A single-step, electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots
Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [av...
Saved in:
Published in | Chemical communications (Cambridge, England) Vol. 54; no. 83; pp. 11733 - 11736 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
England
Royal Society of Chemistry
25.10.2018
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm (
N
= 50)] obtained in this work exhibit
ca.
88.7% quantum efficiency. |
---|---|
AbstractList | Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm (N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency.Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm (N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency. Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm ( N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency. Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm (N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency. |
Author | Alwarappan, Subbiah Pillai, Vijayamohanan K. Ozhukil Valappil, Manila Ahlawat, Monika |
Author_xml | – sequence: 1 givenname: Manila orcidid: 0000-0003-0973-2091 surname: Ozhukil Valappil fullname: Ozhukil Valappil, Manila organization: CSIR-Central Electrochemical Research Institute, Karaikudi, India, Academy of Scientific and Innovative Research (AcSIR), CSIR-Human Resource Development Centre – sequence: 2 givenname: Monika surname: Ahlawat fullname: Ahlawat, Monika organization: School of Basic Sciences, Indian Institute of Technology, Mandi, India – sequence: 3 givenname: Vijayamohanan K. orcidid: 0000-0003-4839-4531 surname: Pillai fullname: Pillai, Vijayamohanan K. organization: CSIR-Central Electrochemical Research Institute, Karaikudi, India, Academy of Scientific and Innovative Research (AcSIR), CSIR-Human Resource Development Centre – sequence: 4 givenname: Subbiah orcidid: 0000-0001-9559-8989 surname: Alwarappan fullname: Alwarappan, Subbiah organization: CSIR-Central Electrochemical Research Institute, Karaikudi, India, Academy of Scientific and Innovative Research (AcSIR), CSIR-Human Resource Development Centre |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30276374$$D View this record in MEDLINE/PubMed |
BookMark | eNqF0U1rFjEQAOAgFfuhF3-ABLxIcTXJ5mNzLItWoeBFwduSZGf7pmSTbZI99N-b0hahCA6ECeSZIcmcoqOYIiD0lpJPlPT68ziMI1FMyvEFOqG95J3gw--j-73Qneq5OEanpdyQFlQMr9BxT5iSveInaL7AxcfrAF2psH3EEMDVnNwBVu9MwOUu1gMUX3BacPTt6BointMGM7ZhBxz21UcoDmLF2yGVtjJEwLe7iXVfG63lNXq5mFDgzWM-Q7--fvk5fuuuflx-Hy-uOtfzoXaWOuvkIjThVg_OSk0EdSA0l8YqqpXgrAfl5mWWxFollXXA5OzkDIQZ15-hDw99t5xudyh1Wn27WQgmQtrLxBijhCsx6P9TSoXiWirS6Ptn9CbtObaHNMUIlQOnvKl3j2q3K8zTlv1q8t309NUNkAfgciolwzI5X031KdZsfJgome6nOf2dZis5f1by1PUf-A_0r59A |
