A single-step, electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots

Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [av...

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Published inChemical communications (Cambridge, England) Vol. 54; no. 83; pp. 11733 - 11736
Main Authors Ozhukil Valappil, Manila, Ahlawat, Monika, Pillai, Vijayamohanan K., Alwarappan, Subbiah
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 25.10.2018
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Abstract Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm ( N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency.
AbstractList Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm (N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency.Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm (N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency.
Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm ( N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency.
Herein, we report a one-step strategy for the electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots (NPQDs) from black phosphorus at room temperature. Nitrogen percentage in NPQDs can be varied by the appropriate choice of solvent and supporting electrolyte. NPQDs [average size 6 ± 1.5 nm (N = 50)] obtained in this work exhibit ca. 88.7% quantum efficiency.
Author Alwarappan, Subbiah
Pillai, Vijayamohanan K.
Ozhukil Valappil, Manila
Ahlawat, Monika
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Cites_doi 10.1002/anie.201409400
10.1021/acsami.7b02900
10.1021/am509056b
10.1021/acsomega.7b01058
10.1039/C6NR04773D
10.3390/ma10020210
10.1002/anie.201506154
10.1103/PhysRevLett.112.176801
10.1073/pnas.1602215113
10.1002/smll.201602896
10.1021/acsnano.5b01143
10.1002/chem.201701277
10.1039/C4CC09826A
10.1002/adma.201605776
10.1038/srep42357
10.1038/srep27307
10.1002/chem.201201043
10.1039/C4CC05752J
10.1016/j.elecom.2018.02.010
10.1002/adma.201405150
10.1021/nn501226z
10.1038/nnano.2014.35
10.1039/C5TA03869C
10.1039/C8CS00387D
10.1038/ncomms9563
10.1002/anie.201705071
10.1021/acs.chemmater.8b00521
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References Gui (C8CC07266C-(cit11)/*[position()=1]) 2018; 47
Hanlon (C8CC07266C-(cit13)/*[position()=1]) 2015; 6
Zhang (C8CC07266C-(cit5)/*[position()=1]) 2015; 54
Zhu (C8CC07266C-(cit27)/*[position()=1]) 2017; 29
Shinde (C8CC07266C-(cit15)/*[position()=1]) 2012; 18
Ambrosi (C8CC07266C-(cit19)/*[position()=1]) 2017; 56
Lee (C8CC07266C-(cit26)/*[position()=1]) 2017; 2
Du (C8CC07266C-(cit9)/*[position()=1]) 2017; 7
Sun (C8CC07266C-(cit6)/*[position()=1]) 2015; 54
Ge (C8CC07266C-(cit25)/*[position()=1]) 2016; 6
Yasaei (C8CC07266C-(cit23)/*[position()=1]) 2015; 27
Li (C8CC07266C-(cit21)/*[position()=1]) 2018; 30
Sun (C8CC07266C-(cit10)/*[position()=1]) 2017; 13
Valappil (C8CC07266C-(cit18)/*[position()=1]) 2017; 23
Xiao (C8CC07266C-(cit20)/*[position()=1]) 2018; 89
Li (C8CC07266C-(cit2)/*[position()=1]) 2014; 9
Rodin (C8CC07266C-(cit1)/*[position()=1]) 2014; 112
Late (C8CC07266C-(cit24)/*[position()=1]) 2015; 7
Mu (C8CC07266C-(cit7)/*[position()=1]) 2017; 9
Liu (C8CC07266C-(cit3)/*[position()=1]) 2014; 8
Gao (C8CC07266C-(cit22)/*[position()=1]) 2016; 8
Kang (C8CC07266C-(cit14)/*[position()=1]) 2016; 113
Gopalakrishnan (C8CC07266C-(cit17)/*[position()=1]) 2015; 51
Kang (C8CC07266C-(cit4)/*[position()=1]) 2015; 9
Jaison (C8CC07266C-(cit16)/*[position()=1]) 2015; 3
Brent (C8CC07266C-(cit12)/*[position()=1]) 2014; 50
Jiang (C8CC07266C-(cit8)/*[position()=1]) 2017; 10
References_xml – volume: 54
  start-page: 3653
  year: 2015
  ident: C8CC07266C-(cit5)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201409400
– volume: 9
  start-page: 20399
  year: 2017
  ident: C8CC07266C-(cit7)/*[position()=1]
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/acsami.7b02900
– volume: 7
  start-page: 5857
  year: 2015
  ident: C8CC07266C-(cit24)/*[position()=1]
  publication-title: ACS Appl. Mater. Interfaces
  doi: 10.1021/am509056b
– volume: 2
  start-page: 7096
  year: 2017
  ident: C8CC07266C-(cit26)/*[position()=1]
  publication-title: ACS Omega
  doi: 10.1021/acsomega.7b01058
– volume: 8
  start-page: 15132
  year: 2016
  ident: C8CC07266C-(cit22)/*[position()=1]
  publication-title: Nanoscale
  doi: 10.1039/C6NR04773D
– volume: 10
  start-page: 210
  year: 2017
  ident: C8CC07266C-(cit8)/*[position()=1]
  publication-title: Materials
  doi: 10.3390/ma10020210
– volume: 54
  start-page: 11526
  year: 2015
  ident: C8CC07266C-(cit6)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201506154
– volume: 112
  start-page: 1
  year: 2014
  ident: C8CC07266C-(cit1)/*[position()=1]
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.112.176801
– volume: 113
  start-page: 11688
  year: 2016
  ident: C8CC07266C-(cit14)/*[position()=1]
  publication-title: Proc. Natl. Acad. Sci. U. S. A.
