneous catalysis
metallacycles
P ligands
palladium
Physical Sciences
Science & Technology
Title Palladacycles as Precatalysts in Heck and Cross-Coupling Reactions
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https://onlinelibrary.wiley.com/doi/abs/10.1002%2F1615-4169%2820010226%29343%3A4%3C338%3A%3AAID-ADSC338%3E3.0.CO%3B2-I
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