CitedBy_id | crossref_primary_10_1063_5_0219794 crossref_primary_10_1002_smsc_202200040 crossref_primary_10_1109_JSEN_2020_3046675 crossref_primary_10_1021_acs_jpclett_8b03600 crossref_primary_10_1039_D1TA02027G crossref_primary_10_1002_advs_201902359 crossref_primary_10_1016_j_cej_2022_138872 crossref_primary_10_1088_2053_1591_ab6c09 crossref_primary_10_1039_D0RA10829D crossref_primary_10_1002_adfm_202105190 crossref_primary_10_1088_1361_6463_acf0ce crossref_primary_10_3390_ijms23020733 crossref_primary_10_1021_acs_langmuir_4c00128 crossref_primary_10_1039_D1NR07340K crossref_primary_10_1002_inf2_12365 crossref_primary_10_1016_j_apsusc_2021_150450 crossref_primary_10_1088_1402_4896_abe06a crossref_primary_10_1002_cjoc_202000330 crossref_primary_10_1016_j_nantod_2021_101183 crossref_primary_10_1016_j_est_2023_108799 crossref_primary_10_1039_D1CS00847A crossref_primary_10_1016_j_cej_2024_153916 crossref_primary_10_1016_j_commatsci_2024_113020 crossref_primary_10_1016_j_jclepro_2022_135541 |
Cites_doi | 10.1002/anie.201409400 10.1021/acsami.7b02900 10.1021/am509056b 10.1021/acsomega.7b01058 10.1039/C6NR04773D 10.3390/ma10020210 10.1002/anie.201506154 10.1103/PhysRevLett.112.176801 10.1073/pnas.1602215113 10.1002/smll.201602896 10.1021/acsnano.5b01143 10.1002/chem.201701277 10.1039/C4CC09826A 10.1002/adma.201605776 10.1038/srep42357 10.1038/srep27307 10.1002/chem.201201043 10.1039/C4CC05752J 10.1016/j.elecom.2018.02.010 10.1002/adma.201405150 10.1021/nn501226z 10.1038/nnano.2014.35 10.1039/C5TA03869C 10.1039/C8CS00387D 10.1038/ncomms9563 10.1002/anie.201705071 10.1021/acs.chemmater.8b00521 |
ContentType | Journal Article |
Copyright | Copyright Royal Society of Chemistry 2018 |
Copyright_xml | – notice: Copyright Royal Society of Chemistry 2018 |
DBID | AAYXX CITATION NPM 7SR 7U5 8BQ 8FD JG9 L7M 7X8 7S9 L.6 |
DOI | 10.1039/C8CC07266C |
DatabaseName | CrossRef PubMed Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace MEDLINE - Academic AGRICOLA AGRICOLA - Academic |
DatabaseTitle | CrossRef PubMed Materials Research Database Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace METADEX MEDLINE - Academic AGRICOLA AGRICOLA - Academic |
DatabaseTitleList | MEDLINE - Academic CrossRef AGRICOLA PubMed Materials Research Database |
Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1364-548X |
EndPage | 11736 |
ExternalDocumentID | 30276374 10_1039_C8CC07266C |
Genre | Journal Article |
GroupedDBID | --- -DZ -~X 0-7 0R~ 29B 2WC 4.4 53G 5GY 6J9 705 70~ 7~J AAEMU AAHBH AAIWI AAJAE AAMEH AANOJ AAWGC AAXHV AAXPP AAYXX ABASK ABDVN ABEMK ABJNI ABPDG ABRYZ ABXOH ACBEA ACGFO ACGFS ACIWK ACLDK ACNCT ADMRA ADSRN AEFDR AENEX AENGV AESAV AETIL AFLYV AFOGI AFRDS AFRZK AFVBQ AGEGJ AGKEF AGRSR AHGCF AKMSF ALMA_UNASSIGNED_HOLDINGS ALUYA ANUXI APEMP ASKNT AUDPV AZFZN BLAPV BSQNT C6K CITATION CS3 DU5 EBS ECGLT EE0 EF- EJD F5P GGIMP GNO H13 HZ~ H~N IDZ IH2 J3I M4U N9A O9- P2P R56 R7B R7C R7D RAOCF RCNCU RPMJG RRA RRC RSCEA SJN SKA SKF SKH SLH TN5 TWZ UPT VH6 WH7 X7L -JG AGSTE NPM VQA 7SR 7U5 8BQ 8FD JG9 L7M 7X8 7S9 L.6 |
ID | FETCH-LOGICAL-c348t-b1cbc6f5904b98cb69051ce5946ab71975423e7cdfd60bb767bce26dc6de02ac3 |
ISSN | 1359-7345 1364-548X |