  doi: 10.1073/pnas.1602215113
– volume: 13
  start-page: 1602896
  year: 2017
  ident: C8CC07266C-(cit10)/*[position()=1]
  publication-title: Small
  doi: 10.1002/smll.201602896
– volume: 9
  start-page: 3596
  year: 2015
  ident: C8CC07266C-(cit4)/*[position()=1]
  publication-title: ACS Nano
  doi: 10.1021/acsnano.5b01143
– volume: 23
  start-page: 9144
  year: 2017
  ident: C8CC07266C-(cit18)/*[position()=1]
  publication-title: Chem. – Eur. J.
  doi: 10.1002/chem.201701277
– volume: 51
  start-page: 6293
  year: 2015
  ident: C8CC07266C-(cit17)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/C4CC09826A
– volume: 29
  start-page: 1605776
  year: 2017
  ident: C8CC07266C-(cit27)/*[position()=1]
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201605776
– volume: 7
  start-page: 42357
  year: 2017
  ident: C8CC07266C-(cit9)/*[position()=1]
  publication-title: Sci. Rep.
  doi: 10.1038/srep42357
– volume: 6
  start-page: 27307
  year: 2016
  ident: C8CC07266C-(cit25)/*[position()=1]
  publication-title: Sci. Rep.
  doi: 10.1038/srep27307
– volume: 18
  start-page: 12522
  year: 2012
  ident: C8CC07266C-(cit15)/*[position()=1]
  publication-title: Chem. – Eur. J.
  doi: 10.1002/chem.201201043
– volume: 50
  start-page: 13338
  year: 2014
  ident: C8CC07266C-(cit12)/*[position()=1]
  publication-title: Chem. Commun.
  doi: 10.1039/C4CC05752J
– volume: 89
  start-page: 10
  year: 2018
  ident: C8CC07266C-(cit20)/*[position()=1]
  publication-title: Electrochem. Commun.
  doi: 10.1016/j.elecom.2018.02.010
– volume: 27
  start-page: 1887
  year: 2015
  ident: C8CC07266C-(cit23)/*[position()=1]
  publication-title: Adv. Mater.
  doi: 10.1002/adma.201405150
– volume: 8
  start-page: 4033
  year: 2014
  ident: C8CC07266C-(cit3)/*[position()=1]
  publication-title: ACS Nano
  doi: 10.1021/nn501226z
– volume: 9
  start-page: 372
  year: 2014
  ident: C8CC07266C-(cit2)/*[position()=1]
  publication-title: Nat. Nanotechnol.
  doi: 10.1038/nnano.2014.35
– volume: 3
  start-page: 18222
  year: 2015
  ident: C8CC07266C-(cit16)/*[position()=1]
  publication-title: J. Mater. Chem. A
  doi: 10.1039/C5TA03869C
– volume: 47
  start-page: 6795
  year: 2018
  ident: C8CC07266C-(cit11)/*[position()=1]
  publication-title: Chem. Soc. Rev.
  doi: 10.1039/C8CS00387D
– volume: 6
  start-page: 8563
  year: 2015
  ident: C8CC07266C-(cit13)/*[position()=1]
  publication-title: Nat. Commun.
  doi: 10.1038/ncomms9563
– volume: 56
  start-page: 10443
  year: 2017
  ident: C8CC07266C-(cit19)/*[position()=1]
  publication-title: Angew. Chem., Int. Ed.
  doi: 10.1002/anie.201705071
– volume: 30
  start-page: 2742
  year: 2018
  ident: C8CC07266C-(cit21)/*[position()=1]
  publication-title: Chem. Mater.
  doi: 10.1021/acs.chemmater.8b00521
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SubjectTerms ambient temperature
chemical compounds
chemical reactions
Chemical synthesis
electrolytes
electrosynthesis
luminescence
Nitrogen
Phosphorene
phosphorus
Quantum dots
Quantum efficiency
solvents
Title A single-step, electrochemical synthesis of nitrogen doped blue luminescent phosphorene quantum dots
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