Mechanism of interaction and removal of zinc with lignocellulosic adsorbents, closing the cycle with a soil conditioner
Batch experiments were performed to remove Zn2+ by adsorption process using organic residuals (pistachio, peanut, and almond) as an adsorbent. The adsorbents were characterized by FTIR spectra, SEM images, and elemental analysis. Optimum adsorption of Zn2+ was obtained at pH 6 with a contact time of...
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| Published in | Journal of King Saud University. Science Vol. 33; no. 8; p. 101607 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.12.2021
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| Abstract | Batch experiments were performed to remove Zn2+ by adsorption process using organic residuals (pistachio, peanut, and almond) as an adsorbent. The adsorbents were characterized by FTIR spectra, SEM images, and elemental analysis. Optimum adsorption of Zn2+ was obtained at pH 6 with a contact time of 45 min at room temperature with 1.0 g adsorbents. The adsorption of Zn2+ was found to well describe Langmuir isotherm model and a pseudo-second-order rate equation. The maximum adsorption capacity of pistachio, peanut, and almond is as follows; 59.52 mgg-1, 54.64 mgg-1, and 51.81 mgg-1, respectively. Functional groups on shell surfaces can cooperate with metal ions in many ways such as electrostatic interaction, ion exchange, complex formation, and diffusion. This study has shown that pistachio, peanut, and almond shell can be used for reducing Zn2+ from aqueous solutions as an eco-friendly, low-cost adsorbent. The end-product containing organic compounds and zinc can be used as a soil conditioner. Furthermore, the usage of the organic shell as a sorbent for the capturing of zinc from contaminated water ensures both the technical advantage and cost-effectiveness for the sustainable environmental management concept. |
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| AbstractList | Batch experiments were performed to remove Zn2+ by adsorption process using organic residuals (pistachio, peanut, and almond) as an adsorbent. The adsorbents were characterized by FTIR spectra, SEM images, and elemental analysis. Optimum adsorption of Zn2+ was obtained at pH 6 with a contact time of 45 min at room temperature with 1.0 g adsorbents. The adsorption of Zn2+ was found to well describe Langmuir isotherm model and a pseudo-second-order rate equation. The maximum adsorption capacity of pistachio, peanut, and almond is as follows; 59.52 mgg-1, 54.64 mgg-1, and 51.81 mgg-1, respectively. Functional groups on shell surfaces can cooperate with metal ions in many ways such as electrostatic interaction, ion exchange, complex formation, and diffusion. This study has shown that pistachio, peanut, and almond shell can be used for reducing Zn2+ from aqueous solutions as an eco-friendly, low-cost adsorbent. The end-product containing organic compounds and zinc can be used as a soil conditioner. Furthermore, the usage of the organic shell as a sorbent for the capturing of zinc from contaminated water ensures both the technical advantage and cost-effectiveness for the sustainable environmental management concept. |
| ArticleNumber | 101607 |
| Author | Kayranli, Birol |
| Author_xml | – sequence: 1 givenname: Birol surname: Kayranli fullname: Kayranli, Birol email: bkayranli@gazi.edu.tr organization: Graduate School of Natural and Applied Science, Department of Environmental Science Gazi University, Ankara, Turkey |
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| CitedBy_id | crossref_primary_10_1016_j_jenvman_2024_121722 crossref_primary_10_1016_j_hazadv_2023_100253 crossref_primary_10_1007_s11356_022_22963_4 crossref_primary_10_1016_j_hazadv_2025_100627 crossref_primary_10_3390_ma17215281 crossref_primary_10_1016_j_chemosphere_2024_143056 crossref_primary_10_1016_j_jece_2022_107155 crossref_primary_10_1007_s11356_022_21023_1 crossref_primary_10_14710_jksa_25_9_329_337 crossref_primary_10_1016_j_molstruc_2024_140799 crossref_primary_10_1016_j_jclepro_2023_139138 crossref_primary_10_25259_JKSUS_423_2024 crossref_primary_10_1016_j_ijbiomac_2023_125880 |
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| Keywords | Zinc removal Lignocellulosic adsorbent Removal mechanisms Soil conditioner |
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| SubjectTerms | Lignocellulosic adsorbent Removal mechanisms Soil conditioner Zinc removal |
| Title | Mechanism of interaction and removal of zinc with lignocellulosic adsorbents, closing the cycle with a soil conditioner |
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