IngestDate | Thu Jul 10 23:20:58 EDT 2025 Fri Jul 11 09:55:53 EDT 2025 Sun Jun 29 15:23:02 EDT 2025 Wed Feb 19 02:43:28 EST 2025 Tue Jul 01 01:14:19 EDT 2025 Thu Apr 24 23:08:10 EDT 2025 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 83 |
Language | English |
LinkModel | OpenURL |
MergedId | FETCHMERGED-LOGICAL-c348t-b1cbc6f5904b98cb69051ce5946ab71975423e7cdfd60bb767bce26dc6de02ac3 |
Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
ORCID | 0000-0001-9559-8989 0000-0003-0973-2091 0000-0003-4839-4531 |
PMID | 30276374 |
PQID | 2120168414 |
PQPubID | 2047502 |
PageCount | 4 |
ParticipantIDs | proquest_miscellaneous_2221047589 proquest_miscellaneous_2115749670 proquest_journals_2120168414 pubmed_primary_30276374 crossref_citationtrail_10_1039_C8CC07266C crossref_primary_10_1039_C8CC07266C |
ProviderPackageCode | CITATION AAYXX |
PublicationCentury | 2000 |
PublicationDate | 2018-10-25 |
PublicationDateYYYYMMDD | 2018-10-25 |
PublicationDate_xml | – month: 10 year: 2018 text: 2018-10-25 day: 25 |
PublicationDecade | 2010 |
PublicationPlace | England |
PublicationPlace_xml | – name: England – name: Cambridge |
PublicationTitle | Chemical communications (Cambridge, England) |
PublicationTitleAlternate | Chem Commun (Camb) |
PublicationYear | 2018 |
Publisher | Royal Society of Chemistry |
Publisher_xml | – name: Royal Society of Chemistry |
References | Gui (C8CC07266C-(cit11)/*[position()=1]) 2018; 47 Hanlon (C8CC07266C-(cit13)/*[position()=1]) 2015; 6 Zhang (C8CC07266C-(cit5)/*[position()=1]) 2015; 54 Zhu (C8CC07266C-(cit27)/*[position()=1]) 2017; 29 Shinde (C8CC07266C-(cit15)/*[position()=1]) 2012; 18 Ambrosi (C8CC07266C-(cit19)/*[position()=1]) 2017; 56 Lee (C8CC07266C-(cit26)/*[position()=1]) 2017; 2 Du (C8CC07266C-(cit9)/*[position()=1]) 2017; 7 Sun (C8CC07266C-(cit6)/*[position()=1]) 2015; 54 Ge (C8CC07266C-(cit25)/*[position()=1]) 2016; 6 Yasaei (C8CC07266C-(cit23)/*[position()=1]) 2015; 27 Li (C8CC07266C-(cit21)/*[position()=1]) 2018; 30 Sun (C8CC07266C-(cit10)/*[position()=1]) 2017; 13 Valappil (C8CC07266C-(cit18)/*[position()=1]) 2017; 23 Xiao (C8CC07266C-(cit20)/*[position()=1]) 2018; 89 Li (C8CC07266C-(cit2)/*[position()=1]) 2014; 9 Rodin (C8CC07266C-(cit1)/*[position()=1]) 2014; 112 Late (C8CC07266C-(cit24)/*[position()=1]) 2015; 7 Mu (C8CC07266C-(cit7)/*[position()=1]) 2017; 9 Liu (C8CC07266C-(cit3)/*[position()=1]) 2014; 8 Gao (C8CC07266C-(cit22)/*[position()=1]) 2016; 8 Kang (C8CC07266C-(cit14)/*[position()=1]) 2016; 113 Gopalakrishnan (C8CC07266C-(cit17)/*[position()=1]) 2015; 51 Kang (C8CC07266C-(cit4)/*[position()=1]) 2015; 9 Jaison (C8CC07266C-(cit16)/*[position()=1]) 2015; 3 Brent (C8CC07266C-(cit12)/*[position()=1]) 2014; 50 Jiang (C8CC07266C-(cit8)/*[position()=1]) 2017; 10 |
References_xml | – volume: 54 start-page: 3653 year: 2015 ident: C8CC07266C-(cit5)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201409400 – volume: 9 start-page: 20399 year: 2017 ident: C8CC07266C-(cit7)/*[position()=1] publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.7b02900 – volume: 7 start-page: 5857 year: 2015 ident: C8CC07266C-(cit24)/*[position()=1] publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/am509056b – volume: 2 start-page: 7096 year: 2017 ident: C8CC07266C-(cit26)/*[position()=1] publication-title: ACS Omega doi: 10.1021/acsomega.7b01058 – volume: 8 start-page: 15132 year: 2016 ident: C8CC07266C-(cit22)/*[position()=1] publication-title: Nanoscale doi: 10.1039/C6NR04773D – volume: 10 start-page: 210 year: 2017 ident: C8CC07266C-(cit8)/*[position()=1] publication-title: Materials doi: 10.3390/ma10020210 – volume: 54 start-page: 11526 year: 2015 ident: C8CC07266C-(cit6)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201506154 – volume: 112 start-page: 1 year: 2014 ident: C8CC07266C-(cit1)/*[position()=1] publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.112.176801 – volume: 113 start-page: 11688 year: 2016 ident: C8CC07266C-(cit14)/*[position()=1] publication-title: Proc. Natl. Acad. Sci. U. S. A. doi: 10.1073/pnas.1602215113 – volume: 13 start-page: 1602896 year: 2017 ident: C8CC07266C-(cit10)/*[position()=1] publication-title: Small doi: 10.1002/smll.201602896 – volume: 9 start-page: 3596 year: 2015 ident: C8CC07266C-(cit4)/*[position()=1] publication-title: ACS Nano doi: 10.1021/acsnano.5b01143 – volume: 23 start-page: 9144 year: 2017 ident: C8CC07266C-(cit18)/*[position()=1] publication-title: Chem. – Eur. J. doi: 10.1002/chem.201701277 – volume: 51 start-page: 6293 year: 2015 ident: C8CC07266C-(cit17)/*[position()=1] publication-title: Chem. Commun. doi: 10.1039/C4CC09826A – volume: 29 start-page: 1605776 year: 2017 ident: C8CC07266C-(cit27)/*[position()=1] publication-title: Adv. Mater. doi: 10.1002/adma.201605776 – volume: 7 start-page: 42357 year: 2017 ident: C8CC07266C-(cit9)/*[position()=1] publication-title: Sci. Rep. doi: 10.1038/srep42357 – volume: 6 start-page: 27307 year: 2016 ident: C8CC07266C-(cit25)/*[position()=1] publication-title: Sci. Rep. doi: 10.1038/srep27307 – volume: 18 start-page: 12522 year: 2012 ident: C8CC07266C-(cit15)/*[position()=1] publication-title: Chem. – Eur. J. doi: 10.1002/chem.201201043 – volume: 50 start-page: 13338 year: 2014 ident: C8CC07266C-(cit12)/*[position()=1] publication-title: Chem. Commun. doi: 10.1039/C4CC05752J – volume: 89 start-page: 10 year: 2018 ident: C8CC07266C-(cit20)/*[position()=1] publication-title: Electrochem. Commun. doi: 10.1016/j.elecom.2018.02.010 – volume: 27 start-page: 1887 year: 2015 ident: C8CC07266C-(cit23)/*[position()=1] publication-title: Adv. Mater. doi: 10.1002/adma.201405150 – volume: 8 start-page: 4033 year: 2014 ident: C8CC07266C-(cit3)/*[position()=1] publication-title: ACS Nano doi: 10.1021/nn501226z – volume: 9 start-page: 372 year: 2014 ident: C8CC07266C-(cit2)/*[position()=1] publication-title: Nat. Nanotechnol. doi: 10.1038/nnano.2014.35 – volume: 3 start-page: 18222 year: 2015 ident: C8CC07266C-(cit16)/*[position()=1] publication-title: J. Mater. Chem. A doi: 10.1039/C5TA03869C – volume: 47 start-page: 6795 year: 2018 ident: C8CC07266C-(cit11)/*[position()=1] publication-title: Chem. Soc. Rev. doi: 10.1039/C8CS00387D – volume: 6 start-page: 8563 year: 2015 ident: C8CC07266C-(cit13)/*[position()=1] publication-title: Nat. Commun. doi: 10.1038/ncomms9563 – volume: 56 start-page: 10443 year: 2017 ident: C8CC07266C-(cit19)/*[position()=1] publication-title: Angew. Chem., Int. Ed. doi: 10.1002/anie.201705071 – volume: 30 start-page: 2742 year: 2018 ident: C8CC07266C-(cit21)/*[position()=1] publication-title: Chem. Mater. doi: 10.1021/acs.chemmater.8b00521 |
SSID | ssj0000158 |
Score | 2.4001262 |
Snippet | Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black... |
SourceID | proquest pubmed crossref |
SourceType | Aggregation Database Index Database Enrichment Source |
StartPage | 11733 |
SubjectTerms | ambient temperature chemical compounds chemical reactions Chemical synthesis electrolytes electrosynthesis luminescence Nitrogen Phosphorene phosphorus Quantum dots Quantum efficiency solvents |
Title | A single-step, electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots |
URI | https://www.ncbi.nlm.nih.gov/pubmed/30276374 https://www.proquest.com/docview/2120168414 https://www.proquest.com/docview/2115749670 https://www.proquest.com/docview/2221047589 |
Volume | 54 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3db9MwELfK9gAviG8KAxnBCyopSezYyWNVDY2PIR66qW-V7ThqWZZUbaNp-_v4wzgnjhtGQYOHRm1iW27ul_Odc_c7hN4QromKfe0xHXKPZpR6MkuZF2sWxKlMA1-YROHjr-zohH6aRtNe70cnaqnayKG62plX8j9ShXMgV5Ml-w-SdYPCCfgO8oUjSBiON5LxaGA8_Vx7IKq6zpwtaqNaFoD1ZQEGnuUcgYd3VcJYg7RcGrszr_QAVJOJezchmoPlvFzDx3BcmlxLWIzOoWnD9OTIDNqRVTexpN65ddlftXptaoN0d3Gv5tXZIh-cilwsl83O87EoFrlbF0bzXFyIJnwENM2Zu_DNVEaqow5OF9_FpTgv56IAvfR56LrmF2IFw9rd3ErKhd3nthsaQc0u2yQ_Wx1MosTjpGGZHGp7jlEPnKtpV3E37NMWoDHpqOEg4A29hl3TzW-2c8HwieFbHcfjsc_BVhlvl8U2FODaauliGOu39ySZbfveQvshOCugbfdHh5OPXzo0ZnWdWPfHWppckrzf9v7VMPqDt1NbPZN76K51V_Cowd591NPFA3R73FYJfIjSEe5g8B2-hkDsEIjLDLcIxDUCsUEg7iAQdxCILQKxQeAjdPLhcDI-8mzlDk8RGm88GSipWBYlPpVJrCQzLHAm4Y8yIXmQmLLLRHOVglrwpeSMS6VDliqWaj8UijxGe0VZ6KcIg4cAV7WMKSiSlEUy5Vko41CQTItIJH30tr1tM2Vp7U11lXz2u4D66LVru2zIXHa2Omjv_sw-7OsZWHjgHMU0oH30yl2Ge23er4lCl5VpE0ScJoz7f2kThoYcJYph4k8aybqpmBACRjh9dqNpPkd3tk_PAdrbrCr9AgzkjXxp8fcTmji_iw |
linkProvider | Royal Society of Chemistry |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=A+single-step%2C+electrochemical+synthesis+of+nitrogen+doped+blue+luminescent+phosphorene+quantum+dots&rft.jtitle=Chemical+communications+%28Cambridge%2C+England%29&rft.au=Ozhukil+Valappil%2C+Manila&rft.au=Ahlawat%2C+Monika&rft.au=Pillai%2C+Vijayamohanan+K.&rft.au=Alwarappan%2C+Subbiah&rft.date=2018-10-25&rft.issn=1359-7345&rft.eissn=1364-548X&rft.volume=54&rft.issue=83&rft.spage=11733&rft.epage=11736&rft_id=info:doi/10.1039%2FC8CC07266C&rft.externalDBID=n%2Fa&rft.externalDocID=10_1039_C8CC07266C |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1359-7345&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1359-7345&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1359-7345&client=summon |